Export citation

Export citation

Choose format for download:

Download Citation
  • Access by Xinjiang University

Colloquium: Reactive plasmas as a versatile nanofabrication tool

K. Ostrikov*

K. Ostrikov*

  • School of Physics, The University of Sydney, Sydney NSW 2006, Australia

  • *Also at: Plasma Sources and Applications Center, NIE, Nanyang Technological University, 637616 Singapore. Electronic address: K.Ostrikov@physics.usyd.edu.au

Rev. Mod. Phys. 77, 489 – Published 22 June, 2005

DOI: https://doi.org/10.1103/RevModPhys.77.489

Abstract

The underlying physics of the application of low-temperature, low-pressure reactive plasmas in various nanoassembly processes is described. From the viewpoint of the “cause and effect” approach, this Colloquium focuses on the benefits and challenges of using plasma-based systems in nanofabrication of nanostructured silicon films, low-dimensional semiconducting quantum structures, ordered carbon nanotip arrays, highly crystalline TiO2 coatings, and nanostructured hydroxyapatite bioceramics. Other examples and future prospects of plasma-aided nanofabrication are also discussed.

Article Text

References (132)

  1. American Society for Testing and Materials (ASTM), 2003, Standard Specification for Composition of Hydroxyapatite for Surgical Implants (ASTM, New York), F1185-03; see also http://www.astm.org
  2. Arnault, C., and X. Devaux, 2004, J. Mater. Sci. Technol. 20, 63.
  3. Bapat, A., C. R. Perrey, S. A. Campbell, C. B. Carter, and U. Kortshagen, 2003, J. Appl. Phys. 94, 1969.
  4. Barnes, M. C., A. R. Gerson, S. Kumar, and N. M. Hwang, 2003, Thin Solid Films 436, 181.
  5. Barnes, M. C., A. R. Gerson, S. Kumar, and N. M. Hwang, 2004, Thin Solid Films 446, 29.
  6. Barnes, M. C., S. Kumar, L. Green, N. M. Hwang, and A. R. Gerson, 2005, Surf. Coat. Technol. 190, 321.
  7. Baron, T., P. Gentile, N. Magnea, and P. Mur, 2001, Appl. Phys. Lett. 79, 1175.
  8. Bethune, D. S., C. H. Kiang, M. S. DeVries, G. Gorman, R. Savoy, and R. Beyers, 1993, Nature (London) 363, 605.
  9. Bhandarkar, U. V., M. T. Swihart, S. L. Girshik, and U. Kortshagen, 2000, J. Phys. D 33, 2731.
  10. Boufendi, L., W. Stoffels, and E. Stoffels, 1999, in Dusty Plasmas: Physics, Chemistry and Technological Impacts in Plasma Processing, edited by A. Bouchoule (Wiley, New York), p. 181.
  11. Bower, C., W. Zhu, S. Jin, and O. Zhou, 2000, Appl. Phys. Lett. 77, 830.
  12. Chaabane, N., A. V. Kharchenko, H. Vach, and P. Roca i Cabarrocas, 2003, New J. Phys. 3, 37.1.
  13. Chaabane, N., P. Roca i Cabarrocas, and H. Vach, 2004, J. Non-Cryst. Solids 338-340, 51.
  14. Chau, J. L. H., M. K. Hsu, C. C. Hsieh, and C. C. Kao, 2005, Mater. Lett. 59, 905.
  15. Chhowalla, M., K. B. K. Teo, C. Ducati, N. L. Rupersinghe, G. A. J. Amaratunga, A. C. Ferrari, D. Roy, J. Robertson, and W. I. Milne, 2001, J. Appl. Phys. 90, 5308.
  16. Cho, K. S., N. M. Park, T. Y. Kim, K. H. Kim, G. Y. Sung, and J. H. Shin, 2005, Appl. Phys. Lett. 86, 071909.
  17. Cho, W. J., O. Rodriguez, R. Saxena, M. Ojha, R. A. Chanta, J. L. Plawsky, and W. N. Gill, 2005, J. Electrochem. Soc. 152, F26.
  18. Choi, W. B., E. Bae, D. Kang, S. Chae, B. Cheong, J. Ko, E. Lee, and W. Park, 2004, Nanotechnology 15, S512.
  19. Collard, C., J. P. Holloway, and M. L. Brake, 2005, IEEE Trans. Plasma Sci. 33, 170.
  20. Costa, J., 2000, in Handbook of Nanostructured Materials, edited by H. S. Nalva (Academic, New York), Vol. 1, p. 57.
  21. De Bleecker, K., A. Bogaerts, R. Gijbels, and W. Goedheer, 2004, Phys. Rev. E 69, 056409.
  22. Denysenko, I. B., K. Ostrikov, S. Xu, M. Y. Yu, and C. H. Diong 2003, J. Appl. Phys. 94, 6097.
  23. Denysenko, I. B., S. Xu, P. P. Rutkevych, J. D. Long, N. A. Azarenkov, and K. Ostrikov, 2004, J. Appl. Phys. 95, 2713.
  24. Dresselhaus, M. S., G. Dresselhaus, and P. C. Eklund, 1996, Science of Fullerenes and Carbon Nanotubes (Academic, New York).
  25. Fontcuberta i Morral, A., and P. Roca i Cabarrocas, 2001, Thin Solid Films 383, 161.
  26. Fontcuberta i Morral, A., P. Roca i Cabarrocas, and C. Clerc, 2004, Phys. Rev. B 69, 125307.
  27. Franklin, N. R., and H. Dai, 2002, Adv. Mater. (Weinheim, Ger.) 12, 890.
  28. Frantz, J., and K. Nordlund, 2003, Phys. Rev. B 67, 075415.
  29. Frenklash, M., and H. Wang, 1991, Phys. Rev. B 43, 1520.
  30. Fridman, A., and L. A. Kennedy, 2004, Plasma Physics and Engineering (Taylor & Francis, New York).
  31. Fridman, A. A., L. Boufendi, T. Hbid, B. N. Potapkin, and A. Bouchoule, 1996, J. Appl. Phys. 79, 1303.
  32. Gebauer, G., and J. Winter, 2003, New J. Phys. 5, 38.1.
  33. Gerhardt, P., and K. H. Homann, 1990, Combust. Flame 81, 289.
  34. Ghidini, R., C. H. J. M. Groothuis, M. Sorokin, G. M. W. Kroesen, and W. W. Stoffels, 2004, Plasma Sources Sci. Technol. 13, 143.
  35. Gilbert, B., F. Huang, H. Zhang, G. Waychunas, and J. F. Banfield, 2004, Science 305, 651.
  36. Gordillo-Vazques, F. J., and J. M. Albella, 2004, Plasma Sources Sci. Technol. 13, 50.
  37. Goree, J., and T. E. Sheridan, 1992, J. Vac. Sci. Technol. A 10, 3540.
  38. Gruen, D. M., 2001, MRS Bull. 26, 771.
  39. Gruen, D. M., P. C. Redfern, D. A. Horner, P. Zapol, and L. A. Curtis, 1999, J. Phys. Chem. B 103, 5459.
  40. Hash, D., and M. Meyyappan, 2003, J. Appl. Phys. 93, 750.
  41. Helveg, S., C. Lopez-Cartez, J. Sehested, P. L. Hansen, B. S. Clausen, J. R. Rostrup-Nielsen, F. Abild-Pedersen, and J. Norskov, 2004, Nature (London) 427, 426.
  42. Hirata, T., N. Satake, G. H. Jeong, and T. Kato, 2003, Appl. Phys. Lett. 83, 1119.
  43. Hofmann, S., C. Dukati, J. Robertson, and B. Kleinsorge, 2003, Appl. Phys. Lett. 83, 135.
  44. Hollenstein, C., 2000, Plasma Phys. Controlled Fusion 42, R93.
  45. Hong, S., J. Berndt, and J. Winter, 2003, Plasma Sources Sci. Technol. 12, 46.
  46. Hrivnak, B. J., and S. Kwok, 1999, Astrophys. J. 513, 869.
  47. Hua, X. F., C. Stolz, G. S. Oehrlein, P. Lazzeri, N. Coghe, M. Anderle, C. K. Inoki, M. Anderle, T. S. Kuan, and P. Jiang, 2005, J. Vac. Sci. Technol. A 23, 151.
  48. Huang, H. W., C. C. Kao, T. H. Hsueh, C. C. Yu, C. F. Lin, J. T. Chu, H. C. Kuo, and S. C. Wang, 2004, Mater. Sci. Eng., B 113, 125.
  49. Hwang, N. M., 1999, J. Cryst. Growth 204, 85.
  50. Hwang, N. M., W. S. Cheong, D. Y. Yoon, and D. Y. Kim, 2000, J. Cryst. Growth 218, 33.
  51. Hwang, N. M., J. H. Hahn, and D. Y. Yoon, 1996, J. Cryst. Growth 162, 55.
  52. Hwang, N. M., and D. Y. Kim, 2004, Int. Mater. Rev. 49, 171.
  53. Hwang, N. M., and D. Y. Yoon, 1994, J. Cryst. Growth 143, 103.
  54. Iijima, S., 1991, Nature (London) 354, 56.
  55. Jeon, I. D., C. J. Park, D. Y. Kim, and N. N. Hwang, 2000, J. Cryst. Growth 213, 79.
  56. Jeong, K. H., S. G. Park, and S. W. Rhee, 2004, J. Vac. Sci. Technol. B 22, 2799.
  57. Kanzow, H., and A. Ding, 1999, Phys. Rev. B 60, 11180.
  58. Kersten, H., R. Wiese, G. Thieme, M. Froehlich, A. Kopitov, D. Bojic, F. Scholze, H. Neumann, M. Quaas, H. Wulff, and R. Hippler, 2003, New J. Phys. 5, 93.1.
  59. Kim, M. J., J. S. Lee, S. K. Kim, G. Y. Yeom, J. B. Yoo, and C. Y. Park, 2005, Thin Solid Films 475, 41.
  60. Kimura, T., 2005, Microporous Mesoporous Mater. 77, 97.
  61. Klein, C. P. A. T., P. Patsa, J. G. C. Wolke, J. Blieck-Hogervorst, and K. Groot, 1994, J. Biomed. Mater. Res. 28, 909.
  62. Kovacevic, E., I. Stefanovic, J. Berndt, and J. Winter, 2003, J. Appl. Phys. 93, 2924.
  63. Kuykendall, T., P. J. Pauzauskie, Y. Zhang, J. Goldberger, D. Sirbuly, J. Denlinger, and P. Yang, 2004, Nat. Mater. 3, 524.
  64. Kwon, Y. S., J. S. Kim, P. P. Choi, J. H. Song, and D. Dudina, 2005, J. Ind. Eng. Chem. (Seoul, Repub. Korea) 11, 103.
  65. Lee, J. M., S. H. Oh, C. W. Lee, H. Ko, S. Park, K. S. Kim, and M. H. Park, 2005, Thin Solid Films 475, 189.
  66. Lee, Y. J., 2005, Mater. Lett. 59, 615.
  67. Levchenko, I., M. Korobov, M. Romanov, and M. Keidar, 2004, J. Phys. D 37, 1690.
  68. Levchenko, I., and K. Ostrikov, 2005, unpublished.
  69. Lieberman, M. A., and A. J. Lichtenberg, 1994, Principles of Plasma Discharges and Materials Processing (Wiley, New York).
  70. Lii, Y. J. T., 1996, in ULSI Technology, edited by C. Y. Chang and S. M. Sze (McGraw-Hill, New York), p. 329.
  71. Lin, M., K. P. Loh, C. Boothroyd, and A. Y. Du, 2004, Appl. Phys. Lett. 85, 5388.
  72. Lister, K. A., B. G. Casey, P. S. Dobson, S. Thoms, D. S. Macintyre, C. D. W. Wilkinson, and J. M. R. Weaver, 2004, Microelectron. Eng. 73-74, 319.
  73. Long, J. D., P. P. Rutkevych, J. Z. Wu, and S. Xu, 2005, unpublished.
  74. Long, J. D., S. Xu, J. W. Cai, N. Jiang, J. H. Lu, K. N. Ostrikov, and C. H. Diong, 2002, Mater. Sci. Eng., C 20, 175.
  75. Long, J. D., S. Xu, J. H. Lu, K. N. Ostrikov, and C. H. Diong, 2002, IEEE Trans. Plasma Sci. 30, 118.
  76. Louchev, O. A., and J. R. Hester, 2003, J. Appl. Phys. 94, 2002.
  77. Magnano, E., C. Cepek, M. Sancrotti, F. Siviero, S. Vinati, C. Lenardi, P. Piseri, E. Barborini, and P. Milani, 2003, Phys. Rev. B 67, 125414.
  78. Marks, N., J. M. Bell, G. K. Pearce, D. R. McKenzie, and M. M. M. Bilek, 2003, Diamond Relat. Mater. 12, 2003.
  79. Marks, N., N. C. Cooper, D. R. McKenzie, D. G. McCulloch, P. Bath, and S. P. Russo, 2002, Phys. Rev. B 65, 075411.
  80. Menon, L., K. B. Ram, S. Patibandla, D. Aurongzeb, M. Holtz, J. Yun, V. Kuryatkov, and K. Zhu, 2004, J. Electrochem. Soc. 151, C492.
  81. Merkulov, V. I., A. V. Melechko, M. A. Guillorn, D. H. Lowndes, and M. L. Simpson, 2000, Appl. Phys. Lett. 76, 3555.
  82. Merkulov, V. I., A. V. Melechko, M. A. Guillorn, D. H. Lowndes, and M. L. Simpson, 2001, Appl. Phys. Lett. 79, 2970.
  83. Merlino, R., and J., Goree, 2004, Phys. Today 57 (7), 32.
  84. Meyyappan, M., L. Delzeit, A. Cassel, and D. Hash, 2003, Plasma Sources Sci. Technol. 12, 205.
  85. Monticone, S., R. Tufeu, A. V. Kanaev, E. Scolan, C. Sanchez, 2000, Appl. Surf. Sci. 162, 565.
  86. Mulvaney, P., 2001, MRS Bull. 26, 1009.
  87. Obraztsov, A. N., I. Pavlovsky, A. P. Volkov, E. D. Obraztsova, A. L. Chuvilin, and V. L. Kuznetsov, 2000, J. Vac. Sci. Technol. B 18, 1059.
  88. Oehrlein, G. S., 2003, Plasma Processing of Electronic Materials (Springer, Berlin).
  89. Ostraat, M. L., J. W. De Blauwe, M. L. Green, L. D. Bell, M. L. Brongersma, J. Casperson, R. C. Flagan, and H. A. Atwater, 2001, Appl. Phys. Lett. 79, 433.
  90. Ostrikov, K., I. B. Denysenko, S. V. Vladimirov, S. Xu, H. Sugai, and M. Y. Yu, 2003, Phys. Rev. E 67, 056408.
  91. Ostrikov, K., I. Denysenko, M. Y. Yu, C. H. Diong, and S. Xu, 2005, Phys. Scr. (to be published).
  92. Panin, G. N., Y. S. Park, T. W. Kang, T. W. Kim, K. L. Wang, and M. Bao, 2005, J. Appl. Phys. 97, 043527.
  93. Pei, Z. W., A. Y. K. Su, H. L. Hwang, and H. L. Hsiao, 2005, Appl. Phys. Lett. 86, 063503.
  94. Perrin, J., and C. Hollenstein, 1999, in Dusty Plasmas: Physics, Chemistry and Technological Impacts in Plasma Processing, edited by A. Bouchoule (Wiley, New York), p. 77.
  95. Perrin, J., M. Shiratani, P. Kae-Nune, H. Videlot, J. Jolly, and J. Guillon, 1998, J. Vac. Sci. Technol. A 16, 278.
  96. Pitkethly, M. J., 2003, Nano Today, 36.
  97. Poissant, Y., P. Chatterjee, and P. Roca i Cabarrocas, 2003, J. Appl. Phys. 94, 7305.
  98. Poole, C. P., Jr., and F. J. Owens, 2003, Introduction to Nanotechnology (Wiley, New York).
  99. Roca i Cabarrocas, P., N. Chaabane, A. V. Kharchenko, and S. Tchakarov, 2004, Plasma Phys. Controlled Fusion 46, B235.
  100. Roca i Cabarrocas, P., S. Hamma, S. N. Sharma, G. Viera, E. Bertran, and J. Costa, 1998, J. Non-Cryst. Solids 227-230, 871.
  101. Roco, M. C., S. Williams, and P. Alivisatos, 1999, Nanotechnology Research Directions: Vision for Nanotechnology Research and Development in the Next Decade (Kluwer Academic, Amsterdam); see also US National Nanotechnology Initiative, http://www.nano.gov
  102. Rode, A. V., E. G. Gamaly, A. G. Christy, J. C. F. Gerald, S. T. Hyde, R. G. Elliman, B. Luther-Davies, A. I. Veinger, J. Androulakis, and J. Giapintzakis, 2004, Phys. Rev. B 70, 054407.
  103. Rutkevych, P. P., K. Ostrikov, S. Xu, and S. V. Vladimirov, 2004, J. Appl. Phys. 96, 4421.
  104. Shchukin, V., N. N. Ledentsov, and D., Bimberg, 2003, Epitaxy of Nanostructures (Springer, Berlin/Heidelberg).
  105. Shieh, J., T. S. Ko, H. L. Chen, B. T. Dai, and T. C. Chu, 2004, Chem. Vap. Deposition 10, 265.
  106. Shiratani, M., K. Koga, and Y. Watanabe, 2003, Thin Solid Films 427, 1.
  107. Shiratani, M., S. Maeda, K. Koga, and Y. Watanabe, 2000, Jpn. J. Appl. Phys., Part 1 39, 287.
  108. Song, S. P., M. A. Crimp, V. M. Ayres, C. J. Collard, J. P. Holloway, and M. L. Brake, 2004, J. Nanosci. Nanotechnol. 4, 817.
  109. Stangl, J., V. Holy, and G. Bauer, 2004, Rev. Mod. Phys. 76, 725.
  110. Stoffels, W. W., E. Stoffels, G. H. P. M. Swinkels, H. Videlot, M. Boufnichkel, and G. M. W. Kroesen, 1999, Phys. Rev. E 59, 2302.
  111. Stoykov, S., C. Eggs, and U. Kortshagen, 2001, J. Phys. D 34, 2160.
  112. Suendo, V., A. Kharchenko, and P. Roca i Cabarrocas, 2004, Thin Solid Films 451-452, 259.
  113. Sugai, H., I. Ghanashev, M. Hosokawa, K. Mizuno, K. Nakamura, H. Toyoda, and K. Yamauchi, 2001, Plasma Sources Sci. Technol. 10, 378.
  114. Suh, S. M., S. L. Girshik, U. R. Kortshagen, and M. R. Zachariah, 2003, J. Vac. Sci. Technol. A 21, 251.
  115. Sun, L., C. C. Berndt, K. A. Gross, and A. Kucuk, 2001, J. Biomed. Mater. Res. 58, 570.
  116. Tanda, M., M. Kondo, and A. Matsuda, 2003, Thin Solid Films 427, 33.
  117. Thomas, H. M., and G. E. Morphill, 1996, Nature (London) 379, 806.
  118. Tsai, S. H., F. K. Chiang, T. G. Tsai, F. S. Shieu, and H. C. Shih, 2000, Thin Solid Films 366, 11.
  119. Tsakadze, Z. L., K. Ostrikov, J. D. Long, and S. Xu, 2004, Diamond Relat. Mater. 13, 1923.
  120. Tsakadze, Z. L., K. Ostrikov, and S. Xu, 2005, Surf. Coat. Technol. 191/1, 49.
  121. Tsubouchi, K., and K., Masu, 1992, J. Vac. Sci. Technol. A 10, 856.
  122. Tsui, Y. C., C. Doyle, and T. W. Clyne, 1998, Biomaterials 19, 2031.
  123. Veprek, S., H.-D. Mannling, M. Jilek, and P. Holubar, 2004, Mater. Sci. Eng., A 366, 202.
  124. Veprek, S., S. Mukherjee, P. Karvankova, H.-D. Mannling, J. L. He, K. Moto, J. Prochazka, and A. S. Argon, 2003, J. Vac. Sci. Technol. A 21, 532.
  125. Viera, G., M. Mikikian, E. Bertran, P. Roca i Cabarrocas, and L. Boufendi, 2002, J. Appl. Phys. 92, 4684.
  126. Vladimirov, S. V., and K. Ostrikov, 2004, Phys. Rep. 393, 175.
  127. Walch, S., and R. Merkle, 1998, Nanotechnology 9, 1998.
  128. Wang, L. J., and F. C. N. Hong, 2005, Microporous Mesoporous Mater. 77, 167.
  129. Xu, S., J. D. Long, L. Sim, C. H. Diong, and K. Ostrikov, 2005, Plasma Proc. Polym. 2, 373.
  130. Xu, S., K. Ostrikov, J. D. Long, and S. Y. Huang, 2005, unpublished.
  131. Yang, Q., W. Chen, C. Xiao, R. Sammynaiken, and A. Hirose, 2005, Carbon 43, 748.
  132. Yasuda, H., 1985, Plasma Polymerization (Academic, New York).

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation