Nonmonotonic dependence of comb polymer relaxation on branch density in semidilute solutions of linear polymers
Shivani F. Patel, Charles D. Young, Charles E. Sing, and Charles M. Schroeder
Phys. Rev. Fluids 5, 121301(R) (2020) - Published 17 December, 2020
The relaxation of comb polymers in semidilute solutions is studied using single-molecule fluorescence microscopy and Brownian dynamics simulations with long-range hydrodynamic interactions (HI). Unexpectedly, comb polymer relaxation is found to depend nonmonotonically on branching density, such that lightly branched chains relax faster than linear chains in semidilute solutions. These results challenge commonly held notions in the field and show that the dynamics of branched polymers in nondilute solutions is governed by a coupling between polymer architecture, long-range HI, and excluded volume interactions.



















































