We propose gravitational caloric theory (GCT)—an extension of general relativity that features a vector field sourced by and nonminimally coupled to the fluid sector while preserving covariant conservation of the standard fluid energy-momentum tensor. Our initial motivation is to trigger early dark energy (EDE) using the total fluid equation of state that encodes the cosmic radiation-matter transition. This mechanism provides a natural resolution of the EDE coincidence problem. The cosmological background dynamics are analyzed in detail by casting the evolution equations into dynamical-system form and, in relevant reduced cases, using Poincaré compactification to uncover the corresponding global phase-space structure. Beyond EDE, GCT admits two novel cosmological applications associated with critical points at infinity. Both arise from a class of energy-canceling solutions in which conventional energy components preferentially excite rather than source spacetime curvature. One is a -canceling solution that realizes the self-tuning mechanism for the old cosmological constant problem. However, the present realization does not reenter the standard hot Big Bang phase and is therefore incomplete. The other is a fluid-canceling solution that serves as the basis for our proposed early static hot Universe. In this scenario, offsets the gravitational effect of ordinary hot gas, yielding quasi-static expansion with a decreasing comoving Hubble radius that can address the horizon problem. This offers an alternative to inflation. Furthermore, its hot ingredient distinguishes this scenario from other quasi-static early Universe models and may leave observable signatures in primordial fluctuations. To probe the viability of GCT beyond cosmology, we further analyze linear perturbations about Minkowski spacetime and investigate static spherically symmetric (strong-field) systems. The perturbative analysis singles out a special parameter point at which the theory is free from instabilities and, under standard asymptotically flat boundary conditions, recovers Newtonian gravity in the Solar System regime and admits six independent luminal gravitational-wave polarizations in the radiative sector. For static spherically symmetric configurations, the solution space exhibits rich structures, including wormholes, naked singularities, and effective -like behavior, whereas no black hole solution other than Schwarzschild is found in the cases analyzed. Our findings reveal a wide variety of nontrivial gravitational phenomena in GCT, underscoring its promise for future investigations.