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Measuring subdiffusion parameters

T. Kosztołowicz1, K. Dworecki1, and St. Mrówczyński1,2

  • 1Institute of Physics, Świȩtokrzyska Academy, ul. Świȩtokrzyska 15, PL-25-406 Kielce, Poland
  • 2Sołtan Institute for Nuclear Studies, ul. Hoża 69, PL-00-681 Warsaw, Poland

Phys. Rev. E 71, 041105 – Published 18 April, 2005

DOI: https://doi.org/10.1103/PhysRevE.71.041105

Abstract

We propose a method to extract from experimental data the subdiffusion parameter α and subdiffusion coefficient Dα which are defined by means of the relation x2=[2DαΓ(1+α)]tα where x2 denotes the mean-square displacement of a random walker starting from x=0 at the initial time t=0. The method exploits a membrane system where a substance of interest is transported in a solvent from one vessel to another across a thin membrane which plays here only an auxiliary role. Using such a system, we experimentally study the diffusion of glucose and sucrose in a gel solvent. We find a fully analytic solution of the fractional subdiffusion equation with the initial and boundary conditions representing the system under study. Confronting the experimental data with the derived formulas, we show the subdiffusive character of sugar transport in a gel solvent. We precisely determine the parameter α, which is smaller than 1, and the subdiffusion coefficient Dα.

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