- Open Access
Entanglement in elastic electron scattering: Perturbation theory misses fundamental aspects of Bragg scattering
Phys. Rev. Research 8, 033217 – Published 21 August, 2026
DOI: https://doi.org/10.1103/vvb9-rf35
Abstract
Elastic electron scattering is one of the primary means of investigating materials on the atomic scale. It is usually described in a one-particle approach (the probe electron's evolution in a perturbative static potential), whereas we are dealing here with a two-body interaction between the probe and the sample, both described by separate quantum states, inducing entanglement. In this work, we present a quantum treatment of elastic electron scattering. We find that the entanglement between probe and scatterer can have far-reaching consequences, particularly on coherence and image contrast. As a timely example, we discuss decoherence in Bragg scattering on nanoparticles. We find that conventional scattering theory is recovered in most cases. The situation changes dramatically for freely evolving nanoparticles as, e.g., levitated motional ground states, an active field of research.
Physics Subject Headings (PhySH)
Article Text
References (34)
- H. Gegier and E. Marsden, On a diffuse reflection of the -particles, Proc. R. Soc. London A 82, 495 (1909).
- E. Rutherford, The scattering of and particles by matter and the structure of the atom, Philos. Mag. 21, 669 (1911).
- J. W. Menter, The direct study by electron microscopy of crystal lattices and their imperfections, Proc. R. Soc. A 236, 119 (1956).
- J. C. Meyer, C. Kisielowski, R. Erni, M. D. Rossell, M. F. Crommie, and A. Zettl, Direct imaging of lattice atoms and topological defects in graphene membranes, Nano Lett. 8, 3582 (2008).
- J. Frank, Three-dimensional Electron Microscopy of Macromolecular Assemblies (Oxford University Press, New York, 2006).
- D. B. Williams and C. B. Carter, Transmission Electron Microscopy (Plenum Press, New York, 1996).
- M. Arndt, O. Nairz, J. Vos-Andreae, C. Keller, G. van der Zouw, and A. Zeilinger, Wave-particle duality of molecules, Nature (London) 401, 680 (1999).
- S. Gerlich, S. Eibenberger, M. Tomandl, S. Nimmrichter, K. Hornberger, P. J. Fagan, J. Tüxen, M. Mayor, and M. Arndt, Quantum interference of large organic molecules, Nat. Commun. 2, 263 (2011).
- Y. Y. Fein, P. Geyer, P. Zwick, F. Kiałka, S. Pedalino, M. Mayor, S. Gerlich, and M. Arndt, Quantum superposition of molecules beyond 25 kDa, Nat. Phys. 15, 1242 (2019).
- S. Pedalino, B. E. Ramírez-Galindo, R. Ferstl, K. Hornberger, M. Arndt, and S. Gerlich, Probing quantum mechanics with nanoparticle matter-wave interferometry, Nature 649, 866 (2026).
- S. Nimmrichter, D. Rätzel, I. C. Bicket, M. S. Seifner, and P. Haslinger, Electron-enabled nanoparticle diffraction, Phys. Rev. Lett. 135, 173601 (2025).
- P. Schattschneider and S. Löffler, Entanglement and decoherence in electron microscopy, Ultramicroscopy 190, 39 (2018).
- P. Schattschneider, S. Löffler, H. Gollisch, and R. Feder, Entanglement and entropy in electron–electron scattering, J. Electron Spectrosc. Relat. Phenom. 241, 146810 (2020).
- K. Blum, Density Matrix Theory and Applications, Physics of Atoms and Molecules (Springer, Berlin, Heidelberg, 1996), 2nd ed.
- P. Schattschneider, M. Nelhiebel, and B. Jouffrey, Density matrix of inelastically scattered fast electrons, Phys. Rev. B 59, 10959 (1999).
- P. Schattschneider, M. Nelhiebel, H. Souchay, and B. Jouffrey, The physical significance of the mixed dynamic form factor, Micron 31, 333 (2000).
- R. Ruimy, O. Tziperman, A. Gorlach, K. Mølmer, and I. Kaminer, Many-body entanglement via ‘which-path’ information, npj Quantum Inf. 10, 121 (2024).
- M. Schlosshauer, Quantum decoherence, Phys. Rep. 831, 1 (2019).
- U. Delić, M. Reisenbauer, K. Dare, D. Grass, V. Vuletić, N. Kiesel, and M. Aspelmeyer, Cooling of a levitated nanoparticle to the motional quantum ground state, Science 367, 892 (2020).
- J. Piotrowski, D. Windey, J. Vijayan, C. Gonzalez-Ballestero, A. de los Ríos Sommer, N. Meyer, R. Quidant, O. Romero-Isart, R. Reimann, and L. Novotny, Simultaneous ground-state cooling of two mechanical modes of a levitated nanoparticle, Nat. Phys. 19, 1009 (2023).
- A. Pontin, H. Fu, M. Toroš, T. S. Monteiro, and P. F. Barker, Simultaneous cavity cooling of all six degrees of freedom of a levitated nanoparticle, Nat. Phys. 19, 1003 (2023).
- T. D. Kieu, Quantum central limit theorems, emergence of classicality and time-dependent differential entropy, Entropy 25, 600 (2023).
- C. Cohen-Tannoudji, in Quantum Mechanics, edited by B. Diu, F. Laloe, N. Ostrowsky, and D. Ostrowsky (Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2020), 2nd ed.
- O. L. Krivanek, T. C. Lovejoy, N. Dellby, T. Aoki, R. W. Carpenter, P. Rez, E. Soignard, J. Zhu, P. E. Batson, M. J. Lagos, R. F. Egerton, and P. A. Crozier, Vibrational spectroscopy in the electron microscope, Nature (London) 514, 209 (2014).
- E. J. Kirkland, Advanced Computing in Electron Microscopy (Plenum Press, New York, 1998).
- S. Löffler, V. Motsch, and P. Schattschneider, A pure state decomposition approach of the mixed dynamic form factor for mapping atomic orbitals, Ultramicroscopy 131, 39 (2013).
- J. Rusz, A. Lubk, J. Spiegelberg, and D. Tyutyunnikov, Fully nonlocal inelastic scattering computations for spectroscopical transmission electron microscopy methods, Phys. Rev. B 96, 245121 (2017).
- J. E. Bateman, S. Nimmrichter, K. Hornberger, and H. Ulbricht, Near-field interferometry of a free-falling nanoparticle from a point-like source, Nat. Commun. 5, 4788 (2014).
- O. Romero-Isart, A. C. Pflanzer, F. Blaser, R. Kaltenbaek, N. Kiesel, M. Aspelmeyer, and J. I. Cirac, Large quantum superpositions and interference of massive nanometer-sized objects, Phys. Rev. Lett. 107, 020405 (2011).
- M. Rossi, A. Militaru, N. C. Zambon, A. Riera-Campeny, O. Romero-Isart, M. Frimmer, and L. Novotny, Quantum delocalization of a levitated nanoparticle, Phys. Rev. Lett. 135, 083601 (2025).
- F. Tebbenjohanns, M. L. Mattana, M. Rossi, M. Frimmer, and L. Novotny, Quantum control of a nanoparticle optically levitated in cryogenic free space, Nature (London) 595, 378 (2021).
- L. Dania, O. S. Kremer, J. Piotrowski, D. Candoli, J. Vijayan, O. Romero-Isart, C. Gonzalez-Ballestero, L. Novotny, and M. Frimmer, High-purity quantum optomechanics at room temperature, Nat. Phys. 21, 1603 (2025).
- S. Troyer, F. Fechtel, L. Hummer, H. Rudolph, B. A. Stickler, U. Delić, and M. Arndt, Quantum ground-state cooling of two librational modes of a nanorotor, Nat. Phys. 22, 584 (2026).
- https://en.wikipedia.org/wiki/Characteristic_function_(probability_theory), accessed 6 March 2026.