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Coherent population transfer among quantum states of atoms and molecules
Rev. Mod. Phys. 70, 1003 – Published 1 July, 1998
DOI: https://doi.org/10.1103/RevModPhys.70.1003
Abstract
The authors discuss the technique of stimulated Raman adiabatic passage (STIRAP), a method of using partially overlapping pulses (from pump and Stokes lasers) to produce complete population transfer between two quantum states of an atom or molecule. The procedure relies on the initial creation of a coherence (a population-trapping state) with subsequent adiabatic evolution. The authors present the basic theory, with some extensions, and then describe examples of experimental utilization. They note some applications of the technique not only to preparation of selected states for reaction studies, but also to quantum optics and atom optics.
References (85)
- Alzetta, G., A. Gozzini, L. Moi, and G. Orriols, 1976, “An experimental method for the observation of r.f. transitions and laser beat resonances in oriented Na vapour,” Nuovo Cimento B 36, 5–20.
- Arimondo, E., 1996, “Coherent population trapping in laser spectroscopy,” Prog. Opt. 35, 259–356.
- Arimondo, E., and G. Orriols, 1976, “Non-absorbing atomic coherences by coherent two-photon transition in a three-level optical pumping,” Nuovo Cimento 17, 333–338.
- Bergmann, K., and B. W. Shore, 1995, Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping (World Scientific, Singapore).
- Boller, K. J., A. Imamoglu, and S. E. Harris, 1991, “Observation of electromagnetically induced transparency,” Phys. Rev. Lett. 66, 2593–2596.
- Broers, B., H. B. van Linden van den Heuvell, and L. D. Noordam, 1992, “Efficient population transfer in a three-level ladder system by frequency-swept ultrashort laser pulses,” Phys. Rev. Lett. 69, 2062–2065.
- Carroll, C. E., and F. T. Hioe, 1987, “Three-state model driven by two laser beams,” Phys. Rev. A 36, 724–729.
- Carroll, C. E., and F. T. Hioe, 1988, “Three-state systems driven by resonant optical pulses of different shapes,” J. Opt. Soc. Am. B 5, 1335–1340.
- Carroll, C. E., and F. T. Hioe, 1989, “Two-photon resonance in three-state model driven by two laser beams,” J. Phys. B 22, 2633–2647.
- Carroll, C. E., and F. T. Hioe, 1990, “Analytic solutions for three-state systems with overlapping pulses,” Phys. Rev. A 42, 1522–1531.
- Carroll, C. E., and F. T. Hioe, 1992, “Coherent population transfer via the continuum,” Phys. Rev. Lett. 68, 3523–3526.
- Chelkowski, S., and A. D. Bandrauk, 1997, “Raman chirped adiabatic passage: A new method for selective excitation of high vibrational states,” J. Raman Spectrosc. 28, 459–466.
- Chelkowski, S., and G. N. Gibson, 1995, “Adiabatic climbing of vibrational ladders using Raman transitions with a chirped pump laser,” Phys. Rev. A 52, 3417–3420.
- Dai, H. C., and R. W. Field, 1994, Eds., Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping (World Scientific, Singapore).
- Dai, B.-N., and P. Lambropoulos, 1987, “Laser-induced autoionizinglike behavior, population trapping, and stimulated Raman process in real atoms,” Phys. Rev. A 36, 5205–5208.
- Dittmann, P., F. P. Pesl, J. Martin, G. W. Coulston, G. Z. He, and K. Bergmann, 1992, “The effect of vibrational excitation on the reaction ,” J. Chem. Phys. 97, 9472–9475.
- Eberly, J. H., J. J. Yeh, and C. M. Bowden, 1982, “Interrupted coarse-grained theory of quasi-continuum photoexcitation,” Chem. Phys. Lett. 86, 76–80.
- Feller, D., E. D. Glendening, E. A. McCullough, Jr., and R. J. Miller, 1993, “A comparison of unrestricted Hartree-Fock and restricted open-shell Hartree-Fock-based methods for determining the magnetic hyperfine parameters of NO ,” J. Chem. Phys. 99, 2829–2840.
- Fewell, M., B. W. Shore, and K. Bergmann, 1997, “Coherent population transfer among three states: Full algebraic solutions and the relevance of non adiabatic processes to transfer by delayed pulses,” Aust. J. Phys. 50, 281–304.
- Fleischhauer, M., C. H. Keitel, M. O. Scully, C. Su, B. T. Ulrich, and S.-Y. Zhu, 1992, “Resonantly enhanced refractive index without absorption via atomic coherence,” Phys. Rev. A 46, 1468–1487.
- Gaubatz, U., P. Rudecki, M. Becker, S. Schiemann, M. Kulz, and K. Bergmann, 1988, “Population switching between vibrational levels in molecular beams,” Chem. Phys. Lett. 149, 463–8.
- Gaubatz, U., P. Rudecki, S. Schiemann, and K. Bergmann, 1990, “Population transfer between molecular vibrational levels. A new concept and experimental results,” J. Chem. Phys. 92, 5363–5376.
- Goldner, L. S., C. Gerz, R. J. C. Spreeuw, S. L. Rolston, C. I. Westbrook, W. D. Phillips, P. Marte, and P. Zoller, 1994a, “Coherent transfer of photon momentum by adiabatic following in a dark state,” Quantum Opt. 6, 387–389.
- Goldner, L. S., C. Gerz, R. J. Spreeuw, S. L. Rolston, C. I. Westbrook, W. D. Phillips, P. Marte, and P. Zoller, 1994b, “Momentum transfer in laser-cooled cesium by adiabatic passage in a light field,” Phys. Rev. Lett. 72, 997–1000.
- Guerin, S., 1997, “Complete dissociation by chirped laser pulses designed by adiabatic Floquet analysis,” Phys. Rev. A 56, 1458–1462.
- Halfmann, T., and K. Bergmann, 1996, “Coherent population transfer and dark resonances in ,” J. Chem. Phys. 104, 7068–7072.
- Halfmann, T., L. P. Yatsenko, M. Shapiro, B. W. Shore, and K. Bergmann, 1998, “Population trapping and laser-induced continuum structure in helium: Experiment and Theory,” Phys. Rev. A 58, R46–R49.
- Hamilton, C. H., J. L. Kinsey, and R. W. Field, 1986, “Stimulated emission pumping: New methods in spectroscopy and molecular dynamics,” Annu. Rev. Phys. Chem. 37, 493–524.
- Harris, S. E., 1993, “Electromagnetically induced transparency with matched pulses,” Phys. Rev. Lett. 70, 552–555.
- Harris, S. E., 1994, “Refractive-index control with strong fields,” Opt. Lett. 19, 2018–2020.
- Harris, S. E., 1997, “Electromagnetically Induced Transparency,” Phys. Today 50, No. 7, 36–42.
- Harris, S. E., J. E. Field, and A. Imamoglu, 1990, “Nonlinear optical processes using electromagnetically induced transparency,” Phys. Rev. Lett. 64, 1107–1110.
- Herzberg, G., 1950, Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules (Van Nostrand, N.Y.).
- Hioe, F. T., 1983, “Theory of generalized adiabatic following in multilevel systems,” Phys. Lett. A 99, 150.
- Hioe, F. T., 1984, “Linear and nonlinear constants of motion for two-photon processes in three-level systems,” Phys. Rev. A 29, 3434–3436.
- Hioe, F. T., and C. E. Carroll, 1988, “Coherent population trapping in N-level quantum systems,” Phys. Rev. A 37, 3000–3005.
- Hioe, F. T., and C. E. Carroll, 1996, “Population transfer and pulse propagation in certain closed-loop systems,” Phys. Lett. A 220, 49–54.
- Hioe, F. T., and C. E. Carroll, 1997, “Solitary waves and atomic population transfer via the continuum,” Phys. Rev. A 56, 2292–2298.
- Hioe, F. T., and J. H. Eberly, 1984, “Multiple-laser excitation of multilevel atoms,” Phys. Rev. A 29, 1164–1167.
- Kasapi, A., M. Jain, G. Y. Yin, and S. E. Harris, 1995, “Electromagnetically induced transparency: Propagation dynamics,” Phys. Rev. Lett. 74, 2447–2450.
- Kasevich, M., and S. Chu, 1991, “Atomic interferometry using stimulated Raman transitions,” Phys. Rev. Lett. 67, 181–184.
- Knight, P. L., 1984, “Laser-induced continuum structure,” Comments At. Mol. Phys. 15, 193–214.
- Knight, P. L., M. A. Lauder, and B. J. Dalton, 1990, “Laser-induced continuum structure,” Phys. Rep. 190, 1–61.
- Kuhn, A., S. Schiemann, G. Z. He, G. Coulston, W. S. Warren, and K. Bergmann, 1992, “Population transfer by stimulated Raman scattering with delayed pulses using spectrally broad light,” J. Chem. Phys. 96, 4215–4223.
- Kuhn, A., S. Steuerwald, and K. Bergmann, 1998, “Coherent population transfer in NO with pulsed lasers: The consequences of hyperfine structure, Doppler broadening and electromagnetically induced absorption,” Eur. Phys. J. D 1, 59–70.
- Kuklinski, J. R., U. Gaubatz, F. T. Hioe, and K. Bergmann, 1989, “Adiabatic population transfer in a three-level system driven by delayed laser pulses,” Phys. Rev. A 40, 6741–6744.
- Kulin, S., B. Saubamea, E. Peik, J. Lawall, T. Hujmans, M. Leduc, and C. Cohen-Tannoudji, 1997a, “Coherent manipulation of atomic wave packets by adiabatic transfer,” Phys. Rev. Lett. 78, 4815–4188.
- Kulin, S., B. Saubamea, E. Peik, J. Lawall, T. Hujmans, M. Leduc, and C. Cohen-Tannoudji, 1997b, “Coherent manipulation of atomic wave packets by adiabatic transfer,” Phys. Rev. Lett. 78, 4815–4188.
- Kulz, M., A. Kortyna, M. Keil, B. Schellhaass, and K. Bergmann, 1995, “On the vibrational dependence of electron impact ionization of diatomic molecules,” Z. Phys. D 33, 109–117.
- Laine, T. A., and S. Stenholm, 1996, “Adiabatic processes in three-level systems,” Phys. Rev. A 53, 2501–2512.
- Lawall, J., S. Kulin, B. Saubamea, N. Bigelow, M. Leduc, and C. Cohen-Tannoudji, 1996, “Subrecoil laser cooling into a single wavepacket by velocity-selective coherent population trapping followed by adiabatic passage,” Laser Phys. 6, 153–158.
- Lindinger, A., M. Verbeek, and H.-G. Rubahn, 1997, “Adiabatic population transfer by acoustooptically modulated laser beams,” Z. Phys. D 39, 93–100.
- Lukin, M. D., M. O. Scully, G. R. Welch, E. S. Fry, L. Hollberg, G. G. Padmabandu, H. G. Robinson, and A. S. Zibrov, 1996, “Lasing without inversion: the road to new short-wavelength lasers,” Laser Phys. 6, 436–447.
- Malinovsky, V. S., and D. J. Tannor, 1997, “A simple and robust extension of STIRAP to N-level sytems,” Phys. Rev. A 56, 4929–4937.
- Marte, P., P. Zoller, and J. L. Hall, 1991, “Coherent atomic mirrors and beam splitters by adiabatic passage in multilevel systems,” Phys. Rev. A 44, R4118–4121.
- Martin, J., B. W. Shore, and K. Bergmann, 1996, “Coherent population transfer in multilevel systems with magnetic sublevel. III. Experimental results,” Phys. Rev. A 54, 1556–1569.
- Messiah, A., 1962, Quantum Mechanics (North-Holland/Elsevier Science, New York).
- Miller, R. J., and D. Feller, 1994, “Comment on the hyperfine structure of the ground state of nitric oxide,” J. Chem. Phys. 98, 10 375.
- Nakajima, T., and P. Lambropoulos, 1996, “Population transfer through an autoionizing state by pulse delay,” Z. Phys. D 36, 17–22.
- Nakajima, T., M. Elk, J. Zhang, and P. Lambropoulos, 1994, “Population transfer through the continuum,” Phys. Rev. A 50, R913–R916.
- Oreg, J., F. T. Hioe, and J. H. Eberly, 1984, “Adiabatic following in multilevel systems,” Phys. Rev. A 29, 690–697.
- Oreg, J., K. Bergmann, B. W. Shore, and S. Rosenwaks, 1992, “Population transfer with delayed pulses in four-state systems,” Phys. Rev. A 45, 4888–4896.
- Padmabandu, G. G., G. R. Welch, I. N. Shubin, E. S. Fry, D. E. Nikonov, M. D. Lukin, and M. O. Scully, 1996, “Laser oscillation without population inversion in a sodium atomic beam,” Phys. Rev. Lett. 76, 2053–2056.
- Parkins, A. S., P. Marte, P. Zoller, and H. J. Kimble, 1993, “Synthesis of arbitrary quantum states via adiabatic transfer of Zeeman coherence,” Phys. Rev. Lett. 71, 3095–3102.
- Paspalakis, E., M. Protopapas, and P. L. Knight, 1997, “Population transfer through the continuum with temporally delayed chirped laser pulses,” Opt. Commun. 142, 34–40.
- Pillet, P., C. Valentin, R.-L. Yuan, and J. Yu, 1993, “Adiabatic population transfer in a multilevel system,” Phys. Rev. A 48, 845–848.
- Romanenko, V. I., and L. P. Yatsenko, 1997, “Adiabatic population transfer in the three-level lambda-system: two-photon lineshape,” Opt. Commun. 140, 231–236.
- Schiemann, S., A. Kuhn, S. Steuerwald, and K. Bergmann, 1993, “Efficient coherent population transfer in Molecules using pulsed lasers,” Phys. Rev. Lett. 71, 3637–3640.
- Scully, M. O., 1991, “Enhancement of the index of refraction via quantum coherence,” Phys. Rev. Lett. 67, 1855–1858.
- Scully, M. O., and M. Fleischhauer, 1994, “Lasers without inversion,” Science 263, 337–338.
- Scully, M. O., S.-Y. Zhu, and A. Gavrielides, 1989, “Degenerate quantum-beat laser: Lasing without inversion and inversion without lasing,” Phys. Rev. Lett. 62, 2813–2816.
- Shore, B. W., 1990, The Theory of Coherent Atomic Excitation (Wiley, New York).
- Shore, B. W., 1995, “Examples of counter-intuitive physics,” Contemp. Phys. 36, 15–28.
- Shore, B. W., K. Bergmann, A. Kuhn, S. Schiemann, J. Oreg, and J. H. Eberly, 1992, “Laser-induced population transfer in multistate systems: A comparative study,” Phys. Rev. A 45, 5297–5300.
- Shore, B. W., K. Bergmann, J. Oreg, and S. Rosenwaks, 1991, “Multilevel adiabatic population transfer,” Phys. Rev. A 44, 7442–7447.
- Smith, A. V., 1992, “Numerical studies of adiabatic population inversion in multilevel system,” J. Opt. Soc. Am. B 9, 1543–1551.
- Suptitz, W., B. C. Duncan, and P. L. Gould, 1997, “Efficient 5D excitation of trapped Rb atoms using pulses of diode-laser light in the counterintuitive order,” J. Opt. Soc. Am. B 14, 1001–1008.
- Theuer, H., and K. Bergmann, 1998, “Atomic beam deflection by coherent momentum transfer and the dependence on weak magnetic fields,” Eur. Phys. J. D (to be published).
- van Enk, S. J., J. Zhang, and P. Lambropoulos, 1995, “Coherent effects through the continuum: Transparency, population trapping and amplification without inversion through auto ionizing resonances,” Appl. Phys. B: Lasers Opt. 60, S141–152.
- Vitanov, N. V., and S. Stenholm, 1996, “Non-adiabatic effects in population transfer in three-level systems,” Opt. Commun. 127, 215–222.
- Vitanov, N. V., and S. Stenholm, 1997, “Population transfer by delayed pulses via continuum states,” Phys. Rev. A 56, 741–747.
- Walser, R., J. I. Cirac, and P. Zoller, 1996, “Magnetic Tomography of a Cavity State,” Phys. Rev. Lett. 77, 2658–2661.
- Weitz, M., B. C. Young, and S. Chu, 1994, “Atom manipulation based on delayed laser pulses in three- and four-level systems: Light shifts and transfer efficiencies,” Phys. Rev. A 50, 2438–2444.
- Yatsenko, L. P., R. G. Unanyan, K. Bergmann, T. Halfmann, and B. W. Shore, 1997, “Population transfer through the continuum using laser-controlled Stark shifts,” Opt. Commun. 135, 406–412.
- Yeh, J. J., C. M. Bowden, and J. H. Eberly, 1982, “Interrupted coarse grained theory of unimolecular relaxation and stimulated recurrences in photoexcitation of a quasicontinuum,” J. Chem. Phys. 76, 5936–5946.