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The solid molecular hydrogens in the condensed phase: Fundamentals and static properties

Isaac F. Silvera

Isaac F. Silvera

  • Natuurkundig Laboratorium, Universiteit van Amsterdam, Valckenierstraat 65, 1018 XE Amsterdam, The Netherlands

Rev. Mod. Phys. 52, 393 – Published 1 April, 1980

DOI: https://doi.org/10.1103/RevModPhys.52.393

Abstract

The molecular hydrogens (H2, D2, HD, etc.) form the simplest of all molecular solids. The combination of the light mass, small moment of inertia, weak interactions, and the quasi-metastable ortho-para species result in a fascinating low-temperature behavior that can be understood to a large extent from considerations of first principles. After discussing single molecule properties and intermolecular interactions we discuss in detail the ortho-para properties, conversion and diffusion. This is followed by a description of the crystal structures and the orientational ordering phenomena. The thermodynamic properties are reviewed. The article is concluded with a discussion of the translational ground state of the solid and the effect of the large zero-point motion on the solid state properties. A large number of data are collected in tables and graphs to provide a reference source.

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