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Control of chaos in an electrochemical cell

P. Parmananda, P. Sherard, and R. W. Rollins

H. D. Dewald

  • Condensed Matter and Surface Sciences Program, Department of Physics Astronomy, Ohio University, Athens, Ohio 45701-2979

  • Department of Chemistry, Ohio University, Athens, Ohio 45701-2979

Phys. Rev. E 47, R3003(R) – Published 1 May, 1993

DOI: https://doi.org/10.1103/PhysRevE.47.R3003

Abstract

We report control of chemical chaos observed during the electrodissolution of a rotating copper disk in a sodium acetate–acetic acid buffer. An adaptation of a simple recursive proportional-feedback control strategy, generally applicable to systems well described by one-dimensional maps, was used to stablize the chaotic response of the system on an unstable period-1 orbit. The successive minima in the measured anodic current generated a return map that was used to characterize the dynamics, and the control algorithm prescribed small changes in the anodic potential to affect the control.

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