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Impact of Interfaces on Photoluminescence Efficiency of High-Indium-Content (In,Ga)N Quantum Wells

P. Wolny1,*, H. Turski1, G. Muziol1, M. Sawicka1, J. Smalc-Koziorowska1, J. Moneta1, M. Hajdel1, A. Feduniewicz-Żmuda1, S. Grzanka1 et al.

R. Kudrawiec2 and C. Skierbiszewski1

  • 1Institute of High Pressure Physics, Polish Academy of Sciences, Warsaw 01-142, Poland
  • 2Department of Semiconductor Materials Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

  • *wolny@unipress.waw.pl
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Phys. Rev. Applied 19, 014044 – Published 17 January, 2023

DOI: https://doi.org/10.1103/PhysRevApplied.19.014044

Abstract

(In,Ga)N-based light-emitting diodes (LEDs) are known to suffer from low electron-hole wave-function overlap due to a high piezoelectric field. Staggered (In,Ga)N quantum wells (QWs) are proposed to increase the wave-function overlap and improve the efficiency of LEDs, especially for long-wavelength emitters. In this work, we show evidence that the growth of staggered QWs by plasma-assisted molecular beam epitaxy has another beneficial effect, as it allows a reduction in the formation of defects, responsible for nonradiative Shockley-Read-Hall recombination, at the bottom interface of the QW. Staggered QWs comprised an (In,Ga)N layer of an intermediate In content between the barrier and the QW. We show that insertion of such a layer results in a significant increase of the luminescence intensity, even if the calculated wave-function overlap drops. We study the dependence of the thickness of such an intermediate-In-content layer on photoluminescence intensity behavior. Staggered QWs exhibit increased cathodoluminescence homogeneity that is a fingerprint of a lower density of defects, in contrast to standard QWs for which a high density of dark spots is observed in QW-emission mapping. Transmission electron microscopy of standard QWs reveals the formation of basal-plane stacking faults and voids that can result from vacancy aggregation. A stepwise increase of the In content in staggered QWs prevents the formation of point defects and results in an increased luminescence efficiency. The In-composition difference between the barrier and the well is, therefore, a key parameter to control the formation of point defects in the high-In-content QWs, influencing the luminescence efficiency. Characteristics of the cyan laser diode (LD) utilizing staggered QWs are presented.

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Phys. Rev. Applied 19, 014044– Published 17 January, 2023
  • Received 28 June 2022
  • Revised 26 September 2022
  • Accepted 23 November 2022
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