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X-Ray Wavelengths

J. A. BEARDEN

J. A. BEARDEN

  • The Johns Hopkins University, Baltimore, Maryland

Rev. Mod. Phys. 39, 78 – Published 1 January, 1967

DOI: https://doi.org/10.1103/RevModPhys.39.78

Abstract

Inconsistencies in accepted values (in x units) of x-ray reference lines have recently been demonstrated, although all are supposedly based on "good" calcite crystals. Factors supporting the selection of the W Kα1 line as the X-Ray Wavelength Standard are critically discussed. A review is given of the experimental measurements which are used to establish the wavelength of this line on an absolute angstrom basis. Its value is λ W Kα1=(0.2090100±5 ppm) Å. This may be used to define a new unit, denoted by Å*, such that the W Kα1 wavelength is exactly 0.2090100 Å*; hence 1Å*=1ű5 ppm. The wavelengths of the Ag Kα1, Mo Kα1, Cu Kα1, and the Cr Kα2 have been established as secondary standards with probable error of approximately one part per million. Sixty-one additional x-ray lines have been used as reference values in a comprehensive review and reevaluation of more than 2700 emission and absorption wavelengths. The recommended wavelength values are listed in Å* units together with probable errors; corresponding energies are given in keV. A second table lists the wavelengths in numerical order, and likewise includes their energies in keV.

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