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HIGHLIGHTED ARTICLES

Modification and Control of Topological Insulator Surface States Using Surface Disorder

Vincent Sacksteder, Tomi Ohtsuki, and Koji Kobayashi

Phys. Rev. Applied 3, 064006 (2015) - Published 11 June, 2015

A topological insulator (TI) does not conduct electrons in its interior, but guarantees robust metallic conduction on its surface, with potential applications in spintronics and quantum computing. This study shows that by introducing a layer of strong surface disorder, and patterning that layer’s depth, a TI’s surface conduction can be focused, directed along particular channels, and switched—all of the requirements for a “topological integrated circuit”. The key is tuning the surface-disorder potential by electrically modulating the Fermi level.

Hysteresis from Multiscale Porosity: Modeling Water Sorption and Shrinkage in Cement Paste

Matthew B. Pinson, Enrico Masoero, Patrick A. Bonnaud, Hegoi Manzano, Qing Ji, Sidney Yip, Jeffrey J. Thomas, Martin Z. Bazant, Krystyn J. Van Vliet, and Hamlin M. Jennings

Phys. Rev. Applied 3, 064009 (2015) - Published 17 June, 2015

The importance of concrete and cement to civil infrastructure cannot be overstated, yet there are still surprising gaps in our knowledge of these systems, which are unexpectedly complex. One basic example is that cement paste shrinks when water is removed from its multiscale pore network, and swells when water is added, but the mechanism is unclear. In a complete reassessment of this phenomenon, the authors differentiate the physical behavior of water in the layered nanostructures of cement hydrates from that in larger gel and capillary pores, linking microstructure to macroscopic material properties.

Physical Origins of Thermal Properties of Cement Paste

Mohammad Javad Abdolhosseini Qomi, Franz-Josef Ulm, and Roland J.-M. Pellenq

Phys. Rev. Applied 3, 064010 (2015) - Published 17 June, 2015

Concrete is the most used human-made material on earth, the backbone of civil infrastructure, yet the link between the composition of cement paste and its thermophysical properties remains rather obscure. This multiscale study combines statistical physics and mean-field homogenization theory to unravel the relationship between the chemistry of the calcium silicate phases present in the paste and its macroscopic heat capacity and thermal conductivity. These results offer a robust physical basis for engineering thermal and acoustic isolation of buildings, and more durable ceramics and other construction materials.

ARTICLES

Elastic Valve Using Induced-Charge Electro-Osmosis

Hideyuki Sugioka

Phys. Rev. Applied 3, 064001 (2015) - Published 2 June, 2015

Biological functional systems generally have been optimized for high performance at low energy cost. Inspired by natural cilia, the authors propose an elastic valve based on induced-charge electro-osmotic flow, and simulate its outstanding performance. This biomimetic device would offer microfluidics applications a short closing time of 5–10 ms at low voltage, and a design that passively blocks reverse flow, reminiscent of the action in veins of the circulatory system.

Time-Resolved Mass Sensing of a Molecular Adsorbate Nonuniformly Distributed Along a Nanomechnical String

T. S. Biswas, Jin Xu, N. Miriyala, C. Doolin, T. Thundat, J. P. Davis, and K. S. D. Beach

Phys. Rev. Applied 3, 064002 (2015) - Published 3 June, 2015

Chip-based micromechanical devices, already used as compasses and accelerometers in smartphones, are being developed for molecular sensing applications, from point-of-care medical diagnostics to airport luggage screening. The vibrational frequency of a nanomechanical resonator changes when it adsorbs mass (molecules), but when the adsorption is not uniform, the proportionality constant connecting frequency to deposited mass is obscured. The authors solve this problem by taking time-dependent measurements of multiple frequencies, and in proof of principle accurately measure the molecular mass of the explosive RDX.

Benefits of Carrier-Pocket Anisotropy to Thermoelectric Performance: The Case of p-Type AgBiSe2

David S. Parker, Andrew F. May, and David J. Singh

Phys. Rev. Applied 3, 064003 (2015) - Published 5 June, 2015

Room-temperature thermoelectric applications have been impeded by a shortage of suitable materials. This study indicates that electronic anisotropy, in particular a one-dimensional feature of the Fermi surface, allows decoupling of the factors that largely determine electrical transport, elevating the dimensionless figure of merit ZT. The authors predict this electronic structure to occur specifically in the valence band of hexagonal AgBiSe2, but the concept is quite general and can guide the rational search for even better materials that will drive applications.

Impact of Heterostructure Design on Transport Properties in the Second Landau Level of In Situ Back-Gated Two-Dimensional Electron Gases

J. D. Watson, G. A. Csáthy, and M. J. Manfra

Phys. Rev. Applied 3, 064004 (2015) - Published 8 June, 2015

In condensed matter physics, the fractional quantum Hall effect is still keenly studied, particularly the ν=52 state, long believed to harbor exotic non-Abelian anyon quasiparticles that could be used for quantum computation. Such study, however, requires an ultrahigh-quality two-dimensional electron gas (2DEG) for a test bed. The authors show that careful design and device processing of the host semiconductor heterostructure yields a 2DEG whose density can be widely tuned while preserving a very strong ν=52 state, which to date has been a great challenge.

Formation of a Positive Fixed Charge at cSi(111)/aSi3N3.5:H Interfaces

L. E. Hintzsche, C. M. Fang, M. Marsman, M. W. P. E. Lamers, A. W. Weeber, and G. Kresse

Phys. Rev. Applied 3, 064005 (2015) - Published 11 June, 2015

A positive fixed charge at the interface between crystalline silicon and amorphous silicon nitride attracts electrons and repels holes. Although this phenomenon is extensively exploited in high-efficiency solar cells, its atomic-scale origin is not precisely understood. The authors’ high-throughput calculations allow a statistically meaningful analysis of many sample structures, relating the fixed charge to the abundance of K+ defects featuring threefold-coordinated Si at the interface. This understanding furthers the quest to improve solar-cell efficiency.

Modification and Control of Topological Insulator Surface States Using Surface Disorder

Vincent Sacksteder, Tomi Ohtsuki, and Koji Kobayashi

Phys. Rev. Applied 3, 064006 (2015) - Published 11 June, 2015

A topological insulator (TI) does not conduct electrons in its interior, but guarantees robust metallic conduction on its surface, with potential applications in spintronics and quantum computing. This study shows that by introducing a layer of strong surface disorder, and patterning that layer’s depth, a TI’s surface conduction can be focused, directed along particular channels, and switched—all of the requirements for a “topological integrated circuit”. The key is tuning the surface-disorder potential by electrically modulating the Fermi level.

Electrically Tunable Critically Coupled Terahertz Metamaterial Absorber Based on Nematic Liquid Crystals

Goran Isić, Borislav Vasić, Dimitrios C. Zografopoulos, Romeo Beccherelli, and Radoš Gajić

Phys. Rev. Applied 3, 064007 (2015) - Published 11 June, 2015

Technology to efficiently handle light in the terahertz range is sought for a wide range of applications, including nondestructive testing, medical diagnostics, and weapons detection. Liquid-crystal devices are cheap and promising, but currently suffer from high operating voltage and long response times. The authors exploit coupling between periodically arranged patch resonators and external fields to propose a low-voltage absorber whose reflectance can be modulated from nearly 0 to 90%, with switching times around 50 ms–a dramatic improvement over existing technology that stands to enable new, low-cost, highly tunable terahertz devices.

Analyzing Variability in Short-Channel Quantum Transport from Atomistic First Principles

Qing Shi, Hong Guo, Yu Zhu, and Lei Liu

Phys. Rev. Applied 3, 064008 (2015) - Published 12 June, 2015

At the nanoscale, random distribution of impurities causes pronounced device-to-device variability (DDV) in short-channel transistors. This study investigates quantum transport with multiple-impurity scattering in silicon nanoFETs as a function of channel length, doping concentration, and doping profile. The results reveal the microscopic physics of DDV and provide insight for rectifying it, to yield better electronics.

Hysteresis from Multiscale Porosity: Modeling Water Sorption and Shrinkage in Cement Paste

Matthew B. Pinson, Enrico Masoero, Patrick A. Bonnaud, Hegoi Manzano, Qing Ji, Sidney Yip, Jeffrey J. Thomas, Martin Z. Bazant, Krystyn J. Van Vliet, and Hamlin M. Jennings

Phys. Rev. Applied 3, 064009 (2015) - Published 17 June, 2015

The importance of concrete and cement to civil infrastructure cannot be overstated, yet there are still surprising gaps in our knowledge of these systems, which are unexpectedly complex. One basic example is that cement paste shrinks when water is removed from its multiscale pore network, and swells when water is added, but the mechanism is unclear. In a complete reassessment of this phenomenon, the authors differentiate the physical behavior of water in the layered nanostructures of cement hydrates from that in larger gel and capillary pores, linking microstructure to macroscopic material properties.

Physical Origins of Thermal Properties of Cement Paste

Mohammad Javad Abdolhosseini Qomi, Franz-Josef Ulm, and Roland J.-M. Pellenq

Phys. Rev. Applied 3, 064010 (2015) - Published 17 June, 2015

Concrete is the most used human-made material on earth, the backbone of civil infrastructure, yet the link between the composition of cement paste and its thermophysical properties remains rather obscure. This multiscale study combines statistical physics and mean-field homogenization theory to unravel the relationship between the chemistry of the calcium silicate phases present in the paste and its macroscopic heat capacity and thermal conductivity. These results offer a robust physical basis for engineering thermal and acoustic isolation of buildings, and more durable ceramics and other construction materials.

Molecular Oxygen as Charge-Compensating and Magnetic Centers in Anatase TiO2

Hungru Chen and James A. Dawson

Phys. Rev. Applied 3, 064011 (2015) - Published 18 June, 2015

Anatase TiO2 is of great interest for applications spanning photovoltaics, memristor electronics, and catalysis. Among its interesting properties is d0 ferromagnetism: Undoped samples can be intrinsically, strongly magnetic at room temperature, despite a nominally diamagnetic electronic structure. The authors’ refined calculations reveal that cation vacancies in TiO2 can yield molecular oxygen, which itself carries a magnetic moment and is probably the source of the phenomenon. This explanation may extend to other oxides, and the insight about these defects informs the processing and band-gap engineering of titania.

Coherent Subnanosecond Switching of Perpendicular Magnetization by the Fieldlike Spin-Orbit Torque without an External Magnetic Field

William Legrand, Rajagopalan Ramaswamy, Rahul Mishra, and Hyunsoo Yang

Phys. Rev. Applied 3, 064012 (2015) - Published 18 June, 2015

The recently discovered spin-orbit torque could be used to flip bits in spintronic devices. The authors investigate its less-studied component, the fieldlike torque, and find that with the help of this piece, there is no need for an external magnetic field to achieve the deterministic reversal of magnetization. In principle this solves one of the critical issues in spintronics, and is promising for applications in terms of speed and energy efficiency.

Ablation of Submicrometer Holes Using an Extreme-Ultraviolet Laser

Andrew K. Rossall, Valentin Aslanyan, Greg J. Tallents, Ilya Kuznetsov, Jorge J. Rocca, and Carmen S. Menoni

Phys. Rev. Applied 3, 064013 (2015) - Published 19 June, 2015

Advanced mesoscale devices require tight tolerances of very fine features. Laser ablation is widely used for this purpose, and extreme-ultraviolet (EUV) lasers in particular allow for a tighter focus and lower-temperature machining than traditional lasers. The authors perform simulations and experiments of laser ablation using an EUV laser, producing high-aspect-ratio mesoscale (100 nm—1µm) features with a high level of control over the ablation profile. This work provides an effective technique to investigate and promote capillary-discharge laser technology for industrial processes.

Frequency-Preserved Acoustic Diode Model with High Forward-Power-Transmission Rate

Chang Liu, Zongliang Du, Zhi Sun, Huajian Gao, and Xu Guo

Phys. Rev. Applied 3, 064014 (2015) - Published 19 June, 2015

Acoustic diodes (ADs) have applications ranging from medical imaging to nondestructive testing, but existing ADs change wave frequencies, often leading to poor efficiency. The authors propose a nonlinear AD that preserves frequencies with good forward power transmission, breaking the classical reciprocal-transmission law for linear devices. Its forward, reverse, and breakdown characteristics echo those of electrical diodes, hinting that designs from electronics could be used in acoustics.

Device Performance of the Mott Insulator LaVO3 as a Photovoltaic Material

Lingfei Wang, Yongfeng Li, Ashok Bera, Chun Ma, Feng Jin, Kaidi Yuan, Wanjian Yin, Adrian David, Wei Chen, Wenbin Wu, Wilfrid Prellier, Suhuai Wei, and Tom Wu

Phys. Rev. Applied 3, 064015 (2015) - Published 22 June, 2015

Finding solar absorbers that are chemically stable and made of abundant elements will promote the improvement of photovoltaic technology. Perhaps surprisingly, the prototypical Mott insulator LaVO3 is promising in this arena, as it strongly absorbs visible light and has a suitable band gap. The authors study the optical and transport properties of this material in a working device, discussing the advantages and challenges of using a Mott insulator, and showing the way for further solar cells based on strongly correlated electron systems.

Control of Lasing from Bloch States in Microcavity Photonic Wires via Selective Excitation and Gain

A. Mischok, R. Brückner, H. Fröb, V. G. Lyssenko, K. Leo, and A. A. Zakhidov

Phys. Rev. Applied 3, 064016 (2015) - Published 22 June, 2015

Polariton lasers, which provide low-threshold lasing, are sought as energy-efficient light sources for photonic devices. The authors create deep photonic wires in organic microcavities, altering their angle-dependent emission to facilitate polariton dispersions with coexisting localized and extended states. Selective excitation precisely controls the build-up of coherent modes, providing tunable lasing on the microscale. These experiments are performed at room temperature under ambient conditions, and thus are clearly adaptable to real-world applications.

Enhanced Thermoelectric Performance of Hybrid Nanoparticle–Single-Molecule Junctions

Elinor Zerah-Harush and Yonatan Dubi

Phys. Rev. Applied 3, 064017 (2015) - Published 23 June, 2015

Molecular junctions have been predicted to be excellent thermoelectric energy converters, but actual devices show poor efficiency and low thermopower. The authors’ model indicates that a different sort of hybrid junction, between a single molecule and a semiconducting nanoparticle, could offer 1000 times the performance, and furthermore would be tunable, offering a pathway to efficient recovery of energy at the nanoscale.

Wide Compositional Range In Situ Electric Field Investigations on Lead-Free Ba(Zr0.2Ti0.8)O3x(Ba0.7Ca0.3)TiO3 Piezoceramic

M. Zakhozheva, L. A. Schmitt, M. Acosta, H. Guo, W. Jo, R. Schierholz, H.-J. Kleebe, and X. Tan

Phys. Rev. Applied 3, 064018 (2015) - Published 24 June, 2015

Applications ranging from microphones to AFM transducers exploit the interplay between mechanical stress and electric field arising from structural transitions in certain perovskite oxides. The classic material contains lead, however, and efficient, environmentally friendly alternatives have long been sought. The authors use a challenging technique to visualize the real-time microstructural evolution of a lead-free ferroelectric system, and the multidomain states and transitions they find are expected to inform the search for additional systems, as well as the applications that will rely on them.

Broadband Acoustic Cloaking within an Arbitrary Hard Cavity

Weiwei Kan, Victor M. García-Chocano, F. Cervera, Bin Liang, Xin-ye Zou, Lei-lei Yin, Jianchun Cheng, and José Sánchez-Dehesa

Phys. Rev. Applied 3, 064019 (2015) - Published 26 June, 2015

Concepts from optics aimed at creating “invisibility cloaks” are being extended to acoustics for soundproofing and stealth technology, with the same goal of passing waves around an object with no perceptible perturbation. The authors employ transformation acoustics to design and demonstrate a broadband, three-dimensional cloak that renders an object in an open cavity with hard boundaries nearly undetectable. Their actual cloak is an acoustic metamaterial made simply of stacked sheets of common acrylic plastic, with millimeter-scale features.

Electronic Structure of Polar and Semipolar (112¯2)-Oriented Nitride Dot-in-a-Well Systems

S. Schulz and O. Marquardt

Phys. Rev. Applied 3, 064020 (2015) - Published 30 June, 2015

Heterostructures of group-III nitride semiconductors attract considerable interest for optoelectronics applications requiring wavelengths anywhere from infrared to ultraviolet. The authors analyze the electronic structure of nitride-based quantum dots placed inside a nitride-based quantum well, grown along different crystallographic directions. Certain orientations offer reduced intrinsic electrostatic fields and seem promising for devices, with improved carrier capture and radiative-recombination rates.

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