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Theory of band tails in heavily doped semiconductors

Piet Van Mieghem

Piet Van Mieghem

  • Interuniversity Micro Electronics Center (IMEC), Kapeldreef 75, B-3001 Leuven, Belgium

Rev. Mod. Phys. 64, 755 – Published 1 July, 1992

DOI: https://doi.org/10.1103/RevModPhys.64.755

Abstract

The random distribution of impurities in a semiconductor host lattice introduces potential fluctuations that allow energy levels within the forbidden energy gap. This statistical effect distorts the unperturbed density of states of the pure semiconductor, and, at high doping concentrations, substantial band tails appear. The changes in the density-of-states function are particularly important in determining the number of free carriers in a heavily doped semiconductor. Together with many-particle interactions, band tailing constitutes one of the most significant heavy-doping effects. Although the band-tailing phenomenon has been studied for many years, only a one-dimensional analytical model, which assumes a Gaussian whitenoise probability distribution of the potential fluctuation, exists. In this paper the different classes of theories that describe this band tailing of the density of states in heavily doped semiconductors are reviewed in detail.

References (119)

  1. Abram, R. A., and S. F. Edwards, 1972a, "The nature of the electronic states of a disordered system: I. Localized states," J. Phys. C 5, 1183-1195
  2. Abram, R. A., and S. F. Edwards, 1972b, "The nature of the electronic states of a disordered system: II. Extended states," J. Phys. C 5, 1196-1206
  3. Abram, R. A., G. J. Rees, and B. L. H. Wilson, 1978, "Heavily doped semiconductors and devices," Adv. Phys. 27, 799-892
  4. Abramowitz, M., and I. Stegun, 1968, Handbook of Mathematical Functions, Appl. Math. Series 55 (U.S. National Bureau of Standards, Washington, D.C.)
  5. Arnaudov, B. G., V. A. Vil'kotskii, D. S. Domanevskii, S. K. Evtimova, and V. D. Tkachev, 1987, "Influence of fluctuations of the impurity potential on the Burnstein-Moss effect," Sov. Phys. Semicond. 11, 1054-1056
  6. Ashcroft, N. W., and N. D. Mermin, 1981, Solid State Physics (Saunders, Philadelphia)
  7. Aslangul, C., M. Barthélémy, N. Pottier, D. Saint-James, 1991, "Dynamical properties of a random walk in a one-dimensional random medium," Physica A 171, 47-68
  8. Bagaev, V. S., Yu. N. Berozashvili, B. M. Vul, E. I. Zavaritskaya, L. V. Keldysh, and A. P. Shotov, 1964-1965, "On the energy level spectrum of heavily doped gallium arsenide," Sov. Phys. Solid State 6, 1093-1098
  9. Berggren, K.-F., and B. E. Sernelius, 1981, "Band-gap narrowing in heavily doped many-valley semiconductors," Phys. Rev. B 24, 1971-1986
  10. Berggren, K.-F., and B. E. Sernelius, 1985, "Very heavily doped semiconductors as a `nearly-free-electron-gas' system," Solid-State Electronics 25, 11-15
  11. Bethe, H., and E. Salpeter, 1957, Quantum Mechanics of One- and Two-Electron Atoms (Springer, Berlin)
  12. Bonch-Bruevich, V. L., 1963, "On the theory of heavily doped semiconductors," Sov. Phys. Solid State 4, 1953-1962
  13. Bonch-Bruevich, V. L., 1965, "On the electron theory of heavily doped semiconductors," in Solid State Physics (VINITI, Moscow), p. 174
  14. Borland, R. E., 1961, "One-dimensional chains with random spacing between atoms," Proc. Phys. Soc. London 77, 705-711
  15. Bouchaud, J. P., A. Comtet, A. Georges, and P. Le Doussal, 1991, Ann. Phys. (in press)
  16. Brennan, K. F., 1990, "Random well width superlattices as one-dimensional artificial amorphous materials and their possible exploitation in a new Ovshinsky switch," Appl. Phys. Lett. 57, 1114-1116
  17. Brézin, E., and G. Parisi, 1980, "Exponential tail of the electronic density of levels in a random potential," J. Phys. C 13, L307
  18. Cardy, J. L., 1978, "Electron localisation in disordered systems and classical solutions in Ginzburg-Landau field theory," J. Phys. C 11, L321
  19. Casey, H. C., and M. B. Panish, 1978, Heterostructure Lasers (Academic, New York)
  20. Chiayasith, P., S. Kokpol, and V. Sa-yakanit, 1983, "A Simplified Approach to Impurity-band Tails in Heavily Doped Semiconductors," Phys. Lett. A 98, 273-276
  21. Cohen, M. H., M. Y. Chou, E. N. Economou, S. John, and C. M. Soukoulis, 1988, "Band tails, path integrals, instantons, polarons and all that," IBM J. Res. Develop. 32, 82-92
  22. Davydov, A. S., 1976, Quantum Mechanics (Pergamon, Oxford), Sec. 21 and p. 317
  23. Dobbelaere, W., J. De Boeck, P. Van Mieghem, R. Mertens, and G. Borghs, 1991, "Optical characterization of Si-doped InAs1xSbx grown on GaAs and GaAs-coated Si by molecular beam epitaxy," J. Appl. Phys. 69, 2536-2542
  24. Domanevskii, D. S., S. V. Zhokhovets, and M. V. Prokopenya, 1988, "The valence band tail state filling in heavily doped and compensated crystals of gallium arsenide," Phys. Status Solidi B 110, 221-226
  25. Donsker, M. D., and S. R. S. Varadhan, 1975, in Functional Integration and its Applications, edited by A. M. Arthurs (Clarendon, Oxford)
  26. Doob, J. L., 1953, Stochastic Processes (Wiley, New York)
  27. Economou, E. N., 1979, Greens' Functions in Quantum Physics (Springer, Berlin)
  28. Edwards, S. F., 1979, "The density of states of the Schrödinger equation with a random potential," J. Non-Cryst. Solids 32, 113-130
  29. Edwards, S. F., and P. W. Anderson, 1975, "Theory of spin glasses," J. Phys. F 5, 965
  30. Edwards, S. F., and Y. B. Gulyaev, 1964, "The density of states of a highly impure semiconductor," Proc. Phys. Soc. London 83, 495-496
  31. Efros, A. L., 1971, "Theory of electron states in heavily doped semiconductors," Sov. Phys. JETP 32, 479-483
  32. Efros, A. L., 1974 "Density of states and interband absorption of light in strongly doped semiconductors," Sov. Phys. Usp. 16, 789-805
  33. Eymard, R., and G. Duraffourg, 1973, "The impurity density-of-states tails in neutral semiconductors: applications to the diffusion current in GaSb pn junctions," J. Phys. D 6, 66-81
  34. Fetter, A. L., and J. D. Walecka, 1971, Quantum Theory of Many-Particle Systems (McGraw-Hill, New York)
  35. Feynman, R. P., 1955, "Slow electrons in a polar crystal," Phys. Rev. 97, 660-665
  36. Feynman, R. P., 1972, Statistical Mechanics, A Set of Lectures, Frontiers in Physics (Benjamin, Reading, MA)
  37. Feynman, R. P., and A. R. Hibbs, 1965, Quantum Mechanics and Path Integrals (McGraw-Hill, New York)
  38. Friedberg, R., and J. M. Luttinger, 1975, "Density of electronic energy levels in disordered systems," Phys. Rev. B 12, 4460-4474
  39. Frisch, H. L., and S. P. Lloyd, 1960, "Electron levels in a one-dimensional random lattice," Phys. Rev. 120, 1175-1189
  40. Ghazali, A., A. Gold, and J. Serre, 1988, "Impurity bands and band tails in accumulation of inversion layers," Surf. Sci. 196, 346-351
  41. Glaser, E., R. Czaputa, B. D. McCombe, G. M. Kramer, and R. F. Wallis, 1986, "Oxide-charge-induced localized states and screening in a model two-dimensional system," Phys. Rev. Lett. 57, 893-896
  42. Glaser, E., and B. D. McCombe, 1988, "Far-infrared and electrical transport studies of oxide-charge-induced localized states in a quasi-two-dimensional system," Phys. Rev. B 37, 10 769-10 785
  43. Gold, A., J. Serre, and A. Ghazali, 1988, "Density of states in a two-dimensional electron gas: Impurity bands and band tails," Phys. Rev. B 37, 4589-4603
  44. Gross, E. P., "Partition function for an electron in a random potential," J. Stat Phys. 17, 265-287
  45. Gross, E. P., 1983, "Partition function of a particle subject to Gaussian noise," J. Stat. Phys. 33, 107-132
  46. Hafez, I. M., G. Ghibaudo, and F. Balestra, 1990, "Assessment of interface state density in silicon metal-oxide semiconductors at room, liquid-nitrogen, and liquid-helium temperatures," J. Appl. Phys. 67, 1950-1952
  47. Halperin, B. I., 1965, "Green's functions for a particle in a one-dimensional random potential," Phys. Rev. 139, 104A-117A
  48. Halperin, B. I., 1973, "Electronic states in disordered systems," Physica Fennica 8, 215-251
  49. Halperin, B. I., and Melvin Lax, 1966, "Impurity-band tails in the high-density limit. I. Minimum counting methods," Phys. Rev. 148, 722-740
  50. Halperin, B. I., and Melvin Lax, 1967, "Impurity-band tails in the high-density limit. II. Higher-order corrections," Phys. Rev. 153, 802-814
  51. Haug, H., 1988, Optical Nonlinearities and Instabilities in Semiconductors (Academic, New York)
  52. John, S., 1987, "Localization and the density of states for an electron in a quantized elastic continuum," Phys. Rev. B 35, 9291-9294
  53. John, S., and M. J. Stephen, 1984, J. Phys. C 17, L559
  54. John, S., M. Y. Chou, M. H. Cohen, and C. M. Soukoulis, 1988, "Density of states for an electron in a correlated Gaussian random potential: Theory of the Urbach tail," Phys. Rev. B 37, 6963-6976
  55. John, S., and C. H. Grein, 1990, "Instantons, polarons, localization and the Urbach optical absorption edge in disordered semiconductors," Rev. Solid State Sci. 4, 1-59
  56. Kane, E. O., 1963, "Thomas-Fermi approach to impure semiconductor band structure," Phys. Rev. 131, 79-88
  57. Kane, E. O., 1985, "Band tails in semiconductors," Solid-State Electronics 28, 3-10
  58. Keldysh, L. V., and G. P. Proshko, 1964, "Infrared absorption in heavily doped germanium," Sov. Phys. Solid State 5, 2481-2488
  59. Klauder, J. R., 1961, "The modification of electron energy levels by impurity atoms," Ann. Phys. (N.Y.) 14, 43-76
  60. Kubo, R., 1962, J. Phys. Soc. Jpn. 17, 1100
  61. Lax, M., and James C. Philips, 1958, "One-dimensional impurity bands," Phys. Rev. 110, 41-49
  62. Lewis, L. J., and B. Movaghar, 1990, "On the effect of charged centers in crystalline and amorphous semiconductors," Solid State Commun. 75, 885-889
  63. Liebler, J., and H. Haug, 1990, "Theory of the band-tail absorption saturation in polar semiconductors," Phys. Rev. B 41, 5843-5856
  64. Lifshitz, I. M., 1964, "The energy spectrum of disordered systems," Adv. Phys. 13, 483-536
  65. Lifshitz, I. M., 1965, "Energy spectrum structure and quantum states of disordered condensed systems," Sov. Phys. Usp. 7, 549-573
  66. Livescu, G., David A. B. Miller, D. S. Chemla, M. Ramaswamy, T. Y. Chang, Nicholas Sauer, A. C. Gossard, and J. H. English, 1988, "Free carrier and many-body effects in absorption spectra of modulation-doped quantum wells," IEEE J. Quantum Electron. 24, 1677-1689
  67. Lloyd, P., 1969, "Exactly solvable model of electronic states in a three-dimensional disordered Hamiltonian: Nonexistence of localized states," J. Phys. C 2, 1717-1725
  68. Lloyd, P., and P. R. Best, 1975, "A variational approach to disordered systems," J. Phys. C 8, 3725-3766
  69. Madelung, O., 1981, Introduction to Solid-State Theory (Springer, Berlin)
  70. Mahan, G. D., 1986, Many-Particle Physics (Plenum, New York)
  71. Mézard, M., G. Parisi, and M. A. Virasoro, 1987, Spin Glass Theory and Beyond, Lecture Notes in Physics Vol. 9 (World Scientific, Singapore)
  72. Morgan, T. N., 1965, "Broadening of impurity bands in heavily doped semiconductors," Phys. Rev. 139, 343A-348A
  73. Morse, P. M., and H. Feshbach, 1978, Methods of Theoretical Physics (McGraw-Hill, New York)
  74. Nitzan, A., K. F. Freed, and M. H. Cohen, 1977, "Renormalization group and critical localization," Phys. Rev. B 15, 4476-4489
  75. Pankove, J. I., 1971, Optical Processes in Semiconductors (Dover, N.Y.)
  76. Parisi, G., 1988, Statistical Field Theory, Frontiers in Physics, (Addison-Wesley, Reading, MA)
  77. Pines, D., and P. Nozières, 1966, The Theory of Quantum Liquids (Benjamin, New York)
  78. Quang, D. N., 1989, "On the theory of Auger recombination in disordered semiconductors," Phys. Status Solidi B 154, 237-248
  79. Reihlen, E. H., M. J. Jou, D. H. Jaw, and G. B. Stringfellow, 1990, "Optical absorption and emission of GaP1xSbx alloys," J. Appl. Phys. 68, 760-767
  80. Rice, S. O., 1944, Bell System Tech. 23, 282
  81. Samathiyakanit, V., 1974, "Path-integral theory of a model disordered system," J. Phys. C 7, 2849-2876
  82. Samathiyakanit, V., and H. R. Glyde, 1973, "Path integral theory of anharmonic crystals," J. Phys. C 6, 1166-1180
  83. Sa-yakanit, V., 1979, "Electron density of states in a Gaussian random potential: Path-integral approach," Phys. Rev. B 19, 2266-2275
  84. Sa-yakanit, V., and H. R. Glyde, 1980, "Impurity-band density of states in heavily doped semiconductors: A variational calculation," Phys. Rev. B 22, 6222-6232
  85. Sa-yakanit, V., W. Sritrakool, and H. R. Glyde, 1982, "Impurity-band density of states in heavily doped semiconductors: Numerical results," Phys. Rev. B 25, 2776-2780
  86. Schmidt, H., 1957, "Disordered one-dimensional crystals," Phys. Rev. 105, 425-441
  87. Sernelius, Bo. E., 1983, "Theoretical high-stress optical birefringence and piezoresistance in heavily doped germanium. Arguments against bandtailing," Phys. Rev. B 27, 6234-6245
  88. Sernelius, Bo. E., 1986, "Band-gap shifts in heavily p-type doped semiconductors of the zincblende and diamond type," Phys. Rev. B 34, 5610-5620
  89. Serre, J., and A. Ghazali, 1983, "From band tailing to impurity-band formation and discussion of localization in doped semiconductors: A multiple-scattering approach," Phys. Rev. B 28, 4704
  90. Serre, J., A. Ghazali, and P. Leroux Hugon, 1981, "Bandtailing in heavily doped semiconductors. Scattering and impurity-concentration-fluctuation effects," Phys. Rev. B 23, 1971-1976
  91. Shklovskii, B. I., and A. L. Efros, 1984, Electronic Properties of Doped Semiconductors (Springer, Berlin)
  92. Silver, M., L. Pautmeier, and H. Bässler, 1989, "On the origin of exponential band tails in amorphous semiconductors," Solid State Commun. 72, 177-180
  93. Slater, J. C., 1949, "Electrons in perturbed periodic lattices," Phys. Rev. 76, 1592-1601
  94. Sritrakool, W., V. Sa-yakanit, and H. R. Glyde, 1986, "Band tails in disordered systems," Phys. Rev. B 33, 1199-1202
  95. Sze, S. M., 1981, Physics of Semiconductor Devices (Wiley, New York)
  96. Takeshima, M., 1983a, "Impurity-band tails based on semiempirical pseudopotentials in heavily doped semiconductors," Phys. Rev. B 27, 2387-2395
  97. Takeshima, M., 1983b, "Effects of impurity-band tails on Auger recombination in semiconductors," Phys. Rev. B 27, 7524-7532
  98. Takeshima, M., 1984, "Semiempirical pseudopotential approach to Green's-function formalism of electronic states in heavily doped semiconductors," Phys. Rev. B 30, 4540-4548
  99. Takeshima, M., 1985, "Green's-Function formalism of electronic states in heavily doped semiconductors and its application to a problem of inter-valence-band absorption," Phys. Rev. B 32, 8066-8070
  100. Takeshima, M., 1986, "Theory of impurity-doping effect on electronic states in a quasi-two-dimensional-structure semiconductor," Phys. Rev. B 33, 4054-4061
  101. Takeshima, M., 1989, "Quantum theory of electronic properties in doped semiconductors by an extension of the method of the bent-band theory," Phys. Rev. B 40, 3090-3111
  102. Tamor, M. A., 1986, "Effects of strong disorder on recombination in a crystalline semiconductor alloy," Solid State Commun. 58, 101-104
  103. Thouless, D. J., 1970, "Anderson's theory of localized states," J. Phys. C 3, 1559-1566
  104. Thouless, D. J., 1986, "Introduction to disorder systems," in Critical Phenomena, Random Systems, Gauge Theories, Les Houches, Session XLIII (1984), edited by K. Osterwalder and R. Stora (North-Holland, Amsterdam, New York), part II, pp. 681-724
  105. Titchmarsh, E. C., 1967, Introduction to the Theory of Fourier Integrals (Clarendon, Oxford)
  106. Urbach, F., 1953, "The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids," Phys. Rev. 92, 1324
  107. Van Mieghem, P., G. Borghs, and R. Mertens, 1991, "Generalized semiclassical model for the density of statees in heavily doped semiconductors," Phys. Rev. B 44, 12 822
  108. Van Mieghem, P., S. Decoutere, G. Borghs, and R. Mertens, 1992, "Influence of majority carrier bandtails on the performance of semiconductor devices," Solid-State Electron. 35, 699-704
  109. Van Mieghem, P., R. P. Mertens, and R. J. Van Overstraeten, 1990a, "Theory of the junction capacitance of an abrupt diode," J. Appl. Phys. 67, 4203-4211
  110. Van Mieghem, P., R. P. Mertens, G. Borghs, and R. J. Van Overstraeten, 1990b, "Band-gap narrowing in GaAs using a capacitance method," Phys. Rev. B 41, 5952-5959
  111. Wang, M. C., and G. E. Uhlenbeck, 1945, "On the theory of the Brownian Motion II," Rev. Mod. Phys. 17, 323-342
  112. Wannier, G. H., 1937, "Structure of electronic excitation levels in insulating crystals," Phys. Rev. 52, 191-197
  113. Wolff, P. A., 1962, "Theory of the band structure of very degenerate semiconductors," Phys. Rev. 126, 405-412
  114. Yamamoto Y., 1983, "AM and FM quantum noise in semiconductor lasers—Part I: Theoretical analysis," IEEE J. Quantum. Electron QE-19, 34-46
  115. Yamamoto, T., M. Kasu, S. Noda, and A. Sasaki, 1990, "Photoluminescent properties and optical absorption of AlAs/GaAs disordered superlattices," J. Appl. Phys. 68, 5318-5323
  116. Yamamoto, Y., S. Saito, and T. Mukai, 1983, "AM and FM quantum noise in semiconductor lasers—Part II: Comparison of theoretical and experimental results for AlGaAs lasers," IEEE J. Quantum Electron. QE-19, 47-58
  117. Ziman, J. M., 1969, "Localization of electrons in ordered and disordered systems. II. Bound bands," J. Phys. C 2, 1230-1247
  118. Ziman, J. M., 1990, Models of Disorder (Cambridge University, Cambridge, England)
  119. Zittartz, J., and J. S. Langer, 1966, "Theory of bound states in a random potential," Phys. Rev. 148, 741-747

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