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Structure of metal catalysts
Rev. Mod. Phys. 51, 569 – Published 1 July, 1979
DOI: https://doi.org/10.1103/RevModPhys.51.569
Abstract
Metal catalysts are technologically very important. Moreover, these materials are intriguing systems for scientific investigation. In general, metal catalysts are highly dispersed materials, i.e., materials with very high surface areas. The study of these materials with chemical probes including chemisorption and selected catalytic reactions, in conjunction with physical methods such as electron microscopy, x-ray diffraction, photoelectron spectroscopy, and extended x-ray absorption fine-structure spectroscopy, has contributed much to our knowledge of their structures. Metal catalysts considered in this article include systems consisting essentially of a single metal component (monometallic catalysts) and also bimetallic systems, this latter group including metal alloys as well as highly dispersed bimetallic clusters.
References (95)
- Adler, S., and J. J. Keavney, 1960, J. Phys. Chem. 64, 208
- Ahern, S. A., M. J. C. Martin, and W. Sucksmith, 1958, Proc. R. Soc. A 248, 145
- Ashley, C. A., and S. Doniach, 1975, Phys. Rev. B 11, 1279
- Balandin, A. A., 1958, Adv. Catal. Relat. Subj. 10, 96
- Bean, C. P., and J. D. Livingston, 1959, J. Appl. Phys. 30, 120S
- Beelen, J. M., V. Ponec, and W. M. H. Sachtler, 1973, J. Catal. 28, 376
- Bender, M. L., and L. J. Brubacher, 1973, Catalysis and Enzyme Action (McGraw-Hill, New York)
- Best, R. J., and W. W. Russell, 1954, J. Am. Chem. Soc. 76, 838
- Boudart, M., 1968, Kinetics of Chemical Processes (Prentice-Hall, Englewood Cliffs, N.J.), p. 61
- Brown, H. C., and C. A. Brown, 1962, J. Am. Chem. Soc. 84, 1493
- Brunauer, S., P. H. Emmett, and E. Teller, 1938, J. Am. Chem. Soc. 60, 309
- Cadenhead, D. A., and N. J. Wagner, 1968, J. Phys. Chem. 72, 2775
- Carter, J. L., J. A. Cusumano, and J. H. Sinfelt, 1971, J. Catal. 20, 223
- Carter, J. L., and J. H. Sinfelt, 1966, J. Phys. Chem. 70, 3003
- Cimino, A., M. Boudart, and H. S. Taylor, 1954, J. Phys. Chem. 58, 796
- Coles, B. R., 1956, J. Inst. Met. 84, 346
- Dowden, D. A., 1950, J. Chem. Soc. 242
- Eisenberger, P., B. Kincaid, S. Hunter, D. Sayers, E. Stern, and F. W. Lytle, 1974, Proceedings of the IV International Conference on Vacuum U. V. Radiation Physics, Hamburg, July 22-26, 1974 (Pergamon, London), p. 806
- Emmett, P. H., and N. Skau, 1943, J. Am. Chem. Soc. 65, 1029
- Emmett, P. H., and S. Brunauer, 1937, J. Am. Chem. Soc. 59, 310
- Frankenburg, W. G., 1955, in Catalysis, edited by P. H. Emmett (Reinhold, New York), Vol. III, p. 171
- Gruber, H., 1962, J. Phys. Chem. 66, 48
- Haensel, V., 1949a, U. S. Patent 2, 479, 109
- Haensel, V., 1949b, U. S. Patent 2, 479, 110
- Haensel, V., and G. R. Donaldson, 1951, Ind. Eng. Chem. 43, 2102
- Hall, W. K., and P. H. Emmett, 1958, J. Phys. Chem. 62, 816
- Hall, W. K., and P. H. Emmett, 1959, J. Phys. Chem., 63, 1102
- Helms, C. R., 1975, J. Catal. 36, 114
- Helms, C. R., and J. H. Sinfelt, 1978, Surf. Sci. 72, 229
- Kincaid, B. M., 1975, Ph.D. dissertation, Stanford University
- Kincaid, B. M., 1977, J. Appl. Phys. 48, 2684
- Kincaid, B. M., and P. Eisenberger, 1975, Phys. Rev. Lett. 34, 1361
- Klug, H. P., and L. E. Alexander, 1974, X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials (Wiley, New York), 2nd edition, p. 656
- Kokes, R. J., and P. H. Emmett, 1959, J. Am. Chem. Soc. 81, 5032
- Kronig, R. de L., 1931, Z. Phys. 70, 317
- Kronig, R. de L., 1932a, Z. Phys. 75, 191
- Kronig, R. de L., 1932b, Z. Phys. 75, 468
- Lee, P. A., and G. Beni, 1977, Phys. Rev. B 15, 2862
- Lee, P. A., and J. B. Pendry, 1975, Phys. Rev. B 11, 2795
- Lytle, F. W., 1965, in Physics of Non-Crystalline Solids, edited by J. A. Prins (North-Holland, Amsterdam), p. 12
- Lytle, F. W., 1966, in Advances in X-ray Analysis, edited by G. R. Mallett, M. Fay, and W. M. Mueller (Plenum, New York), p. 398
- Lytle, F. W., D. Sayers, and E. Stern, 1975, Phys. Rev. B 11, 4825
- Lytle, F. W., G. H. Via, and J. H. Sinfelt, 1977, J. Chem. Phys. 67, 3831
- McKee, D. W., 1965, Trans. Faraday Soc. 61, 2273
- McKee, D. W., 1967, J. Catal. 8, 240
- Murphree, E. V., C. L. Brown, H. G. M. Fischer, E. J. Gohr, and W. J. Sweeney, 1943, Ind. Eng. Chem. 35, 768
- Pearson, W. B., 1964, A Handbook of Lattice Spacings and Structures of Metals and Alloys (Pergamon, London), p. 704
- Ponec, V., and W. M. H. Sachtler, 1972, J. Catal. 24, 250
- Prestridge, E. B., G. H. Via, and J. H. Sinfelt, 1977, J. Catal. 50, 115
- Prestridge, E. B., and D. J. C. Yates, 1971, Nature (Lond.) 234, 345
- Prettre, M., David Antin1963, Catalysis and Catalysts, translated by (Dover, New York), pp. 69-81
- Raney, M., 1940, Ind. Eng. Chem. 32, 1199
- Rideal, E. K., 1968, Concepts in Catalysis (Academic, London), pp. 4-42
- Sachtler, W. M. H., and P. van der Plank, 1969, Surf. Sci. 18, 62
- Sayers, D. E., 1971, Ph.D. dissertation, University of Washington
- Sayers, D. E., F. W. Lytle, and E. A. Stern, 1970, Adv. X-ray Anal. 13, 248
- Sayers, D. E., F. W. Lytle, and E. A. Stern, 1971, Phys. Rev. Lett. 27, 1204
- Schwab, G. M., 1950, Discuss. Faraday Soc. 8, 166
- Selwood, P. W., 1956, Magnetochemistry (Interscience, New York), 2nd edition, pp. 374-408
- Selwood, P. W., 1962, Adsorption and Collective Paramagnetism (Academic, New York)
- Sinfelt, J. H., 1964, J. Phys. Chem. 68, 344
- Sinfelt, J. H., 1969, Catal. Rev. 3(2), 175
- Sinfelt, J. H., 1972a, Annu. Rev. Mater. Sci. 2, 641
- Sinfelt, J. H., 1972b, in Chem. Eng. News (July 3, 1972 issue) 50, 18
- Sinfelt, J. H., 1972c, J. Catal. 27, 468
- Sinfelt, J. H., 1973a, Adv. Catal. 23, 91
- Sinfelt, J. H., 1973b, J. Catal. 29, 308
- Sinfelt, J. H., 1974a, Catal. Rev.-Sci. Eng. 9(1), 147
- Sinfelt, J. H., 1974b, Crit. Rev. Solid State Sci. 4, 311
- Sinfelt, J. H., 1975, Prog. Solid State Chem. 10(2), 55
- Sinfelt, J. H., 1976a, Platinum Metals Review 20(4), 114
- Sinfelt, J. H., 1976b, U. S. Patent 3,953,368
- Sinfelt, J. H., 1977a, Acc. Chem. Res. 10, 15
- Sinfelt, J. H., 1977b, Science 195, 641
- Sinfelt, J. H., A. E. Barnett, and J. L. Carter, 1971, U. S. Patent 3,617,518
- Sinfelt, J. H., A. E. Barnett, and G. W. Dembinski, 1969, U. S. Patent 3,442,973
- Sinfelt, J. H., J. L. Carter, and D. J. C. Yates, 1972, J. Catal. 24, 283
- Sinfelt, J. H., Y. L. Lam, J. A. Cusumano, and A. E. Barnett, 1976, J. Catal. 42, 227
- Sinfelt, J. H., and G. H. Via, 1979, J. Catal. 56, 1
- Sinfelt, J. H., G. H. Via, and F. W. Lytle, 1978, J. Chem. Phys. 68, 2009
- Sinfelt, J. H., and D. J. C. Yates, 1967, J. Catal. 8, 82
- Sinfelt, J. H., and D. J. C. Yates, 1968, J. Catal. 10, 362
- Spenadel, L., and M. Boudart, 1960, J. Phys. Chem. 64, 204
- Stern, E. A., 1974, Phys. Rev. B 10, 3027
- Stern, E. A., D. E. Sayers, and F. W. Lytle, 1975, Phys. Rev. B 11, 4836
- Taylor, W. F., and J. H. Sinfelt, 1967, U. S. Patent 3,320,182
- Thomson, S. J., and G. Webb, 1968, Heterogeneous Catalysis (Wiley, New York)
- van der Plank, P., and W. M. H. Sachtler, 1967, J. Catal. 7, 300
- Voge, H., and C. R. Adams, 1967, Adv. Catal. Relat. Subj. 17, 151
- Watt, G. W., W. F. Roper, and S. G. Parker, 1951, J. Am. Chem. Soc. 73, 5791
- Weisz, P. B., and C. D. Prater, 1954, Adv. Catal. 6, 143
- Wheeler, A., 1955, in Catalysis, edited by P. H Emmett (Reinhold, New York), Vol. II, p. 105
- Wilson, G. R., and W. K. Hall, 1970, J Catal. 17, 190
- Yates, D. J. C., and J. H. Sinfelt, 1967, J. Catal. 8, 348
- Yates, D. J. C., W. F. Taylor, and J. H. Sinfelt, 1964, J. Am. Chem. Soc. 86, 2996