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Field-induced transitions between multilayer phases of polar smectic liquid crystals

P. V. Dolganov1, V. M. Zhilin1, V. K. Dolganov1, and E. I. Kats2

  • 1Institute of Solid State Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russia
  • 2L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 117940 GSP-1, Moscow, Russia

Phys. Rev. E 86, 020701(R) – Published 15 August, 2012

DOI: https://doi.org/10.1103/PhysRevE.86.020701

Abstract

Recently Wang et al. [Phys. Rev. Lett. 104, 027801 (2010)] reported the discovery of a novel multilayer phase in polar liquid crystals. The phase was unambiguously assigned to a six-layer antiferroelectric structure (Sm-Cd6*) by resonant x-ray diffraction. This discovery lead to essential progress in understanding the nature of polar phases. However, more recently, Chandani et al. [Liq. Cryst. 38, 663 (2011)] in the same material clearly identified the novel phase as a ferrielectric five-layer structure (Sm-Cd5*) by the electric-field-induced birefringence. This contradiction seemed to be a mystery. In this paper we show that the two experiments are in agreement. Phenomenological Landau theory of the phase transitions shows that both phases (Sm-Cd6* and Sm-Cd5*) exist and transform into each other in a relatively low electric field.

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References (22)

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