Despite its long history, a canonical formulation of quantum ergodicity that applies to general classes of quantum dynamics, including driven systems, has not been fully established. Here we introduce and study a notion of quantum ergodicity for closed systems with time-dependent Hamiltonians, defined as statistical randomness exhibited in their longtime dynamics. Concretely, we consider the temporal ensemble of quantum states (time-evolution operators) generated by the evolution, and investigate the conditions necessary for them to be statistically indistinguishable from uniformly random states (operators) in the Hilbert space (space of unitaries). We find that the number of driving frequencies underlying the Hamiltonian needs to be sufficiently large for this to occur. Conversely, we show that statistical pseudo-randomness—indistinguishability up to some large but finite moment—can already be achieved by a quantum system driven with a single frequency, i.e., a Floquet system, as long as the driving period is sufficiently long. Our work relates the complexity of a time-dependent Hamiltonian and that of the resulting quantum dynamics, and offers a fresh perspective to the established topics of quantum ergodicity and chaos from the lens of quantum information.

Quantum sensing promises to revolutionize sensing applications by employing quantum states of light or matter as sensing probes. Photons are the clear choice as quantum probes for remote sensing because they can travel to and interact with a distant target. Existing schemes are mainly based on the quantum illumination framework, which requires quantum memory to store a single photon of an initially entangled pair until its twin reflects off a target and returns for final correlation measurements. Existing demonstrations are limited to tabletop experiments, and expanding the sensing range faces various roadblocks, including long-time quantum storage and photon loss and noise when transmitting quantum signals over long distances. We propose a novel quantum sensing framework that addresses these challenges using quantum frequency combs with path identity for remote sensing of signatures (“qCOMBPASS”). The combination of one key quantum phenomenon and two quantum resources—namely, quantum-induced coherence by path identity, quantum frequency combs, and two-mode squeezed light—allows for quantum remote sensing without requiring quantum memory. The proposed scheme is akin to a quantum radar based on entangled frequency-comb pairs that uses path identity to detect, range, or sense a remote target of interest by measuring pulses of one comb in the pair that never traveled to the target but that contains target information “teleported” by quantum-induced coherence by path identity from the other comb in the pair that traveled to the target but is not detected. We develop the basic qCOMBPASS theory, analyze the properties of the qCOMBPASS transceiver, and introduce the qCOMBPASS equation—a quantum analog of the well-known LIDAR equation in classical remote sensing. We also describe an experimental scheme to demonstrate the concept using two-mode squeezed quantum combs. qCOMBPASS can strongly impact various applications in remote quantum sensing, imaging, metrology, and communications. These applications include detection and ranging of low-reflectivity objects, measurement of small displacements of a remote target with precision beyond the standard quantum limit (SQL), standoff hyperspectral quantum imaging, discreet surveillance from space with low detection probability (detect without being detected), very-long-baseline interferometry, quantum Doppler sensing, quantum clock synchronization, and networks of distributed quantum sensors.

Topological semimetals with massless Dirac and Weyl fermions represent the forefront of quantum materials research. In two dimensions, a peculiar class of fermions that are massless in one direction and massive in the perpendicular direction was predicted 16 years ago. These highly exotic quasiparticles—the semi-Dirac fermions—ignited intense theoretical and experimental interest but remain undetected. Using magneto-optical spectroscopy, we demonstrate the defining feature of semi-Dirac fermions—$B^{2/3}$ scaling of Landau levels—in a prototypical nodal-line metal ZrSiS. In topological metals, including ZrSiS, nodal lines extend the band degeneracies from isolated points to lines, loops, or even chains in the momentum space. With ab initio calculations and theoretical modeling, we pinpoint the observed semi-Dirac spectrum to the crossing points of nodal lines in ZrSiS. Crossing nodal lines exhibit a continuum absorption spectrum but with singularities that scale as $B^{2/3}$ at the crossing. Our work sheds light on the hidden quasiparticles emerging from the intricate topology of crossing nodal lines and highlights the potential to explore quantum geometry with linear optical responses.

Decoherence in qubits, caused by their interaction with a noisy environment, poses a significant challenge to the development of reliable quantum processors. A prominent source of errors arises from noise in coupled ancillas, which can quickly spread to qubits. By actively monitoring these noisy ancillas, it is possible to not only identify qubit decoherence events but also to correct these errors in real time. This approach is particularly beneficial for bosonic qubits, where the interaction with ancillas is a dominant source of decoherence. In this work, we uncover the intricate dynamics of decoherence in a superconducting cavity qubit due to its interaction with a noisy transmon ancilla. By tracking the noisy ancilla trajectory and using real-time feedback, we successfully recover the lost coherence of the cavity qubit, achieving a fivefold increase in its pure dephasing time. Additionally, by detecting ancilla errors and converting them into erasures, we improve the pure dephasing time by more than an order of magnitude. These advances are essential for realizing long-lived cavity qubits with high-fidelity gates, and they pave the way for more efficient bosonic quantum error-correction codes.

When an ensemble of quantum emitters couples to a common radiation field, their polarizations can synchronize and a collective emission termed superfluorescence can occur. Entering this regime in a free-space setting requires a large number of emitters with a high spatial density as well as coherent optical transitions with small inhomogeneity. Here, we show that, by coupling nitrogen-vacancy centers in a diamond membrane to a high-finesse microcavity, also few, incoherent, inhomogeneous, and spatially separated emitters—as are typical for solid state systems—can enter the regime of collective emission. We observe a superlinear power dependence of the emission rate as a hallmark of collective emission. Furthermore, we find simultaneous photon bunching and antibunching on different timescales in the second-order autocorrelation function, revealing cavity-induced interference in the quantized emission from about 15 emitters. We develop theoretical models for mesoscopic emitter numbers to analyze the behavior in the Dicke state basis and find that the population of collective states together with cavity enhancement and filtering can explain the observations. Such a system has prospects for the generation of multiphoton quantum states, the preparation of entanglement in few-emitter systems, and enhancement of signals in quantum sensing.

We present a new numerical tool designed to probe the dense layers of neutron star crusts. It is based on the time-dependent Hartree-Fock-Bogoliubov theory with generalized Skyrme nuclear energy-density functionals of the Brussels-Montreal family. We use it to study the time evolution of a nucleus accelerating through superfluid neutron medium in the inner crust of a neutron star. We extract an effective mass in the low velocity limit. We observe a threshold velocity and specify mechanisms of dissipation: phonon emission, Cooper pairs breaking, and vortex rings creation. These microscopic effects are of key importance for understanding various neutron star phenomena. Moreover, the mechanisms we describe are general and apply also to other fermionic superfluids interacting with obstacles like liquid helium or ultracold gases.

Materials-realistic microscopic theoretical descriptions of copper-based superconductors are challenging due to their complex crystal structures combined with strong electron interactions. Here, we demonstrate how density functional theory can accurately describe key structural, electronic, and magnetic properties of the normal state of the prototypical cuprate ${\mathrm{Bi}}_2{\mathrm{Sr}}_2{\mathrm{CaCu}}_2{\mathrm{O}}_{8+x}$ (Bi-2212). We emphasize the importance of accounting for energy-lowering structural distortions, which then allows us to (a) accurately describe the insulating antiferromagnetic (AFM) ground state of the undoped parent compound (in contrast to the metallic state predicted by previous ab initio studies); (b) identify numerous low-energy competing spin and charge stripe orders in the hole-overdoped material nearly degenerate in energy with the AFM ordered state, indicating strong spin fluctuations; (c) predict the lowest-energy hole-doped crystal structure including its long-range structural distortions and oxygen dopant positions that match high-resolution scanning transmission electron microscopy measurements; and (d) describe electronic bands near the Fermi energy with flat antinodal dispersions and Fermi surfaces that are in agreement with angle-resolved photoemission spectroscopy (ARPES) measurements and provide a clear explanation for the structural origins of the so-called “shadow bands.” We also show how one must go beyond band theory and include fully dynamic spin fluctuations via a many-body approach when aiming to make quantitative predictions to measure the ARPES spectra in the overdoped material. Finally, regarding spatial inhomogeneity, we show that the local structure at the ${\mathrm{CuO}}_2$ layer, rather than dopant electrostatic effects, modulates the local charge-transfer gaps, local correlation strengths, and by extension the local superconducting gaps.

The observation of unexpected polarization textures such as vortices, skyrmions, and merons in various oxide heterostructures has challenged the widely accepted picture of ferroelectric domain walls as being Ising-like. Bloch components in the 180° domain walls of ${\mathrm{PbTiO}}_3$ have recently been reported in ${\mathrm{PbTiO}}_3/{\mathrm{SrTiO}}_3$ superlattices and linked to domain wall chirality. While this opens exciting perspectives, the ubiquity of this Bloch component remains to be further explored. In this work, we present a comprehensive investigation of domain walls in ${\mathrm{PbTiO}}_3/{\mathrm{SrTiO}}_3$ superlattices, involving a combination of first- and second-principles calculations, phase-field simulations, diffuse scattering calculations, and synchrotron-based diffuse x-ray scattering. Our theoretical calculations highlight that the previously predicted Bloch polarization in the 180° domain walls in ${\mathrm{PbTiO}}_3/{\mathrm{SrTiO}}_3$ superlattices might be more sensitive to the boundary conditions than initially thought and is not always expected to appear. Employing diffuse scattering calculations for larger systems, we develop a method to probe the complex structure of domain walls in these superlattices via diffuse x-ray scattering measurements. Through this approach, we investigate depolarization-driven ferroelectric polarization rotation at the domain walls. Our experimental findings, consistent with our theoretical predictions for realistic domain periods, do not reveal any signatures of a Bloch component in the centers of the 180° domain walls of ${\mathrm{PbTiO}}_3/{\mathrm{SrTiO}}_3$ superlattices, suggesting that the precise nature of domain walls in the ultrathin ${\mathrm{PbTiO}}_3$ layers is more intricate than previously thought and deserves further attention.

We report universal statistical properties displayed by ensembles of pure states that naturally emerge in quantum many-body systems. Specifically, two classes of state ensembles are considered: those formed by (i) the temporal trajectory of a quantum state under unitary evolution or (ii) the quantum states of small subsystems obtained by partial, local projective measurements performed on their complements. These cases, respectively, exemplify the phenomena of “Hilbert-space ergodicity” and “deep thermalization.” In both cases, the resultant ensembles are defined by a simple principle: The distributions of pure states have maximum entropy, subject to constraints such as energy conservation, and effective constraints imposed by thermalization. We present and numerically verify quantifiable signatures of this principle by deriving explicit formulas for all statistical moments of the ensembles, proving the necessary and sufficient conditions for such universality under widely accepted assumptions, and describing their measurable consequences in experiments. We further discuss information-theoretic implications of the universality: Our ensembles have maximal information content while being maximally difficult to interrogate, establishing that generic quantum state ensembles that occur in nature hide (scramble) information as strongly as possible. Our results generalize the notions of Hilbert-space ergodicity to time-independent Hamiltonian dynamics and deep thermalization from infinite to finite effective temperature. Our work presents new perspectives to characterize and understand universal behaviors of quantum dynamics using statistical and information-theoretic tools.

Striving for higher gate fidelity is crucial not only for enhancing existing noisy intermediate-scale quantum devices, but also for unleashing the potential of fault-tolerant quantum computation through quantum error correction. A recently proposed theoretical scheme, the double-transmon coupler (DTC), aims to achieve both suppressed residual interaction and a fast high-fidelity two-qubit gate simultaneously, particularly for highly detuned qubits. Harnessing the state-of-the-art fabrication techniques and a model-free pulse-optimization process based on reinforcement learning, we translate the theoretical DTC scheme into reality, attaining fidelities of 99.90% for a controlled-$Z$ gate and 99.98% for single-qubit gates. The performance of the DTC scheme demonstrates its potential as a competitive building block for superconducting quantum processors.

The Kerr-cat qubit is a bosonic qubit in which multiphoton Schrödinger cat states are stabilized by applying a two-photon drive to an oscillator with a Kerr nonlinearity. The suppressed bit-flip rate with increasing cat size makes this qubit a promising candidate to implement quantum error correction codes tailored for noise-biased qubits. However, achieving strong light-matter interactions necessary for stabilizing and controlling this qubit has traditionally required strong microwave drives that heat the qubit and degrade its performance. In contrast, increasing the coupling to the drive port removes the need for strong drives at the expense of large Purcell decay. By integrating an effective band-block filter on chip, we overcome this trade-off and realize a Kerr-cat qubit in a scalable 2D superconducting circuit with high coherence. This filter provides 30 dB of isolation at the qubit frequency with negligible attenuation at the frequencies required for stabilization and readout. We experimentally demonstrate quantum nondemolition readout fidelity of 99.6% for a cat with eight photons. Also, to have high-fidelity universal control over this qubit, we combine fast Rabi oscillations with a new demonstration of the $X(\pi /2)$ gate through phase modulation of the stabilization drive. Finally, the lifetime in this architecture is examined as a function of the cat size of up to ten photons in the oscillator, achieving a bit-flip time higher than 1 ms and only a linear increase in the phase-flip rate, in good agreement with the theoretical analysis of the circuit. Our qubit shows promise as a building block for fault-tolerant quantum processors with a small footprint.

Topologically protected edge channels show prospects for quantum devices. They have been found experimentally in two-dimensional quantum spin Hall insulators (QSHIs), weak topological insulators, and higher-order topological insulators, but the number of materials realizing these topologies is still quite limited. Here, we provide evidence for topological edge states within a novel topology named three-dimensional QSHIs. Its topology originates solely from a nonzero ${\mathbf{S}}_{\mathit{z}}$ spin Chern number for each ${\mathbf{k}}_{\mathit{z}}$ plane of the crystal and is realized in bulk $\alpha \text{−}{\mathrm{Bi}}_4{\mathrm{I}}_4$ with trivial symmetry indicators, as we show by density-functional-theory calculations. We experimentally observe the related edge states at each type of monolayer and bilayer step of this material by scanning tunneling microscopy. Consistently, the edge states are neither interrupted nor backscattered by defects at the step edges corroborating their helical character as expected from the nontrivial topology. Furthermore, two individual edge channels are directly observed at bilayer steps without visible interaction gap opening, demonstrating the robustness of these edge modes against vertical stacking. Our results establish $\alpha \text{−}{\mathrm{Bi}}_4{\mathrm{I}}_4$ as the first material realization of a 3D QSHI whose definition goes beyond the scope of topological symmetry indicators, and provide a pathway for realizing nearly quantized spin Hall conductivity per unit cell in a bulk crystal.

We consider a dynamic system that is driven by an intensity-modulated Poisson process with intensity $\mathrm{\Lambda }(t)=\lambda (t)+ϵ\nu (t)$. We derive an exact relation between the input-output cross-correlation in the spontaneous state ($ϵ=0$) and the linear response to the modulation ($ϵ>0$). If $ϵ$ is sufficiently small, linear-response theory captures the full response. The relation can be regarded as a variant of the Furutsu-Novikov theorem for the case of shot noise. As we show, the relation is still valid in the presence of additional independent noise. Furthermore, we derive an extension to Cox-process input, which provides an instance of colored shot noise. We discuss applications to particle detection and to neuroscience. Using the new relation, we obtain a fluctuation-response relation for a leaky integrate-and-fire neuron. We also show how the new relation can be used in a remote control problem in a recurrent neural network. The relations are numerically tested for both stationary and nonstationary dynamics. Lastly, extensions to marked Poisson processes and to higher-order statistics are presented.

In recent demonstrations of the quantum charge-coupled device computer architecture, circuit times are dominated by cooling. Some motional modes of multi-ion crystals take orders of magnitude longer to cool than others because of low coolant ion participation. Here we demonstrate a new technique, that solves this issue by coherently exchanging the thermal populations of selected modes on timescales short compared to direct cooling. Using this method, which we call “phonon rapid adiabatic passage,” we can achieve subquanta temperatures from initial states with occupations as high as $\overline{n}\sim 200$ quanta. Analogous to adiabatic rapid passage, we quasistatically couple these slow-cooling modes with fast-cooling modes using dc electric fields. When the crystal is then adiabatically ramped through the resultant avoided crossing, nearly complete phonon population exchange results. We demonstrate this on two-ion crystals, and show the indirect ground-state cooling of all radial modes—achieving an order of magnitude speedup compared to direct cooling. We also show the technique’s insensitivity to trap potential and control field fluctuations, and find that it still achieves subquanta temperatures starting as high as $\overline{n}\sim 200$.

The ground state of an homogeneous electron gas is a paradigmatic state that has been used to model and predict the electronic structure of matter at equilibrium for nearly a century. For half a century, it has been successfully used to predict ground states of quantum systems via the local density approximation (LDA) of density functional theory (DFT), and systematic improvements in the form of generalized gradient approximations and evolution thereon. Here, we introduce the LDA for excited states by considering a particular class of nonthermal ensemble states of the homogeneous electron gas. These states find sound foundation and application in ensemble DFT—a generalization of DFT that can deal with ground and excited states on equal footing. The ensemble LDA is shown to successfully predict difficult low-lying excitations in atoms and molecules for which approximations based on local spin density approximation and time-dependent LDA fail.

Phosphorescent organic light-emitting devices (PHOLEDs) suffer from destructive molecular processes due to triplet-polaron and triplet-triplet annihilation. These processes are energetically driven and hence are particularly active in decreasing the lifetime of blue PHOLEDs. It has recently been shown that increasing triplet radiative rates via the Purcell effect effectively extends the device operational lifetime by reducing the triplet radiative lifetime, thus decreasing their density and the probability of triplet-annihilation reactions. We provide an analytical framework using Marcus theory to explain the observed, approximately exponential relationship between exciton energy and device lifetime. From transient drift-diffusion dynamics, we show that the Purcell effect reduces the exciton density in the steady state and increases the photoluminescent yield, thereby reducing defect generation rates and extending the device lifetime. We control the radiative rate of excitons in microcavities, thereby connecting the exciton energy and decay rates with the observed device lifetime. The device lifetime is shown to follow a power-law dependence on the Purcell factor (${\mathrm{PF}}^m$) with $m=1.5$ to 2.5, dependent on the TTA-to-TPA ratio and photoluminescence quantum yield. From our analysis, a fivefold increase in PF has the potential to extend the blue PHOLED lifetime by up to 2 orders of magnitude, making the blue PHOLED lifetime comparable to that of state-of-the-art green PHOLEDs.

We report on broad instantaneous bandwidth microwave spectrum analysis with hot ${}^{87}\mathrm{Rb}$ atoms in a microfabricated vapor cell in a large magnetic field gradient. The sensor is a MEMS atomic vapor cell filled with isotopically pure ${}^{87}\mathrm{Rb}$ and ${\mathrm{N}}_2$ buffer gas to localize the motion of the atoms. The microwave signals of interest are coupled through a coplanar waveguide to the cell, inducing spin-flip transitions between optically pumped ground states of the atoms. A static magnetic field with large gradient maps the frequency spectrum of the input microwave signals to a position-dependent spin-flip pattern on absorption images of the cell recorded with a laser beam onto a camera. In our proof-of-principle experiment, we demonstrate a microwave spectrum analyzer that has $\approx 1\mathrm{GHz}$ instantaneous bandwidth centered around 13 GHz, 3 MHz frequency resolution, 2 kHz refresh rate, and a $-23\mathrm{dBm}$ single-tone microwave power detection limit in 1 s measurement time. A theoretical model is constructed to simulate the image signals by considering the processes of optical pumping, microwave interaction, diffusion of ${}^{87}\mathrm{Rb}$ atoms, and laser absorption. We expect to reach more than 25 GHz instantaneous bandwidth in an optimized setup, limited by the applied magnetic field gradient. Our demonstration offers a practical alternative to conventional microwave spectrum analyzers based on electronic heterodyne detection.

Attosecond physics enables the study of ultrafast coherent electron dynamics in matter upon photoexcitation and photoionization, revealing spectacular effects such as hole migration and coherent Auger dynamics in molecules. In the photoionization scenario, there has been a strong focus on probing the physical manifestations of internal quantum coherence within the individual parent ion and photoelectron systems. However, quantum correlations between these two subsystems emerging from attosecond photoionization events have thus far remained much more elusive. In this work, we design theoretically and model numerically a direct probe of quantum entanglement in attosecond photoionization in the form of a Bell test. We simulate from first principles a Bell test protocol for the case of noble gas atoms photoionized by ultrashort, circularly polarized infrared laser pulses in the strong-field regime predicting robust violation of the Bell inequality. This theoretical result paves the way for the direct observation of entanglement in the context of ultrafast photoionization of many-electron systems. Our work provides a novel perspective on attosecond physics directed toward the detection of quantum correlations between systems born during attosecond photoionization and unraveling the signatures of entanglement in ultrafast coherent molecular dynamics, including in the chemical decomposition pathways of molecular ions.

Topology, like symmetry, is a fundamental concept in understanding general properties of physical systems. In condensed matter, nontrivial topology may manifest itself as singular features in the energy spectrum or the quantization of electrical properties such as conductance and magnetic flux. Using microwave spectroscopy, we determine that a superconducting circuit with three Josephson tunnel junctions in parallel can possess degeneracies indicative of intrinsic nontrivial topology. We identify three topological invariants, one of which is related to a hidden quantum mechanical supersymmetry. Measurements show that devices fabricated in different topological regimes fall on a simple phase diagram, which should be robust to junction imperfections and geometric inductance. Josephson tunnel junction circuits, which are readily fabricated with conventional microlithography techniques, allow access to a wide range of topological systems that may have no condensed matter analog. Notable spectral features of these circuits, such as degeneracies and flat bands, may find use in quantum information, sensing, and metrology.