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Effect of the salt-induced micellar microstructure on the nonlinear shear flow behavior of ionic cetylpyridinium chloride surfactant solutions

D. Gaudino1,*, R. Pasquino1, H. Kriegs2, N. Szekely3, W. Pyckhout-Hintzen4, M. P. Lettinga2,5, and N. Grizzuti1

  • 1Dipartimento di Ingegneria Chimica, dei Materiali d della Produzione Industriale, Università degli Studi di Napoli Federico II, Piazzale Vincenzo Tecchio 80, 80125 Napoli, Italy
  • 2Institute for Complex Systems, Forschungszentrum Jülich, 52425 Jülich, Germany
  • 3Jülich Centre for Neutron Science Outstation at MLZ, Lichtenbergstrasse 1, 85747 Garching, Germany
  • 4Jülich Centre for Neutron Science, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
  • 5Laboratory for Soft Matter and Biophysics, KU Leuven, Celestijnenlaan 200D, 3001 Leuven, Belgium

  • *danila.gaudino@unina.it
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Phys. Rev. E 95, 032603 – Published 7 March, 2017

DOI: https://doi.org/10.1103/PhysRevE.95.032603

Abstract

The shear flow dynamics of linear and branched wormlike micellar systems based on cetylpyridinium chloride and sodium salicylate in brine solution is investigated through rheometric and scattering techniques. In particular, the flow and the structural flow response are explored via velocimetry measurements and rheological and rheometric small-angle neutron scattering (SANS) experiments, respectively. Although all micellar solutions display a similar shear thinning behavior in the nonlinear regime, the experimental results show that shear banding sets in only when the micelle contour length L¯ is sufficiently long, independent of the nature of the micellar connections (either linear or branched micelles). Using rheometric SANS, we observe that the shear banding systems both show very similar orientational ordering as a function of Weissenberg number, while the short branched micelles manifest an unexpected increase of ordering at very low Weissenberg numbers. This suggests the presence of an additional flow-induced relaxation process that is peculiar for branched systems.

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Corrections

17 April, 2017

Erratum

Publisher's Note: Effect of the salt-induced micellar microstructure on the nonlinear shear flow behavior of ionic cetylpyridinium chloride surfactant solutions [Phys. Rev. E 95, 032603 (2017)]

D. Gaudino, R. Pasquino, H. Kriegs, N. Szekely, W. Pyckhout-Hintzen, M. P. Lettinga, and N. Grizzuti
Phys. Rev. E 95, 049902 (2017)

Article Text

References (55)

  1. M. E. Cates, Macromolecules 20, 2289 (1987).
  2. U. Olsson, J. Börjesson, R. Angelico, A. Ceglie, and G. Palazzo, Soft Matter 6, 1769 (2010).
  3. R. Angelico, S. Amin, M. Monduzzi, S. Murgia, U. Olsson, and G. Palazzo, Soft Matter 8, 10941 (2012).
  4. M. E. Cates and S. J. Candau, J. Phys.: Condens. Matter 2, 6869 (1990).
  5. C. A. Dreiss, Soft Matter 3, 956 (2007).
  6. D. Gaudino, R. Pasquino, and N. Grizzuti, J. Rheol. 59, 1363 (2015).
  7. S. A. Rogers, M. A. Calabrese, and N. J. Wagner, Curr. Opin. Colloid Interface Sci. 19, 530 (2014).
  8. D. Gaudino, R. Pasquino, J. Stellbrink, N. Szekely, M. Krutyeva, A. Radulescu, W. Pyckhout-Hintzen, and N. Grizzuti, Phys. Chem. Chem. Phys. 19, 782 (2017).
  9. M. A. Calabrese, S. A. Rogers, R. P. Murphy, and N. J. Wagner, J. Rheol. 59, 1299 (2015).
  10. M. A. Calabrese, S. A. Rogers, L. Porcar, and N. J. Wagner, J. Rheol. 60, 1001 (2016).
  11. W. Richtering, Curr. Opin. Colloid Interface Sci. 6, 446 (2001).
  12. J. F. Berret, R. Gamez-Corrales, Y. Séréro, F. Molino, and P. Lindner, Europhys. Lett. 54, 605 (2001).
  13. S. L. Keller, P. Boltenhagen, D. J. Pine, and J. A. Zasadzinski, Phys. Rev. Lett. 80, 2725 (1998).
  14. B. M. Marín-Santibáñez, J. Pérez-González, L. De Vargas, F. Rodríguez-González, and G. Huelsz, Langmuir 22, 4015 (2006).
  15. S. Förster, M. Konrad, and P. Lindner, Phys. Rev. Lett. 94, 017803 (2005).
  16. V. Croce, T. Cosgrove, C. A. Dreiss, S. King, G. Maitland, and T. Hughes, Langmuir 21, 6762 (2005).
  17. J. B. Hayter and J. Penfold, J. Phys. Chem. 88, 4589 (1984).
  18. Y. T. Hu, C. Palla, and A. Lips, J. Rheol. 52, 379 (2008).
  19. J.-B. Salmon, A. Colin, S. Manneville, and F. Molino, Phys. Rev. Lett. 90, 228303 (2003).
  20. S. Manneville, Rheol. Acta 47, 301 (2008).
  21. J. K. G. Dhont and W. J. Briels, Rheol. Acta 47, 257 (2008).
  22. H. Rehage and H. Hoffmann, J. Phys. Chem. 92, 4712 (1988).
  23. H. Rehage and H. Hoffmann, Mol. Phys. 74, 933 (1991).
  24. N. A. Spenley, M. E. Cates, and T. C. B. McLeish, Phys. Rev. Lett. 71, 939 (1993).
  25. J.-F. Berret, Langmuir 13, 2227 (1997).
  26. A. K. Gurnon, C. Lopez-Barron, M. J. Wasbrough, L. Porcar, and N. J. Wagner, ACS Macro Lett. 3, 276 (2014).
  27. B. A. Schubert, E. W. Kaler, and N. J. Wagner, Langmuir 19, 4079 (2003).
  28. M. W. Liberatore, F. Nettesheim, N. J. Wagner, and L. Porcar, Phys. Rev. E 73, 020504 (2006).
  29. P. Thareja, I. H. Hoffmann, M. W. Liberatore, M. E. Helgeson, Y. T. Hu, M. Gradzielski, and N. J. Wagner, J. Rheol. 55, 1375 (2011).
  30. V. Herle, J. Kohlbrecher, B. Pfister, P. Fischer, and E. J. Windhab, Phys. Rev. Lett. 99, 158302 (2007).
  31. B. A. Schubert, N. J. Wagner, E. W. Kaler, and S. R. Raghavan, Langmuir 20, 3564 (2004).
  32. M. A. Fardin, L. Casanellas, B. Saint-Michel, S. Manneville, and S. Lerouge, J. Rheol. 60, 917 (2016).
  33. G. Porte, R. Gomati, O. El Haitamy, J. Appell, and J. Marignan, J. Phys. Chem. 90, 5746 (1986).
  34. S. J. Haward and G. H. McKinley, Phys. Rev. E 85, 031502 (2012).
  35. C. Oelschlaeger, M. Schopferer, F. Scheffold, and N. Willenbacher, Langmuir 25, 716 (2009).
  36. J. Delgado, H. Kriegs, and C. Rolando, J. Phys. Chem. B 113, 15485 (2009).
  37. R. Granek and M. E. Cates, J. Chem. Phys. 96, 4758 (1992).
  38. S. Dhakal and R. Sureshkumar, J. Chem. Phys. 143, 024905 (2015).
  39. H. A. Barnes, J. F. Hutton, and K. Walters, An Introduction to Rheology (Elsevier, Amsterdam, 1989), Vol. 3.
  40. K. H. De Haas, D. Van Den Ende, C. Blom, E. G. Altena, G. J. Beukema, and J. Mellema, Rev. Sci. Instrum. 69, 1391 (1998).
  41. C. W. Macosko, Rheology: Principles, Measurements, and Applications (Wiley-VCH, New York, 1994); R. G. Larson, The Structure and Rheology of Complex Fluids (Oxford University Press, New York, 1998).
  42. S. J. Picken, J. Aerts, R. Visser, and M. G. Northolt, Macromolecules 23, 3849 (1990).
  43. B. Lonetti, J. Kohlbrecher, L. Willner, J. K. G. Dhont, and M. P. Lettinga, J. Phys.: Condens. Matter 20, 404207 (2008).
  44. B. Hammouda, Probing Nanascale Structures—The SANS Toolbox (NIST, Gaithersburg, 2008).
  45. M. W. Liberatore, F. Nettesheim, P. A. Vasquez, M. E. Helgeson, N. J. Wagner, E. W. Kaler, L. P. Cook, L. Porcar, and Y. T. Hu, J. Rheol. 53, 441 (2009).
  46. M. E. Helgeson, M. D. Reichert, Y. T. Hu, and N. J. Wagner, Soft Matter 5, 3858 (2009).
  47. J. P. Decruppe, S. Lerouge, and J. F. Berret, Phys. Rev. E 63, 022501 (2001).
  48. J. F. Berret, D. C. Roux, G. Porte, and P. Lindner, Europhys. Lett. 25, 521 (1994).
  49. C. R. López-Barrón, A. K. Gurnon, A. P. Eberle, L. Porcar, and N. J. Wagner, Phys. Rev. E 89, 042301 (2014).
  50. F. Lequeux, Europhys. Lett. 19, 675 (1992).
  51. N. Ruocco, L. Dahbi, P. Driva, N. Hadjichristidis, J. Allgaier, A. Radulescu, M. Sharp, P. Lindner, E. Straube, W. Pyckhout-Hintzen, and D. Richter, Macromolecules 46, 9122 (2013).
  52. K. Nakamura and T. Shikata, J. Phys. Chem. B 111, 12411 (2007).
  53. T. C. B. McLeish, J. Allgaier, D. K. Bick, G. Bishko, P. Biswas, R. Blackwell, B. Blottière, N. Clarke, B. Gibbs, D. J. Groves, A. Hakiki, R. K. Heenan, J. M. Johnson, R. Kant, D. J. Read, and R. N. Young, Macromolecules 32, 6734 (1999).
  54. R. G. Larson, J. Rheol. 56, 1363 (2012).
  55. W. Zou and R. G. Larson, J. Rheol. 58, 681 (2014).

Outline

Information

Phys. Rev. E 95, 032603– Published 7 March, 2017
  • Received 31 July 2016
  • Revised 5 December 2016
  • Corrected 17 April 2017

©2017 American Physical Society

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