- Access by Xinjiang University
Colloquium: Quantum fluctuation relations: Foundations and applications
Rev. Mod. Phys. 83, 771 – Published 6 July, 2011Erratum Rev. Mod. Phys. 83, 1653 (2011)
DOI: https://doi.org/10.1103/RevModPhys.83.771
Abstract
Two fundamental ingredients play a decisive role in the foundation of fluctuation relations: the principle of microreversibility and the fact that thermal equilibrium is described by the Gibbs canonical ensemble. Building on these two pillars the reader is guided through a self-contained exposition of the theory and applications of quantum fluctuation relations. These are exact results that constitute the fulcrum of the recent development of nonequilibrium thermodynamics beyond the linear response regime. The material is organized in a way that emphasizes the historical connection between quantum fluctuation relations and (non)linear response theory. A number of fundamental issues are clarified which were not completely settled in the prior literature. The main focus is on (i) work fluctuation relations for transiently driven closed or open quantum systems, and (ii) on fluctuation relations for heat and matter exchange in quantum transport settings. Recently performed and proposed experimental applications are presented and discussed.
Erratum
Erratum: Colloquium: Quantum fluctuation relations: Foundations and applications [Rev. Mod. Phys. 83, 771 (2011)]
Article Text
References (133)
- Adib, A. B., 2005, “Entropy and density of states from isoenergetic nonequilibrium processes,” Phys. Rev. E 71, 056128.
- Adib, A. B., 2009, “Comment on ’On the Crooks fluctuation theorem and the Jarzynski equality,’ ” [J. Chem. Phys. 129, 091101 (2008)], J. Chem. Phys. 130, 247101.
- Allahverdyan, A. E., and T. M. Nieuwenhuizen, 2005, “Fluctuations of work from quantum subensembles: The case against quantum work-fluctuation theorems,” Phys. Rev. E 71, 066102.
- Andrieux, D., and P. Gaspard, 2008, “Quantum Work Relations and Response Theory,” Phys. Rev. Lett. 100, 230404.
- Andrieux, D., P. Gaspard, T. Monnai, and S. Tasaki, 2009, “The fluctuation theorem for currents in open quantum systems,” New J. Phys. 11, 043014.
- Anetsberger, G., O. Arcizet, Q. P. Unterreithmeier, R. Rivière, A. Schliesser, E. M. Weig, J. P. Kotthaus, and T. J. Kippenberg, 2009, “Near-field cavity optomechanics with nanomechanical oscillators,” Nature Phys. 5, 909.
- Bernard, W., and H. B. Callen, 1959, “Irreversible Thermodynamics of Nonlinear Processes and Noise in Driven Systems,” Rev. Mod. Phys. 31, 1017.
- Bochkov, G. N., and Y. E. Kuzovlev, 1977, “General theory of thermal fluctuations in nonlinear systems,” Zh. Eksp. Teor. Fiz. 72, 238 [Sov. Phys. JETP 45, 125 (1977)].
- Bochkov, G. N., and Y. E. Kuzovlev, 1978, “Nonlinear stochastic models of oscillator systems,” Radiophys. Quantum Electron. 21, 1019.
- Bochkov, G. N., and Y. E. Kuzovlev, 1979, “Fluctuation-dissipation relations for nonequilibrium processes in open systems,” Zh. Eksp. Teor. Fiz. 76, 1071 [Sov. Phys. JETP 49, 543 (1979)].
- Bochkov, G. N., and Y. E. Kuzovlev, 1981a, “Nonlinear fluctuation-dissipation relations and stochastic models in nonequilibrium thermodynamics I. Generalized fluctuation-dissipation theorem,” Physica (Amsterdam) 106A, 443.
- Bochkov, G. N., and Y. E. Kuzovlev, 1981b, “Nonlinear fluctuation-dissipation relations and stochastic models in nonequilibrium thermodynamics II. Kinetic potential and variational principles for nonlinear irreversible processes,” Physica (Amsterdam) 106A, 480.
- Caldeira, A. O., and A. J. Leggett, 1983, “Quantum tunnelling in a dissipative system,” Ann. Phys. (N.Y.) 149, 374.
- Callen, H. B., and T. A. Welton, 1951, “Irreversibility and Generalized Noise,” Phys. Rev. 83, 34.
- Campisi, M., 2008, “Increase of Boltzmann entropy in a quantum forced harmonic oscillator,” Phys. Rev. E 78, 051123.
- Campisi, M., P. Talkner, and P. Hänggi, 2009a, “Fluctuation Theorem for Arbitrary Open Quantum Systems,” Phys. Rev. Lett. 102, 210401.
- Campisi, M., P. Talkner, and P. Hänggi, 2009b, “Thermodynamics and fluctuation theorems for a strongly coupled open quantum system: an exactly solvable case,” J. Phys. A 42, 392002.
- Campisi, M., P. Talkner, and P. Hänggi, 2010a, “Fluctuation theorems for continuously monitored quantum fluxes,” Phys. Rev. Lett. 105, 140601.
- Campisi, M., P. Talkner, and P. Hänggi, 2011a, “Quantum Bochkov-Kuzovlev Work Fluctuation Theorems,” Phil. Trans. R. Soc. A 369, 291.
- Campisi, M., P. Talkner, and P. Hänggi, 2011b, “Influence of measurements on the statistics of work performed on a quantum system,” Phys. Rev. E 83, 041114.
- Campisi, M., D. Zueco, and P. Talkner, 2010, “Thermodynamic anomalies in open quantum systems: Strong coupling effects in the isotropic model,” Chem. Phys. 375, 187.
- Casimir, H. B. G., 1945, “On Onsager’s Principle of Microscopic Reversibility,” Rev. Mod. Phys. 17, 343.
- Chen, L. Y., 2008a, “Nonequilibrium fluctuation-dissipation theorem of Brownian dynamics,” J. Chem. Phys. 129, 144113.
- Chen, L. Y., 2008b, “On the Crooks fluctuation theorem and the Jarzynski equality,” J. Chem. Phys. 129, 091101.
- Chen, L. Y., 2009, Response to “Comment on ‘On the Crooks fluctuation theorem and the Jaraynski equality’ and ’Nonequilibrium fluctuation dissipation theorem of Brownian dynamics’,” [J. Chem. Phys. 130, 107101 (2009)] J. Chem. Phys. 130, 107102.
- Cleuren, B, C. Van den Broeck, and R. Kawai, 2006, “Fluctuation and Dissipation of Work in a Joule Experiment,” Phys. Rev. Lett. 96, 050601.
- Cohen-Tannoudji, C., B. Diu, and F. Laloë, 1977, Quantum Mechanics (Wiley, New York), Vol. 1, p. 318.
- Collin, D., F. Ritort, C. Jarzynski, S. B. Smith, I. Tinoco, and C. Bustamante, 2005, “Verification of the Crooks fluctuation theorem and recovery of RNA folding free energies,” Nature (London) 437, 231.
- Crooks, G. E., 1999, “Entropy production fluctuation theorem and the nonequilibrium work relation for free energy differences,” Phys. Rev. E 60, 2721.
- Crooks, G. E., 2008, “On the Jarzynski relation for dissipative quantum dynamics,” J. Stat. Mech. P10023.
- Crooks, G. E., 2009, Comment regarding “On the Crooks fluctuation theorem and the Jarzynski equality” [J. Chem. Phys. 129, 091101 (2008)] and “Nonequilibrium fluctuation-dissipation theorem of Brownian dynamics” [J. Chem. Phys. 129, 144113 (2008)]; J. Chem. Phys. 130, 107101.
- Deffner, S., O. Abah, and E. Lutz, 2010, “Quantum work statistics of linear and nonlinear parametric oscillators,” Chem. Phys. 375, 200.
- Deffner, S., and E. Lutz, 2008, “Nonequilibrium work distribution of a quantum harmonic oscillator,” Phys. Rev. E 77, 021128.
- Deffner, S., and E. Lutz, 2010, “Generalized Clausius Inequality for Nonequilibrium Quantum Processes,” Phys. Rev. Lett. 105, 170402.
- de Groot, S. R., and P. Mazur, 1984, Non-equilibrium Thermodynamics (Dover, New York).
- de Roeck, W., and C. Maes, 2004, “Quantum version of free-energy–irreversible-work relations,” Phys. Rev. E 69, 026115.
- Dittrich, T., P. Hänggi, G.-L. Ingold, B. Kramer, G. Schön, and W. Zwerger, 1998, Quantum Transport and Dissipation (Wiley-VCH, Weinheim).
- Douarche, F., S. Ciliberto, A. Petrosyan, and I. Rabbiosi, 2005, “An experimental test of the Jarzynski equality in a mechanical experiment,” Europhys. Lett. 70, 593.
- Efremov, G. F., 1969, “A fluctuation dissipation theorem for nonlinear media,” Zh. Eksp. Teor. Fiz. 55, 2322 [Sov. Phys. JETP 28, 1232 (1969)].
- Einstein, A., 1905, “Über die von der molekularkinetischen Theorie der Wärme geforderte Bewegung von in ruhenden Flüssigkeiten suspendierten Teilchen,” Ann. Phys. (Leipzig) 322, 549, translated into English in Einstein, 1926.
- Einstein, A., 1906a, “Eine neue Bestimmung der Moleküldimensionen,” Ann. Phys. (Leipzig) 324, 289, translated into English in Einstein, 1926.
- Einstein, A., 1906b, “Zur Theorie der Brownschen Bewegung,” Ann. Phys. (Leipzig) 324, 371, translated into English in Einstein, 1926.
- Einstein, A., 1926, Investigations on the Theory of Brownian Movement (Methuen, London), reprinted by Dover, New York, 1956.
- Esposito, M., U. Harbola, and S. Mukamel, 2009, “Nonequilibrium fluctuations, fluctuation theorems, and counting statistics in quantum systems,” Rev. Mod. Phys. 81, 1665.
- Esposito, M., and S. Mukamel, 2006, “Fluctuation theorems for quantum master equations,” Phys. Rev. E 73, 046129.
- Evans, D. J., E. G. D. Cohen, and G. P. Morriss, 1993, “Probability of second law violations in shearing steady states,” Phys. Rev. Lett. 71, 2401.
- Feynman, R. P., and J. F. L. Vernon, 1963, “The theory of a general quantum system interacting with a linear dissipative system,” Ann. Phys. (N.Y.) 24, 118.
- Ford, G. W., J. T. Lewis, and R. F. O’Connell, 1985, “Quantum oscillator in a blackbody radiation field,” Phys. Rev. Lett. 55, 2273.
- Fujisawa, T., T. Hayashi, R. Tomita, and Y. Hirayama, 2006, “Bidirectional counting of single electrons,” Science 312, 1634.
- Gallavotti, G., and E. G. D. Cohen, 1995, “Dynamical Ensembles in Nonequilibrium Statistical Mechanics,” Phys. Rev. Lett. 74, 2694.
- Grabert, H., P. Schramm, and G.-L. Ingold, 1988, “Quantum Brownian motion: The functional integral approach,” Phys. Rep. 168, 115.
- Grabert, H., U. Weiss, and P. Talkner, 1984, “Quantum theory of the damped harmonic oscillator,” Z. Phys. B 55, 87.
- Green, M. S., 1952, “Markoff Random Processes and the Statistical Mechanics of Time-Dependent Phenomena,” J. Chem. Phys. 20, 1281.
- Green, M. S., 1954, “Markov Random Processes and the Statistical Mechanics of Time-Dependent Phenomena. II. Irreversible Processes in Fluids,” J. Chem. Phys. 22, 398.
- Hahn, A. M., and H. Then, 2009, “Using bijective maps to improve free-energy estimates,” Phys. Rev. E 79, 011113.
- Hahn, A. M., and H. Then, 2010, “Measuring the convergence of Monte Carlo free-energy calculations,” Phys. Rev. E 81, 041117.
- Hänggi, P., 1978, “Stochastic Processes II: Response theory and fluctuation theorems,” Helv. Phys. Acta 51, 202.
- Hänggi, P., 1982, “Nonlinear fluctuations: The problem of deterministic limit and reconstruction of stochastic dynamics,” Phys. Rev. A 25, 1130.
- Hänggi, P., and G.-L. Ingold, 2006, “Quantum Brownian motion and the third law of thermodynamics,” Acta Phys. Pol. B 37, 1537 [http://www.actaphys.uj.edu.pl/vol37/pdf/v37p1537.pdf].
- Hänggi, P., and G. Ingold, 2005, “Fundamental aspects of quantum Brownian motion,” Chaos 15, 026105.
- Hänggi, P., and H. Thomas, 1982, “Stochastic processes: Time evolution, symmetries and linear response,” Phys. Rep. 88, 207.
- Hide, J., and V. Vedral, 2010, “Detecting entanglement with Jarzynski’s equality,” Phys. Rev. A 81, 062303.
- Hofheinz, M., et al., 2009, “Synthesizing arbitrary quantum states in a superconducting resonator,” Nature (London) 459, 546.
- Hofheinz, M., E. M. Weig, M. Ansmann, R. C. Bialczak, E. Lucero, M. Neeley, A. D. O’Connell, H. Wang, J. M. Martinis, and A. N. Cleland, 2008, “Generation of Fock states in a superconducting quantum circuit,” Nature (London) 454, 310.
- Hörhammer, C., and H. Büttner, 2008, “Information and Entropy in Quantum Brownian Motion Thermodynamic Entropy versus von Neumann Entropy,” J. Stat. Phys. 133, 1161.
- Horowitz, J., and C. Jarzynski, 2008, Comment on “Failure of the work-Hamiltonian connection for free-energy calculations,” Phys. Rev. Lett. 101, 098901.
- Horowitz, J., and C. Jarzynski, 2007, “Comparison of work fluctuation relations,” J. Stat. Mech. P11002.
- Huber, G., F. Schmidt-Kaler, S. Deffner, and E. Lutz, 2008, “Employing trapped cold ions to verify the quantum Jarzynski equality,” Phys. Rev. Lett. 101, 070403.
- Husimi, K., 1953, “Miscellanea in Elementary Quantum Mechanics, I,” Prog. Theor. Phys. 9, 238.
- Ingold, G.-L., 2002 Lect. Notes Phys. 611, 1.
- Jarzynski, C., 1997, “Nonequilibrium equality for free energy differences,” Phys. Rev. Lett. 78, 2690.
- Jarzynski, C., 2000, “Hamiltonian derivation of a detailed fluctuation theorem,” J. Stat. Phys. 98, 77.
- Jarzynski, C., 2002, “Targeted free energy perturbation,” Phys. Rev. E 65, 046122.
- Jarzynski, C., 2007, “Comparison of far-from-equilibrium work relations,” C.R. Physique 8, 495.
- Jarzynski, C., 2008, “Nonequilibrium work relations: foundations and applications,” Eur. Phys. J. B 64, 331.
- Jarzynski, C., 2011, “Equalities and inequalities: Irreversibility and the second law of thermodynamics at the nanoscale,” Annu. Rev. Condens. Matter Phys. 2, 329.
- Jarzynski, C., 2004, “Nonequilibrium work theorem for a system strongly coupled to a thermal environment,” J. Stat. Mech. P09005.
- Jarzynski, C., and D. K. Wójcik, 2004, “Classical and quantum fluctuation theorems for heat exchange,” Phys. Rev. Lett. 92, 230602.
- Johnson, J. B., 1928, “Thermal agitation of electricity in conductors,” Phys. Rev. 32, 97.
- Katsuda, H., and M. Ohzeki, 2011, “Jarzynski Equality for an Energy-Controlled System,” J. Phys. Soc. Jpn. 80, 045003.
- Kawai, R., J. M. R. Parrondo, and C. V. den Broeck, 2007, “Dissipation: The Phase-Space Perspective,” Phys. Rev. Lett. 98, 080602.
- Khinchin, A., 1949, Mathematical foundations of statistical mechanics (Dover, New York).
- Kippenberg, T. J., and K. J. Vahala, 2008, “Cavity optomechanics: Back-action at the mesoscale,” Science 321, 1172.
- Kobe, D. H., 1981, “Gauge-invariant classical Hamiltonian formulation of the electrodynamics of nonrelativistic particles,” Am. J. Phys. 49, 581.
- Kubo, R., 1957, “Statistical-mechanical theory of irreversible processes. I,” J. Phys. Soc. Jpn. 12, 570.
- Kurchan, J., 2000, “A quantum fluctuation theorem,” arXiv:cond-mat/0007360.
- LaHaye, M. D., O. Buu, B. Camarota, and K. C. Schwab, 2004, “Approaching the Quantum Limit of a Nanomechanical Resonator,” Science 304, 74.
- Liphardt, J., S. Dumont, S. B. Smith, I. Tinoco, and C. Bustamante, 2002, “Equilibrium information from nonequilibrium measurements in an experimental test of Jarzynski’s equality,” Science 296, 1832.
- Marconi, U. M. B., A. Puglisi, L. Rondoni, and A. Vulpiani, 2008, “Fluctuation-dissipation: Response theory in statistical physics,” Phys. Rep. 461, 111.
- Maruyama, K., F. Nori, and V. Vedral, 2009, “Colloquium: The physics of Maxwell’s demon and information,” Rev. Mod. Phys. 81, 1.
- Messiah, A., 1962, Quantum Mechanics (North-Holland, Amsterdam).
- Minh, D. D. L., and A. B. Adib, 2008, “Optimized free energies from bidirectional single-molecule force spectroscopy,” Phys. Rev. Lett. 100, 180602.
- Morikuni, Y., and H. Tasaki, 2010, “Quantum Jarzynski-Sagawa-Ueda relations,” J. Stat. Phys. 143, 1.
- Mukamel, S., 2003, “Quantum extension of the Jarzynski relation: Analogy with stochastic dephasing,” Phys. Rev. Lett. 90, 170604.
- Nakamura, S., et al., 2010, “Nonequilibrium fluctuation relations in a quantum coherent conductor,” Phys. Rev. Lett. 104, 080602.
- Nakamura, S., et al., 2011, “Fluctuation Theorem and Microreversibility in a Quantum Coherent Conductor,” Phys. Rev. B 83, 155431.
- Nieuwenhuizen, T. M., and A. E. Allahverdyan, 2002, “Statistical thermodynamics of quantum Brownian motion: Construction of perpetuum mobile of the second kind,” Phys. Rev. E 66, 036102.
- Nyquist, H., 1928, “Thermal agitation of electric charge in conductors,” Phys. Rev. 32, 110.
- O’Connell, A. D., et al., 2010, “Quantum ground state and single-phonon control of a mechanical resonator,” Nature (London) 464, 697.
- Ohzeki, M., 2010, “Quantum Annealing with the Jarzynski Equality,” Phys. Rev. Lett. 105, 050401.
- Onsager, L., 1931a, “Reciprocal relations in irreversible processes. I.,” Phys. Rev. 37, 405.
- Onsager, L., 1931b, “Reciprocal relations in irreversible processes. II.,” Phys. Rev. 38, 2265.
- Peliti, L., 2008a, Comment on “Failure of the Work-Hamiltonian Connection for Free-Energy Calculations,” Phys. Rev. Lett. 101, 098903.
- Peliti, L., 2008b, “On the work-Hamiltonian connection in manipulated systems,” J. Stat. Mech. P05002.
- Piechocinska, B., 2000, “Information erasure,” Phys. Rev. A 61, 062314.
- Prost, J., J.-F. Joanny, and J. M. R. Parrondo, 2009, “Generalized Fluctuation-Dissipation Theorem for Steady-State Systems,” Phys. Rev. Lett. 103, 090601.
- Ren, J., P. Hänggi, and B. Li, 2010, “Berry-Phase-Induced Heat Pumping and Its Impact on the Fluctuation Theorem,” Phys. Rev. Lett. 104, 170601.
- Rondoni, L., and C. Mejía-Monasterio, 2007, “Fluctuations in nonequilibrium statistical mechanics: models, mathematical theory, physical mechanisms,” Nonlinearity 20, R1.
- Sagawa, T., and M. Ueda, 2010, “Generalized Jarzynski Equality under Nonequilibrium Feedback Control,” Phys. Rev. Lett. 104, 090602.
- Saito, K., and A. Dhar, 2007, “Fluctuation Theorem in Quantum Heat Conduction,” Phys. Rev. Lett. 99, 180601.
- Saito, K., and Y. Utsumi, 2008, “Symmetry in full counting statistics, fluctuation theorem, and relations among nonlinear transport coefficients in the presence of a magnetic field,” Phys. Rev. B 78, 115429.
- Schleich, W. P., 2001, Quantum Optics in Phase Space (Wiley-VCH, Berlin).
- Schulz, S. A., U. Poschinger, F. Ziesel, and F. Schmidt-Kaler, 2008, “Sideband cooling and coherent dynamics in a microchip multi-segmented ion trap,” New J. Phys. 10, 045007.
- Seifert, U., 2008, “Stochastic thermodynamics: Principles and perspectives,” Eur. Phys. J. B 64, 423.
- Stratonovich, R. L., 1992, Nonlinear Nonequilibrium Thermodynamics I: linear and Nonlinear Fluctuation-dissipation Theorems, Springer Series in Synergetics Vol. 57 (Springer-Verlag, Berlin).
- Stratonovich, R. L., 1994, Nonlinear Nonequilibrium Thermodynamics II: Advanced Theory, Springer Series in Synergetics Vol. 59 (Springer-Verlag, Berlin).
- Sutherland, W., 1902, “Ionization, ionic velocities, and atomic sizes,” Philos. Mag. 3, 161.
- Sutherland, W., 1905, “Dynamical theory of diffusion for non-electrolytes and the molecular mass of albumin,” Philos. Mag. 9, 781.
- Talkner, P., P. S. Burada, and P. Hänggi, 2008, “Statistics of work performed on a forced quantum oscillator,” Phys. Rev. E 78, 011115.
- Talkner, P., P. S. Burada, and P. Hänggi, 2009, “Erratum: Statistics of work performed on a forced quantum oscillator” [Phys. Rev. E 78, 011115 (2008)], Phys. Rev. E 79, 039902(E).
- Talkner, P., M. Campisi, and P. Hänggi, 2009, “Fluctuation theorems in driven open quantum systems,” J. Stat. Mech. P02025.
- Talkner, P., and P. Hänggi, 2007, “The Tasaki-Crooks quantum fluctuation theorem,” J. Phys. A 40, F569.
- Talkner, P., P. Hänggi, and M. Morillo, 2008, “Microcanonical quantum fluctuation theorems,” Phys. Rev. E 77, 051131.
- Talkner, P., E. Lutz, and P. Hänggi, 2007, “Fluctuation theorems: Work is not an observable,” Phys. Rev. E 75, 050102.
- Tasaki, H., 2000, “Jarzynski relations for quantum systems and some applications,” arXiv:cond-mat/0009244.
- Utsumi, Y., D. S. Golubev, M. Marthaler, K. Saito, T. Fujisawa, and G. Schön, 2010, “Bidirectional single-electron counting and the fluctuation theorem,” Phys. Rev. B 81, 125331.
- Vaikuntanathan, S., and C. Jarzynski, 2008, “Escorted free energy simulations: Improving convergence by reducing dissipation,” Phys. Rev. Lett. 100, 190601.
- Vedral, V., 2002, “The role of relative entropy in quantum information theory,” Rev. Mod. Phys. 74, 197.
- Vilar, J. M. G., and J. M. Rubi, 2008a, Comment on “Failure of the work-Hamiltonian connection for free-energy calculations–Reply,” Phys. Rev. Lett. 101, 098902.
- Vilar, J. M. G., and J. M. Rubi, 2008b, Comment on “Failure of the work-Hamiltonian connection for free-energy calculations”–Reply,” Phys. Rev. Lett. 101, 098904.
- Vilar, J. M. G., and J. M. Rubi, 2008c, “Failure of the work-Hamiltonian connection for free-energy calculations,” Phys. Rev. Lett. 100, 020601.
- Yukawa, S., 2000, “A quantum analogue of the Jarzynski equality,” J. Phys. Soc. Jpn. 69, 2367.
- Zimanyi, E. N., and R. J. Silbey, 2009, “The work-Hamiltonian connection and the usefulness of the Jarzynski equality for free energy calculations,” J. Chem. Phys. 130, 171102.