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Evidence of Polaron Formation in Halide Perovskites via Carrier Effective Mass Measurements

Di Bao, Qing Chang, Bingbing Chen, Xiaoxuan Chen, Handong Sun, Yeng Ming Lam, Daming Zhao, Jian-Xin Zhu, and Elbert E.M. Chia

PRX Energy 2, 013001 (2023) - Published 2 February, 2023

A combination of transient spectroscopy techniques provides an estimate of the time-resolved effective carrier mass and carrier-phonon coupling constant in a photovoltaic absorber, here applied to lead-halide perovskites.

Light Harvesting Enhanced by Quantum Ratchet States

Nicholas Werren, Will Brown, and Erik M. Gauger

PRX Energy 2, 013002 (2023) - Published 9 February, 2023

A theoretical study of bio-inspired ring systems demonstrates optical ratcheting as a means to enhance efficiencies of solar energy harvesting devices.

Revisiting the Storage Capacity Limit of Graphite Battery Anodes: Spontaneous Lithium Overintercalation at Ambient Pressure

Cristina Grosu, Chiara Panosetti, Steffen Merz, Peter Jakes, Stefan Seidlmayer, Sebastian Matera, Rüdiger-A. Eichel, Josef Granwehr, and Christoph Scheurer

PRX Energy 2, 013003 (2023) - Published 1 March, 2023

Unexpected experimental and computational evidence of spontaneous lithium overintercalation challenges the currently accepted upper capacity limit of graphite battery anodes.

Relevance of Long Diffusion Lengths for Efficient Halide Perovskite Solar Cells

Samah Akel, Ashish Kulkarni, Uwe Rau, and Thomas Kirchartz

PRX Energy 2, 013004 (2023) - Published 9 March, 2023

Carrier diffusion length is not a reliable indicator of performance in some halide perovskite solar cells; instead, experiments and modeling show that properties of the carrier transport layers limit the performance.

Oxygen-Redox Activity in Non-Lithium-Excess Tungsten-Doped LiNiO2 Cathode

A.S. Menon, B.J. Johnston, S.G. Booth, L. Zhang, K. Kress, B.E. Murdock, G. Paez Fajardo, N.N. Anthonisamy, N. Tapia-Ruiz, S. Agrestini, M. Garcia-Fernandez, K. Zhou, P.K. Thakur, T.L. Lee, A.J. Nedoma, S.A. Cussen, and L.F.J. Piper

PRX Energy 2, 013005 (2023) - Published 13 March, 2023

An experimental study reveals that the same oxidized O2 species appear in conventional layered cathodes as in oxygen-redox-active alkali-excess cathodes.

Energy Conversion Efficiency of the Bulk Photovoltaic Effect

Andreas Pusch, Udo Römer, Dimitrie Culcer, and Nicholas J. Ekins-Daukes

PRX Energy 2, 013006 (2023) - Published 16 March, 2023

Energy conversion efficiency limits for the bulk photovoltaic effect, a mechanism for conversion of light into electricity in solids, are formulated and are more stringent than the Shockley Queisser limit.

Theory of Cation Solvation and Ionic Association in Nonaqueous Solvent Mixtures

Zachary A.H. Goodwin, Michael McEldrew, Boris Kozinsky, and Martin Z. Bazant

PRX Energy 2, 013007 (2023) - Published 23 March, 2023

A simple theory is developed to understand the underlying physical principles of competitive ionic aggregation and solvation for electrolytes in lithium-ion batteries.

Iodine Vacancies do not Cause Nonradiative Recombination in Halide Perovskites

Jingda Zhang, Xie Zhang, Mark E. Turiansky, and Chris G. Van de Walle

PRX Energy 2, 013008 (2023) - Published 24 March, 2023

A systematic first-principles study shows that the iodine vacancy does not lead to strong nonradiative losses in halide perovskites as commonly believed; thus, performance optimization strategies for perovskite solar cells should focus on other defects.

Physics-Guided Machine Learning for Wind-Farm Power Prediction: Toward Interpretability and Generalizability

Navid Zehtabiyan-Rezaie, Alexandros Iosifidis, and Mahdi Abkar

PRX Energy 2, 013009 (2023) - Published 30 March, 2023

A machine-learning model is developed and used to predict the performance of individual wind turbines in wind farms; the strategy leads to an accurate, lightweight, and generalizable data-driven model for wind-farm power prediction.

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