- Access by Xinjiang University
Interaction between two spherical particles in a nematic liquid crystal
Phys. Rev. E 69, 041706 – Published 30 April, 2004
DOI: https://doi.org/10.1103/PhysRevE.69.041706
Abstract
We numerically investigate the interaction between two spherical particles in a nematic liquid crystal mediated by elastic distortions in the orientational order. We pay attention to the cases where two particles with equal radii impose rigid normal anchoring on their surfaces and carry a pointlike topological defect referred to as a hyperbolic hedgehog. To describe the geometry of our system, we use bispherical coordinates, which prove useful in the implementation of boundary conditions at the particle surfaces and at infinity. We adopt the Landau–de Gennes continuum theory in terms of a second-rank tensor order parameter for the description of the orientational order of a nematic liquid crystal. We also utilize an adaptive mesh refinement scheme that has proven to be an efficient way of dealing with topological defects whose core size is much smaller than the particle size. When the two “dipoles,” composed of a particle and a hyperbolic hedgehog, are in parallel directions, the two-particle interaction potential is attractive for large interparticle distances and proportional to as expected from the form of the dipole-dipole interaction, until the well-defined potential minimum at is reached. For the antiparallel configuration with no hedgehogs between the two particles, the interaction potential is repulsive and behaves as for , which is stronger than the dipole-dipole repulsion expected theoretically as an asymptotic behavior for large .
Article Text
References (73)
- W. B. Russel, D. A. Saville, and W. R. Schowalter, Colloidal Dispersions (Cambridge University Press, Cambridge, 1995).
- J. N. Israelachvili, Intermolecular and Surface Forces (Academic Press, London, 1992).
- V. M. Mostepanenko and N. N. Trunov, The Casimir Effect and its Application (Clarendon Press, Oxford, 1997).
- P. Poulin, V. A. Raghunathan, P. Richetti, and D. Roux, J. Phys. II 4, 1557 (1994); V. A. Raghunathan, P. Richetti, and D. Roux, Langmuir 12, 3789 (1996); V. A. Raghunathan, P. Richetti, D. Roux, F. Nallet, and A. K. Sood, Mol. Cryst. Liq. Cryst. 288, 181 (1996); Langmuir 16, 4720 (2000).
- P. Poulin, H. Stark, T. C. Lubensky, and D. A. Weitz, Science 275, 1770 (1997).
- P. Poulin and D. A. Weitz, Phys. Rev. E 57, 626 (1998).
- P. Poulin, Curr. Opin. Colloid Interface Sci. 4, 66 (1999).
- P. Poulin, N. Francès, and O. Mondain-Monval, Phys. Rev. E 59, 4384 (1999).
- O. Mondain-Monval, J. C. Dedieu, T. Gulik-Krzywicki, and P. Poulin, Eur. Phys. J. B 12, 167 (1999).
- M. Zapotocky, L. Ramos, P. Poulin, T. C. Lubensky, and D. A. Weitz, Science 283, 209 (1999); L. Ramos, M. Zapotocky, T. C. Lubensky, and D. A. Weitz, Phys. Rev. E 66, 031711 (2002).
- S. P. Meeker, W. C.K. Poon, J. Crain, and E. M. Terentjev, Phys. Rev. E 61, R6083 (2000); V. J. Anderson, E. M. Terentjev, S. P. Meeker, J. Crain, and W. C.K. Poon, Eur. Phys. J. E 4, 11 (2001); V. J. Anderson and E. M. Terentjev, ibid. 4, 21 (2001).
- J.-C. Loudet, P. Barois, and P. Poulin, Nature (London) 407, 611 (2000); J. C. Loudet, P. Poulin, and P. Barois, Europhys. Lett. 54, 175 (2001).
- J. Yamamoto and H. Tanaka, Nature (London) 409, 321 (2001).
- V. G. Nazarenko, A. B. Nych, and B. I. Lev, Phys. Rev. Lett. 87, 075504 (2001).
- P. Cluzeau, V. Dolganov, P. Poulin, G. Joly, and H. T. Nguyen, Mol. Cryst. Liq. Cryst. 364, 381 (2001); P. Cluzeau, P. Poulin, G. Joly, and H. T. Nguyen, Phys. Rev. E 63, 031702 (2001); P. Cluzeau, G. Joly, H. T. Nguyen, and V. K. Dolganov, JETP Lett. 75, 482 (2002); 76, 351 (2002); P. Cluzeau, V. Bonnand, G. Joly, V. Dolganov, and H. T. Nguyen, Eur. Phys. J. E 10, 231 (2003).
- M. Mitov, C. Portet, C. Bourgerette, E. Snoeck, and M. Verelst, Nat. Mater. 1, 229 (2002).
- T. Bellini, M. Caggioni, N. A. Clark, F. Mantegazza, A. Maritan, and A. Pelizzola, Phys. Rev. Lett. 91, 085704 (2003).
- P. Poulin, V. Cabuil, and D. A. Weitz, Phys. Rev. Lett. 79, 4862 (1997).
- M. Yada, J. Yamamoto, and H. Yokoyama, Phys. Rev. Lett. (to be published); The Third International Symposium on Slow Dynamics in Complex Systems, Sendai, Japan, 2003, Poster Presentation (unpublished).
- S. L. Lopatnikov and V. A. Namiot, Zh. Eksp. Teor. Fiz. 25, 361 (1978) [Sov. Phys. JETP 48, 180 (1978)].
- S. Ramaswamy, R. Nityananda, V. A. Raghunathan, and J. Prost, Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 288, 175 (1996).
- R. W. Ruhwandl and E. M. Terentjev, Phys. Rev. E 55, 2958 (1997).
- T. C. Lubensky, D. Pettey, N. Currier, and H. Stark, Phys. Rev. E 57, 610 (1998).
- B. I. Lev and P. M. Tomchuk, Phys. Rev. E 59, 591 (1999); S. B. Chernyshuk, B. I. Lev, and H. Yokoyama, Sov. Phys. JETP 93, 760 (2001); B. I. Lev, S. B. Chernyshuk, P. M. Tomchuk, and H. Yokoyama, Phys. Rev. E 65, 021709 (2002).
- J. Fukuda, B. I. Lev, K. M. Aoki, and H. Yokoyama, Phys. Rev. E 66, 051711 (2002); Mol. Cryst. Liq. Cryst. (to be published); J. Fukuda, B. I. Lev, and H. Yokoyama, J. Phys.: Condens. Matter 15, 3841 (2003).
- M. S. Turner and P. Sens, Phys. Rev. E 55, R1275 (1997); P. Sens, M. S. Turner, and P. Pincus, ibid. 55, 4394 (1997); P. Sens and M. S. Turner, J. Phys. II 7, 1855 (1997); M. S. Turner and P. Sens, Phys. Rev. E 57, 823 (1998).
- J. Groenwold and G. H. Fredrickson, Eur. Phys. J. E 5, 171 (2001).
- C. D. Santangelo and R. D. Kamien, Phys. Rev. Lett. 91, 045506 (2003).
- R. Adhikari, Eur. Phys. J. E 9, 127 (2002).
- J. Fukuda, B. I. Lev, and H. Yokoyama, Phys. Rev. E 65, 031710 (2002).
- A. Borštnik, H. Stark, and S. Žumer, Phys. Rev. E 60, 4210 (1999); 61, 2831 (2000).
- P. Galatola and J.-B. Fournier, Phys. Rev. Lett. 86, 3915 (2001); J.-B. Fournier and P. Galatola, Phys. Rev. E 65, 032702 (2002); H. Stark, ibid. 66, 041705 (2002); P. Galatola, J.-B. Fournier, and H. Stark, ibid. 67, 031404 (2003).
- H. Stark, Phys. Rep. 351, 387 (2001).
- H. Stark, J. Stelzer, and R. Bernhard, Eur. Phys. J. B 10, 515 (1999).
- P. Patrício, M. Tasinkevych, and M. M. Telo da Gama, Eur. Phys. J. E 7, 117 (2002).
- M. Tasinkevych, N. M. Silvestre, P. Patrício, and M. M. Telo da Gama, Eur. Phys. J. E 9, 341 (2002).
- S. Grollau, E. B. Kim, O. Guzmán, N. L. Abbott, and J. J. de Pablo, J. Chem. Phys. 119, 2444 (2003).
- D. Andrienko, M. Tasinkevych, P. Patricío, M. P. Allen, and M. M. Telo da Gama, Phys. Rev. E 68, 051702 (2003).
- J. Fukuda, M. Yoneya, H. Yokoyama, and H. Stark, The Eighth IUMRS International Conference on Advanced Materials, Yokohama, Japan, 2003, Poster Presentation D11-12-P01 (unpublished); Colloids Surf., B (to be published).
- Y. Gu and N. L. Abbott, Phys. Rev. Lett. 85, 4719 (2000).
- N. D. Mermin, Rev. Mod. Phys. 51, 591 (1979).
- H.-R. Trebin, Adv. Phys. 31, 195 (1982).
- M. Kléman, Points, Lines, and Walls: in Liquid Crystals, Magnetic Systems, and Various Ordered Media (Wiley, New York, 1983).
- P. M. Chaikin and T. C. Lubensky, Principles of Condensed Matter Physics (Cambridge University Press, Cambridge, 1995).
- D. R. Nelson, Defects and Geometry in Condensed Matter Physics (Cambridge University Press, Cambridge, 2002).
- M. Kleman and O. D. Lavrentovich, Soft Matter Physics: An Introduction (Springer-Verlag, New York, 2003).
- S. Chandrasekhar, Liquid Crystals, 2nd ed. (Cambridge University Press, Cambridge, 1992).
- P. G. de Gennes and J. Prost, The Physics of Liquid Crystals, 2nd ed. (Oxford University Press, Oxford, 1993).
- D. Demus and L. Richter, Textures of Liquid Crystals (Verlag Chemie, New York, 1978).
- S. V. Burylov and Y. L. Raikher, Phys. Rev. E 50, 358 (1994).
- E. M. Terentjev, Phys. Rev. E 51, 1330 (1995).
- O. V. Kuksenok, R. W. Ruhwandl, S. V. Shiyanovskii, and E. M. Terentjev, Phys. Rev. E 54, 5198 (1996).
- S. V. Shiyanovskii and O. V. Kuksenok, Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 321, 45 (1998)
- H. Stark, Phys. Rev. E 66, 032701 (2002).
- R. W. Ruhwandl and E. M. Terentjev, Phys. Rev. E 56, 5561 (1997).
- H. Stark, Eur. Phys. J. B 10, 311 (1999).
- J. L. Billeter and R. A. Pelcovits, Phys. Rev. E 62, 711 (2000).
- D. Andrienko, G. Germano, and M. P. Allen, Phys. Rev. E 63, 041701 (2001).
- J. Fukuda and H. Yokoyama, Eur. Phys. J. E 4, 389 (2001).
- J. Fukuda, M. Yoneya, and H. Yokoyama, Phys. Rev. E 65, 041709 (2002).
- J. Fukuda, M. Yoneya, and H. Yokoyama, Mol. Cryst. Liq. Cryst. (to be published).
- J. Fukuda, H. Stark, M. Yoneya, and H. Yokoyama, J. Phys.: Condens. Matter (to be published).
- J. Fukuda, M. Yoneya, and H. Yokoyama, Eur. Phys. J. E13, 87 (2004).
- D. Andrienko, M. P. Allen, G. Skačej, and S. Žumer, Phys. Rev. E 65, 041702 (2002).
- S. Grollau, N. L. Abbott, and J.J. de Pablo, Phys. Rev. E 67, 011702 (2003).
- O. Guzmán, E. B. Kim, S. Grollau, N. L. Abbott, and J. J. de Pablo, Phys. Rev. Lett. 91, 235507 (2003).
- P. M. Morse and H. Feshbach, Methods of Theoretical Physics (McGraw-Hill, New York, 1953).
- J.-R. Roan and T. Kawakatsu, J. Chem. Phys. 116, 7283 (2002).
- W. H. Press, S. A. Teukolsky, W. T. Vetterling, and B. P. Flannery, Numerical Recipes in C, 2nd ed. (Cambridge University Press, Cambridge, 1992).
- P. C. Hohenberg and B. I. Halperin, Rev. Mod. Phys. 49, 435 (1977).
- J. Fukuda and H. Yokoyama, Phys. Rev. E 66, 012703 (2002).
- P. D. Olmsted and P. Goldbart, Phys. Rev. A 46, 4966 (1992).
- The derivative is calculated numerically using the following formula: . Here .