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Quantum effects in the dynamics of deeply supercooled water

A. L. Agapov1,2, A. I. Kolesnikov3, V. N. Novikov1,2, R. Richert4, and A. P. Sokolov1,2

  • 1Department of Chemistry and Joint Institute for Neutron Sciences, University of Tennessee, Knoxville, Tennessee 37996, USA
  • 2Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • 3Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
  • 4Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287, USA

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Phys. Rev. E 91, 022312 – Published 26 February, 2015

DOI: https://doi.org/10.1103/PhysRevE.91.022312

Abstract

Despite its simple chemical structure, water remains one of the most puzzling liquids with many anomalies at low temperatures. Combining neutron scattering and dielectric relaxation spectroscopy, we show that quantum fluctuations are not negligible in deeply supercooled water. Our dielectric measurements reveal the anomalously weak temperature dependence of structural relaxation in vapor-deposited water close to the glass transition temperature Tg∼136K. We demonstrate that this anomalous behavior can be explained well by quantum effects. These results have significant implications for our understanding of water dynamics.

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Phys. Rev. E 91, 022312– Published 26 February, 2015
  • Received 9 August 2013
  • Revised 1 October 2014
Article part of CHORUS

©2015 American Physical Society

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