Export citation

Export citation

Choose format for download:

Download Citation
  • Rapid Communication
  • Access by Xinjiang University

Nearly logarithmic decay in the colloidal hard-sphere system

M. Sperl

  • Fachbereich Physik, Universität Konstanz, 78457 Konstanz, Germany

Phys. Rev. E 71, 060401(R) – Published 13 June, 2005

DOI: https://doi.org/10.1103/PhysRevE.71.060401

Abstract

Nearly logarithmic decay is identified in the data for the mean-squared displacement of the colloidal hard-sphere system at the liquid-glass transition [W. van Megen et al., Phys. Rev. E 58, 6073 (1998)]. The solutions of the mode-coupling theory for the microscopic equations of motion fit the experimental data well. Based on these equations, the nearly logarithmic decay is explained as the equivalent of a β-peak phenomenon, a manifestation of the critical relaxation when the coupling between of the probe variable and the density fluctuations is strong. In an asymptotic expansion, a Cole-Cole formula including corrections is derived from the microscopic equations of motion, which describes the experimental data for three decades in time.

Article Text

References (21)

  1. W. Kob, in Slow Relaxations and Nonequilibrium Dynamics in Condensed Matter, edited by J.-L. Barrat, M. Feigelman, J. Kurchan, and J. Dalibard (Springer, Berlin, 2003), p. 199.
  2. G. Hinze, D. D. Brace, S. D. Gottke, and M. D. Fayer, Phys. Rev. Lett. 84, 2437 (2000); 84, 4783(E) (2000); J. Chem. Phys. 113, 3723 (2000); M. Ricci, P. Bartolini, and R. Torre, Philos. Mag. B 82, 541 (2002); H. Cang, V. N. Novikov, and M. D. Fayer, Phys. Rev. Lett. 90, 197401 (2003); J. Chem. Phys. 118, 2800 (2003).
  3. W. Götze and M. Sperl, Phys. Rev. Lett. 92, 105701 (2004).
  4. M. Sperl, Phys. Rev. E 68, 031405 (2003); F. Sciortino, P. Tartaglia, and E. Zaccarelli, Phys. Rev. Lett. 91, 268301 (2003).
  5. L. Berthier and J. P. Garrahan, J. Phys. Chem. B 109, 3578 (2005).
  6. W. Götze, in Liquids, Freezing and Glass Transition, edited by J. P. Hansen, D. Levesque, and J. Zinn-Justin (North Holland, Amsterdam, 1991), p. 287.
  7. J.-P. Hansen and I. R. McDonald, Theory of Simple Liquids, 2nd ed. (Academic, London, 1986).
  8. U. Bengtzelius, W. Götze, and A. Sjölander, J. Phys. C 17, 5915 (1984).
  9. W. van Megen, Transp. Theory Stat. Phys. 24, 1017 (1995).
  10. T. Voigtmann, A. Puertas, and M. Fuchs, Phys. Rev. E 70, 061506 (2004).
  11. W. van Megen, T. C. Mortensen, S. R. Williams, and J. Müller, Phys. Rev. E 58, 6073 (1998).
  12. M. Fuchs, W. Götze, and M. R. Mayr, Phys. Rev. E 58, 3384 (1998).
  13. P. N. Segrè and P. N. Pusey, Phys. Rev. Lett. 77, 771 (1996).
  14. S.-H. Chong, W. Götze, and M. R. Mayr, Phys. Rev. E 64, 011503 (2001).
  15. M. Tokuyama, Y. Terada, and I. Oppenheim, Physica A 307, 27 (2002).
  16. W. Götze and L. Sjögren, J. Phys.: Condens. Matter 1, 4183 (1989).
  17. N. B. Simeonova and W. K. Kegel, Phys. Rev. Lett. 93, 035701 (2004).
  18. G. Foffi, W. Götze, F. Sciortino, P. Tartaglia, and T. Voigtmann, Phys. Rev. E 69, 011505 (2004).
  19. M. Tokuyama, H. Yamazaki, and Y. Terada, Phys. Rev. E 67, 062403 (2003); M. Tokuyama, Physica A 289, 57 (2001).
  20. H. Cang, J. Li, V. N. Novikov, and M. D. Fayer, J. Chem. Phys. 119, 10421 (2003).
  21. M. Fuchs and M. R. Mayr, Phys. Rev. E 60, 5742 (1999).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation