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Force-induced breakdown of flexible polymerized membrane

J. Paturej1,2, H. Popova3, A. Milchev1,3, and T. A. Vilgis1

  • 1Max Planck Institute for Polymer Research, 10 Ackermannweg, D-55128 Mainz, Germany
  • 2Institute of Physics, University of Szczecin, Wielkopolska 15, PL-70451 Szczecin, Poland
  • 3Institute of Physical Chemistry, Bulgarian Academy of Sciences, BG-1113 Sofia, Bulgaria

Phys. Rev. E 85, 021805 – Published 21 February, 2012

DOI: https://doi.org/10.1103/PhysRevE.85.021805

Abstract

We consider the fracture of a free-standing two-dimensional (2D) elastic-brittle network to be used as protective coating subject to constant tensile stress applied on its rim. Using a molecular-dynamics simulation with a Langevin thermostat, we investigate the scission and recombination of bonds, and the formation of cracks in the 2D graphenelike hexagonal sheet for different pulling force f and temperature T. We find that bond rupture occurs almost always at the sheet periphery, and the first mean breakage time τ of bonds decays with membrane size as τNβ, where β0.50±0.03 and N denotes the number of atoms in the membrane. The probability distribution of bond scission times t is given by a Poisson function W(t)t1/3exp(t/τ). The mean failure time τr necessary to rip off the sheet declines with growing size N as a power law τrNφ(f). We also find τrexp(ΔU0/kBT), where the nucleation barrier for crack formation ΔU0f2, in agreement with Griffith's theory. τr displays an Arrhenian dependence of τr on temperature T. Our results indicate a rapid increase in crack spreading velocity with growing external tension f.

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