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Comparison of complete scaling and a field-theoretic treatment of asymmetric fluid criticality

C. E. Bertrand1,*, J. F. Nicoll2, and M. A. Anisimov1

  • 1Institute for Physical Science & Technology, and Department of Chemical & Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, USA
  • 2Institute for Defense Analysis, Alexandria, Virginia 22311, USA

  • *Present address: Department of Nuclear Science, and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139; cbertran@mit.edu

Phys. Rev. E 85, 031131 – Published 21 March, 2012

DOI: https://doi.org/10.1103/PhysRevE.85.031131

Abstract

We investigate the connection between the theory of complete scaling and a field-theoretic (FT) treatment of asymmetric fluid criticality. To facilitate the comparison, we develop an equation of state from a simplified form of the complete scaling transformations and systematically compare this equation of state with the equation of state generated by a FT treatment of an asymmetric Landau-Ginzburg-Wilson Hamiltonian. We find, with care in interpretation, that these two approaches may be read as equivalent up to terms involving an independent higher-order asymmetric correction-to-scaling exponent.

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