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Heavy-fermion systems

G. R. Stewart

G. R. Stewart

  • Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545

Rev. Mod. Phys. 56, 755 – Published 1 October, 1984

DOI: https://doi.org/10.1103/RevModPhys.56.755

Abstract

Since the discovery by Steglich et al. (1979) of superconductivity in the high-effective-mass (200me) electrons in CeCu2Si2, the search for and characterization of such "heavy-fermion" systems has been a rapidly growing field of study. The eight heavy-fermion systems known to date include superconductors (CeCu2Si2, UBe13, UPt3), magnets (NpBe13, U2Zn17, UCd11), and materials in which no ordering is observed (CeAl3, CeCu6). These f-electron materials have, in comparison to normal metals, enormous specific heat γ values (450-1600 mJ/mol K2), large values of the low-temperature magnetic susceptibility χ (8-50×103 emu/mol G), maxima in the resistivity at low temperatures with large ρmax values (100-200 μΩ cm), and unusual temperature dependences of their specific heats below 10 K. The three heavy-fermion superconductors show such unusual behavior that the possibility of p-wave pairing of the superconducting electrons, rather than the usual BCS s-wave pairing, cannot be ruled out. This paper reviews the experimental results to date, to serve both as a status report and as a starting point for future research. Several correlations between properties are pointed out, including the observation that a low value of the Wilson ratio (χγ) appears to correlate with the occurrence of superconductivity.

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