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Confinement of semiflexible polymers
Phys. Rev. E 85, 026603 – Published 16 February, 2012
DOI: https://doi.org/10.1103/PhysRevE.85.026603
Abstract
A variational framework is developed to examine the equilibrium states of a semiflexible polymer that is constrained to lie on a fixed surface. As an application the confinement of a closed polymer loop of fixed length within a spherical cavity of smaller radius, , is considered. It is shown that an infinite number of distinct periodic completely attached equilibrium states exist, labeled by two integers: and , the number of periods of the polar and azimuthal angles, respectively. Small loops oscillate about a geodesic circle: , is the stable ground state; states with higher exhibit instabilities. If new states appear as oscillations about a doubly covered geodesic circle; the state replaces the twofold as the ground state in a finite band of values of . With increasing , loop states make a transition from oscillatory and orbital behavior on crossing the poles, returning to oscillation upon collapse to a multiple cover of a geodesic circle (signaled, respectively, by an increase in and an increase in ). The force transmitted to the surface does not increase monotonically with loop size, but does asymptotically. It behaves discontinuously where changes. The contribution to energy from geodesic curvature is bounded. In large loops, the energy becomes dominated by a state independent contribution proportional to the loop size; the energy gap between the ground state and excited states disappears.
Article Text
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