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EDITORIALS AND ANNOUNCEMENTS

Editorial: A Welcoming Home for Applied Science

Jessica Thomas and Michael Thoennessen

Phys. Rev. Materials 6, 100001 (2022) - Published 11 October, 2022

HIGHLIGHTED ARTICLES

Electronegative metal dopants improve switching variability in Al2O3 resistive switching devices

Zheng Jie Tan, Vrindaa Somjit, Cigdem Toparli, Bilge Yildiz, and Nicholas Fang

Phys. Rev. Materials 6, 105002 (2022) - Published 19 October, 2022

Resistive switching random access memories (RRAMs) promise to overcome the limitation of time- and energy-consumption set by increased training demand in the deep neural network. These devices enable the colocation of memory and processing by storing and utilizing information in the form of conductive networks, such as those made of oxygen vacancies. However, the inherent stochastic nature of atomic motion results in poor reliability and high switching variability in these devices, hindering their widespread use. In this paper, the authors propose a method to substantially reduce the switching variability of RRAM devices by doping the RRAM oxide electrolyte with electronegative metals. They find that electronegative metals reduce the oxygen vacancy formation energy, thereby pinning the conductive filament formation along fixed, predictable paths. This improved reliability enables multibit switching and can facilitate integration into large-scale hardware neural networks.

Realization of efficient tuning of the Fermi level in iron-based ferrimagnetic alloys

N. Yamashita, E. Shigematsu, S. Honda, R. Ohshima, M. Shiraishi, and Y. Ando

Phys. Rev. Materials 6, 104405 (2022) - Published 12 October, 2022

Researchers demonstrate room-temperature spin transfer across an interface between an iron-based ferromagnet and a semiconductor, opening a route to creating novel spintronic devices.

Helical microstructures in molluscan biomineralization are a biological example of close packed helices that may form from a colloidal liquid crystal precursor in a twist–bend nematic phase

Katarzyna Berent, Julyan H. E. Cartwright, Antonio G. Checa, Carlos Pimentel, Paula Ramos-Silva, and C. Ignacio Sainz-Díaz

Phys. Rev. Materials 6, 105601 (2022) - Published 17 October, 2022

The shells of some mollusk species have compact helical structures that researchers propose develop from the self-assembly of a liquid-crystalline material.

Transient electron scavengers modulate carrier density at a polar/nonpolar perovskite oxide heterojunction

Widitha S. Samarakoon, Peter V. Sushko, Dooyong Lee, Bharat Jalan, Hua Zhou, Yingge Du, Zhenxing Feng, and Scott A. Chambers

Phys. Rev. Materials 6, 103405 (2022) - Published 19 October, 2022

Modern thin-film synthesis enables the fabrication of heterostructures in which individual phases can consist of as little as one unit cell. In this extreme thin-film limit, point defects can have a measurable effect on the electronic properties. Such is the case for SrTiO3/1 u.c. NdTiO3/SrTiO3(001). Assuming perfect materials and interfaces, 0.5 electrons should drift from the NTO to each STO layer to compensate the interface dipoles that form. However, the actual carrier density is half this value. This paper shows that transient electron scavengers create an electrostatic potential drop that drives defect formation and lowers the carrier density.

Composition-tunable magnon-polaron anomalies in spin Seebeck effects in epitaxial BixY3xFe5O12 films

Takashi Kikkawa, Koichi Oyanagi, Tomosato Hioki, Masahiko Ishida, Zhiyong Qiu, Rafael Ramos, Yusuke Hashimoto, and Eiji Saitoh

Phys. Rev. Materials 6, 104402 (2022) - Published 6 October, 2022

Resonant enhancement of spin Seebeck effect (SSE) due to hybridized magnon-phonon excitation (magnon polarons) was recently observed in Y3Fe5O12 (YIG). The effect appears at high magnetic fields when the phonon dispersions are tangential to the magnon dispersion curve. Here, the authors show that the resonance field can be shifted by ~ 2 Tesla to the lower-field side by the Bi substitution in YIG. The result is attributed to the change in the phonon dispersions by the Bi doping. The authors also observe in Bi0.9Y2.1Fe5O12 an enhancement 500% greater than the background magnonic SSE signal at the low temperature of 3 K. Moreover, anisotropic magnon-polaron transport was found through the longitudinal and nonlocal SSE measurements, which provides a clue to further unraveling the physics of magnon-polaron SSEs.

New Gd-based magnetic compound GdPt2B with a chiral crystal structure

Yoshiki J. Sato, Hikari Manako, Yoshiya Homma, Dexin Li, Ryuji Okazaki, and Dai Aoki

Phys. Rev. Materials 6, 104412 (2022) - Published 24 October, 2022

Chirality, a fundamental property of symmetry, can produce unique magnetic and electronic properties in materials. The discovery of new magnetic compounds with “chirality” leads to the exploration of exotic physical phenomena in chiral crystals. Here, the authors report the discovery and single-crystal growth of a novel Gd-based magnetic compound GdPt2B with a chiral crystal structure. GdPt2B exhibits a magnetic transition at 87 K and shows magnetic properties arising from the competition between ferromagnetic and Dzyaloshinskii-Moriya interactions. These results pave the way for demonstrating novel spin textures, topological electronic states, and exotic transport phenomena in the novel rare-earth-based chiral crystal.

Out-of-plane polarization and topological magnetic vortices in multiferroic CrPSe3

Weiwei Gao, Jijun Zhao, and James R. Chelikowsky

Phys. Rev. Materials 6, L101402 (2022) - Published 19 October, 2022

Intrinsic low-dimensional multiferroic materials are rare, but they have been pursued for years as promising platforms for exploring the coupling between ferroic orders and hosting novel quantum phenomena. Using first-principles density functional theory calculations, the authors show CrPSe3, an experimentally synthesized van der Waals layered material, demonstrates several dynamically stable multiferroic phases, including anti-ferroelectric and ferroelectric phases, which show ferromagnetism and compete with the experimental paraelectric phase. These multiferroic phases have non-negligible Dzyaloshinskii-Moriya interactions that may support chiral spin textures. The small energy barriers and energy differences between phases can be effectively tuned under moderate strain or electric fields. 

LETTERS

Structural and mechanical properties

Coalescence dynamics of prismatic dislocation loops due to vacancy supersaturation

Cameron McElfresh, Nicolas Bertin, Sylvie Aubry, and Jaime Marian

Phys. Rev. Materials 6, L100601 (2022) - Published 5 October, 2022

Towards commonality between shear banding and glass-liquid transition in metallic glasses

Zeng-Yu Yang and Lan-Hong Dai

Phys. Rev. Materials 6, L100602 (2022) - Published 26 October, 2022

Development of new methods for materials

Effect of crystal defects in iron on carbon diffusivity: Analytical model married to atomistics

Sebastián Echeverri Restrepo, Predrag Andric, and Anthony T. Paxton

Phys. Rev. Materials 6, L100801 (2022) - Published 13 October, 2022

Magnetic, ferroelectric, and multiferroic materials

Generation and routing of nanoscale droplet solitons without compensation of magnetic damping

Andrei I. Nikitchenko and Nikolay A. Pertsev

Phys. Rev. Materials 6, L101401 (2022) - Published 5 October, 2022

Out-of-plane polarization and topological magnetic vortices in multiferroic CrPSe3

Weiwei Gao, Jijun Zhao, and James R. Chelikowsky

Phys. Rev. Materials 6, L101402 (2022) - Published 19 October, 2022

Intrinsic low-dimensional multiferroic materials are rare, but they have been pursued for years as promising platforms for exploring the coupling between ferroic orders and hosting novel quantum phenomena. Using first-principles density functional theory calculations, the authors show CrPSe3, an experimentally synthesized van der Waals layered material, demonstrates several dynamically stable multiferroic phases, including anti-ferroelectric and ferroelectric phases, which show ferromagnetism and compete with the experimental paraelectric phase. These multiferroic phases have non-negligible Dzyaloshinskii-Moriya interactions that may support chiral spin textures. The small energy barriers and energy differences between phases can be effectively tuned under moderate strain or electric fields. 

Superconducting materials

Pressure-induced superconductivity in magnetic topological insulator candidate MnSb4Te7

Cuiying Pei (裴翠颖), Ming Xi (席明), Qi Wang (王琦), Wujun Shi (史武军), Juefei Wu (吴珏霏), Lingling Gao (高玲玲), Yi Zhao (赵毅), Shangjie Tian (田尚杰), Weizheng Cao (曹渭征), Changhua Li (李昌华), Mingxin Zhang (张明鑫), Shihao Zhu (朱世豪), Yulin Chen (陈宇林), Hechang Lei (雷和畅), and Yanpeng Qi (齐彦鹏)

Phys. Rev. Materials 6, L101801 (2022) - Published 24 October, 2022

ARTICLES

Crystal growth, crystallization, and kinetics

Single crystal growth of iridates without platinum impurities

Jimin Kim, Hoon Kim, Hyun-Woo J. Kim, Sunwook Park, Jin-Kwang Kim, Junyoung Kwon, Jungho Kim, Hyeong Woo Seo, Jun Sung Kim, and B. J. Kim

Phys. Rev. Materials 6, 103401 (2022) - Published 12 October, 2022

Unusual electric polarization behavior in elemental quasi-two-dimensional allotropes of selenium

Dan Liu, Lin Han, Ran Wei, Shixin Song, Jie Guan, Shuai Dong, and David Tománek

Phys. Rev. Materials 6, 103403 (2022) - Published 14 October, 2022

Benchmarking of different strategies to include anisotropy in a curvature-driven multi-phase-field model

Martin Minar and Nele Moelans

Phys. Rev. Materials 6, 103404 (2022) - Published 18 October, 2022

Transient electron scavengers modulate carrier density at a polar/nonpolar perovskite oxide heterojunction

Widitha S. Samarakoon, Peter V. Sushko, Dooyong Lee, Bharat Jalan, Hua Zhou, Yingge Du, Zhenxing Feng, and Scott A. Chambers

Phys. Rev. Materials 6, 103405 (2022) - Published 19 October, 2022

Modern thin-film synthesis enables the fabrication of heterostructures in which individual phases can consist of as little as one unit cell. In this extreme thin-film limit, point defects can have a measurable effect on the electronic properties. Such is the case for SrTiO3/1 u.c. NdTiO3/SrTiO3(001). Assuming perfect materials and interfaces, 0.5 electrons should drift from the NTO to each STO layer to compensate the interface dipoles that form. However, the actual carrier density is half this value. This paper shows that transient electron scavengers create an electrostatic potential drop that drives defect formation and lowers the carrier density.

Investigation of in-liquid ordering mediated transformations in Al-Sc via ab initio molecular dynamics and unsupervised learning

Deep Choudhuri, Bhaskar S. Majumdar, and Hunter Wilkinson

Phys. Rev. Materials 6, 103406 (2022) - Published 25 October, 2022

Structure and phase transitions of metastable hexagonal uranium thin films

Rebecca Nicholls, Chris Bell, Ross Springell, Gerard H. Lander, and Johann Bouchet

Phys. Rev. Materials 6, 103407 (2022) - Published 28 October, 2022

Structural and mechanical properties

Detection of the onset of yielding and creep failure from digital image correlation

Tero Mäkinen, Agata Zaborowska, Małgorzata Frelek-Kozak, Iwona Jóźwik, Łukasz Kurpaska, Stefanos Papanikolaou, and Mikko J. Alava

Phys. Rev. Materials 6, 103601 (2022) - Published 10 October, 2022

Accurate ab initio modeling of solid solution strengthening in high entropy alloys

Franco Moitzi, Lorenz Romaner, Andrei V. Ruban, and Oleg E. Peil

Phys. Rev. Materials 6, 103602 (2022) - Published 24 October, 2022

Structure and glide of Lomer and Lomer-Cottrell dislocations: Atomistic simulations for model concentrated alloy solid solutions

Anas Abu-Odeh, Tarun Allaparti, and Mark Asta

Phys. Rev. Materials 6, 103603 (2022) - Published 31 October, 2022

Development of new methods for materials

Morphological evolution via surface diffusion learned by convolutional, recurrent neural networks: Extrapolation and prediction uncertainty

Daniele Lanzoni, Marco Albani, Roberto Bergamaschini, and Francesco Montalenti

Phys. Rev. Materials 6, 103801 (2022) - Published 3 October, 2022

Deep learning interatomic potential for Ca-O system at high pressure

Fulun Wu, Feng Zheng, Weibo He, Xinrui Cao, Tie-Yu Lü, Zi-Zhong Zhu, and Shunqing Wu

Phys. Rev. Materials 6, 103802 (2022) - Published 28 October, 2022

Two-dimensional materials

Tunable long-lived exciton lifetime in single-layer two-dimensional LiAlTe2

Hao Dong (董昊), Jinfeng Zhao (赵金峰), Huan Yang (杨欢), and Yujun Zheng (郑雨军)

Phys. Rev. Materials 6, 104001 (2022) - Published 10 October, 2022

Single-dopant band bending fluctuations in MoSe2 measured with electrostatic force microscopy

Megan Cowie, Rikke Plougmann, Zeno Schumacher, and Peter Grütter

Phys. Rev. Materials 6, 104002 (2022) - Published 11 October, 2022

Theoretical exploration of mechanical and superconducting properties of two-dimensional Cairo penta-BP2: A first-principles study

Zhiyuan Wen, Zheng Liu, Jing Zhu, and Shunhong Zhang

Phys. Rev. Materials 6, 104003 (2022) - Published 18 October, 2022

Two-dimensional heterostructures formed by graphenelike ZnO and MgO monolayers for optoelectronic applications

Mahsa Seyedmohammadzadeh, Cem Sevik, and Oğuz Gülseren

Phys. Rev. Materials 6, 104004 (2022) - Published 24 October, 2022

Monolayer C2/mSnX (X=P, As): An in-plane anisotropic two-dimensional direct band gap semiconductor with ultrahigh mobility, ideal IR-VIS light transparency, and high absorbance

Qing-Yuan Chen, Fei-Jie Huang, Ju-Qi Ruan, Tai Ma, Kai Xiong, and Yao He

Phys. Rev. Materials 6, 104005 (2022) - Published 28 October, 2022

Topological and Dirac materials

Electronic structures and stability investigation of large band gap topological insulators MTl4Te3 (M = Cd, Hg)

Ying Li and Gang Xu

Phys. Rev. Materials 6, 104201 (2022) - Published 10 October, 2022

Highly anisotropic magnetism in the vanadium-based kagome metal TbV6Sn6

Ganesh Pokharel, Brenden Ortiz, Juan Chamorro, Paul Sarte, Linus Kautzsch, Guang Wu, Jacob Ruff, and Stephen D. Wilson

Phys. Rev. Materials 6, 104202 (2022) - Published 13 October, 2022

Fermiology of a topological line-nodal compound CaSb2 and its implication to superconductivity: Angle-resolved photoemission study

Chien-Wen Chuang, Seigo Souma, Ayumi Moriya, Kosuke Nakayama, Atsutoshi Ikeda, Mayo Kawaguchi, Keito Obata, Shanta Ranjan Saha, Hidemitsu Takahashi, Shunsaku Kitagawa, Kenji Ishida, Kiyohisa Tanaka, Miho Kitamura, Koji Horiba, Hiroshi Kumigashira, Takashi Takahashi, Shingo Yonezawa, Johnpierre Paglione, Yoshiteru Maeno, and Takafumi Sato

Phys. Rev. Materials 6, 104203 (2022) - Published 24 October, 2022

Momentum-inversion symmetry breaking on the Fermi surface of magnetic topological insulators

Hengxin Tan, Daniel Kaplan, and Binghai Yan

Phys. Rev. Materials 6, 104204 (2022) - Published 27 October, 2022

Magnetic, ferroelectric, and multiferroic materials

Electronic structure and magnetic properties of 3d4f double perovskite material

S. Kundu, A. Pal, Amit Chauhan, K. Patro, K. Anand, S. Rana, V. G. Sathe, Amish G. Joshi, P. Pal, K. Sethupathi, B. R. K. Nanda, and P. Khuntia

Phys. Rev. Materials 6, 104401 (2022) - Published 5 October, 2022

Composition-tunable magnon-polaron anomalies in spin Seebeck effects in epitaxial BixY3xFe5O12 films

Takashi Kikkawa, Koichi Oyanagi, Tomosato Hioki, Masahiko Ishida, Zhiyong Qiu, Rafael Ramos, Yusuke Hashimoto, and Eiji Saitoh

Phys. Rev. Materials 6, 104402 (2022) - Published 6 October, 2022

Resonant enhancement of spin Seebeck effect (SSE) due to hybridized magnon-phonon excitation (magnon polarons) was recently observed in Y3Fe5O12 (YIG). The effect appears at high magnetic fields when the phonon dispersions are tangential to the magnon dispersion curve. Here, the authors show that the resonance field can be shifted by ~ 2 Tesla to the lower-field side by the Bi substitution in YIG. The result is attributed to the change in the phonon dispersions by the Bi doping. The authors also observe in Bi0.9Y2.1Fe5O12 an enhancement 500% greater than the background magnonic SSE signal at the low temperature of 3 K. Moreover, anisotropic magnon-polaron transport was found through the longitudinal and nonlocal SSE measurements, which provides a clue to further unraveling the physics of magnon-polaron SSEs.

Single crystal synthesis and magnetic properties of a Shastry-Sutherland lattice compound BaNd2ZnS5

Brianna R. Billingsley, Madalynn Marshall, Zhixue Shu, Huibo Cao, and Tai Kong

Phys. Rev. Materials 6, 104403 (2022) - Published 7 October, 2022

Stacking dependent ferroelectricity and antiferroelectricity in quasi-one-dimensional oxyhalides NbOX3

Wencong Sun, Ning Ding, Jun Chen, Hai-Peng You, Jin Peng, Shan-Shan Wang, and Shuai Dong

Phys. Rev. Materials 6, 104404 (2022) - Published 10 October, 2022

Realization of efficient tuning of the Fermi level in iron-based ferrimagnetic alloys

N. Yamashita, E. Shigematsu, S. Honda, R. Ohshima, M. Shiraishi, and Y. Ando

Phys. Rev. Materials 6, 104405 (2022) - Published 12 October, 2022

Researchers demonstrate room-temperature spin transfer across an interface between an iron-based ferromagnet and a semiconductor, opening a route to creating novel spintronic devices.

Enhancing voltage-controlled magnetic anisotropy in Fe80B20/MgO/HfO2 thin films by dielectric constant modulation

Hiroshige Onoda, Tomohiro Nozaki, Shingo Tamaru, Takayuki Nozaki, and Shinji Yuasa

Phys. Rev. Materials 6, 104406 (2022) - Published 13 October, 2022

Spin-lattice coupling in magnetocaloric Gd5(Ge,Si)4 alloys by $in$ $situ$ x-ray pair distribution analysis in magnetic field

Valeri Petkov, Tadisetti D. Rao, AM Milinda Abeykoon, Jorge R. Galeano-Cabral, and Kaya Wei

Phys. Rev. Materials 6, 104407 (2022) - Published 13 October, 2022

Competition of magnetocrystalline anisotropy of uranium layers and zigzag chains in UNi0.34Ge2 single crystals

Adam P. Pikul, Maria Szlawska, Xiaxin Ding, Józef Sznajd, Masashi Ohashi, Dorota A. Kowalska, Mathieu Pasturel, and Krzysztof Gofryk

Phys. Rev. Materials 6, 104408 (2022) - Published 14 October, 2022

Density functional theory investigations into the magnetic ordering of U3O8

Sara B. Isbill, Ashley E. Shields, J. L. Niedziela, and Andrew J. Miskowiec

Phys. Rev. Materials 6, 104409 (2022) - Published 19 October, 2022

Electric field control of phonon angular momentum in perovskite BaTiO3

Kevin Moseni, Richard B. Wilson, and Sinisa Coh

Phys. Rev. Materials 6, 104410 (2022) - Published 21 October, 2022

Thermal stability of nanoscale ferroelectric domains by molecular dynamics modeling

Arne J. Klomp, Ruben Khachaturyan, Theophilus Wallis, Karsten Albe, and Anna Grünebohm

Phys. Rev. Materials 6, 104411 (2022) - Published 24 October, 2022

New Gd-based magnetic compound GdPt2B with a chiral crystal structure

Yoshiki J. Sato, Hikari Manako, Yoshiya Homma, Dexin Li, Ryuji Okazaki, and Dai Aoki

Phys. Rev. Materials 6, 104412 (2022) - Published 24 October, 2022

Chirality, a fundamental property of symmetry, can produce unique magnetic and electronic properties in materials. The discovery of new magnetic compounds with “chirality” leads to the exploration of exotic physical phenomena in chiral crystals. Here, the authors report the discovery and single-crystal growth of a novel Gd-based magnetic compound GdPt2B with a chiral crystal structure. GdPt2B exhibits a magnetic transition at 87 K and shows magnetic properties arising from the competition between ferromagnetic and Dzyaloshinskii-Moriya interactions. These results pave the way for demonstrating novel spin textures, topological electronic states, and exotic transport phenomena in the novel rare-earth-based chiral crystal.

Defect control in the Heisenberg-Kitaev candidate material NaRuO2

Brenden R. Ortiz, Paul M. Sarte, Alon H. Avidor, and Stephen D. Wilson

Phys. Rev. Materials 6, 104413 (2022) - Published 26 October, 2022

Semiconducting materials

Phase stability of (AlxGa1x)2O3 polymorphs: A first-principles study

Sai Mu and Chris G. Van de Walle

Phys. Rev. Materials 6, 104601 (2022) - Published 4 October, 2022

Thermal conductivity of AlxGa1xN (0x1) epitaxial layers

Dat Q. Tran, Rosalia D. Carrascon, Motoaki Iwaya, Bo Monemar, Vanya Darakchieva, and Plamen P. Paskov

Phys. Rev. Materials 6, 104602 (2022) - Published 7 October, 2022

Rashba effects in lead-free ferroelectric semiconductor [CH3PH3]SnBr3

Ravi Kashikar, P. S. Ghosh, S. Lisenkov, A. Stroppa, and I. Ponomareva

Phys. Rev. Materials 6, 104603 (2022) - Published 10 October, 2022

Hematite surfaces: Band bending and local electronic states

S. Rostami, N. Seriani, and R. Gebauer

Phys. Rev. Materials 6, 104604 (2022) - Published 10 October, 2022

Quasiparticle self-consistent GW band structures and phase transitions of LiAlO2 in tetrahedrally and octahedrally coordinated structures

Phillip Popp and Walter R. L. Lambrecht

Phys. Rev. Materials 6, 104605 (2022) - Published 11 October, 2022

Band gaps of halide perovskites from a Wannier-localized optimally tuned screened range-separated hybrid functional

Guy Ohad, Dahvyd Wing, Stephen E. Gant, Ayala V. Cohen, Jonah B. Haber, Francisca Sagredo, Marina R. Filip, Jeffrey B. Neaton, and Leeor Kronik

Phys. Rev. Materials 6, 104606 (2022) - Published 13 October, 2022

Resolving decay-time dependent photoluminescence induced by phonon-dressed excitons in ZnO

Ryu Yukawa, Susumu Yamamoto, Ren Arita, Yuki Minami, Kohei Yamanoi, Kenichi Ozawa, Kazuyuki Sakamoto, Toshihiko Shimizu, Nobuhiko Sarukura, and Iwao Matsuda

Phys. Rev. Materials 6, 104607 (2022) - Published 21 October, 2022

Strain effect on the ground-state structure of Sr2SnO4 Ruddlesden-Popper oxides

Hwanhui Yun, Dominique Gautreau, K. Andre Mkhoyan, and Turan Birol

Phys. Rev. Materials 6, 104608 (2022) - Published 21 October, 2022

Calculated electron paramagnetic resonance g tensor and hyperfine parameters for zinc vacancy and N related defects in ZnO

Klichchupong Dabsamut, Adisak Boonchun, and Walter R. L. Lambrecht

Phys. Rev. Materials 6, 104609 (2022) - Published 28 October, 2022

Other electronic materials

Electronic and magnetic properties of intermetallic kagome magnets RV6Sn6(R=TbTm)

Xiaoxiao Zhang, Ziyi Liu, Qi Cui, Qi Guo, Ningning Wang, Lifen Shi, Hua Zhang, Weihua Wang, Xiaoli Dong, Jianping Sun, Zhiling Dun, and Jinguang Cheng

Phys. Rev. Materials 6, 105001 (2022) - Published 10 October, 2022

Electronegative metal dopants improve switching variability in Al2O3 resistive switching devices

Zheng Jie Tan, Vrindaa Somjit, Cigdem Toparli, Bilge Yildiz, and Nicholas Fang

Phys. Rev. Materials 6, 105002 (2022) - Published 19 October, 2022

Resistive switching random access memories (RRAMs) promise to overcome the limitation of time- and energy-consumption set by increased training demand in the deep neural network. These devices enable the colocation of memory and processing by storing and utilizing information in the form of conductive networks, such as those made of oxygen vacancies. However, the inherent stochastic nature of atomic motion results in poor reliability and high switching variability in these devices, hindering their widespread use. In this paper, the authors propose a method to substantially reduce the switching variability of RRAM devices by doping the RRAM oxide electrolyte with electronegative metals. They find that electronegative metals reduce the oxygen vacancy formation energy, thereby pinning the conductive filament formation along fixed, predictable paths. This improved reliability enables multibit switching and can facilitate integration into large-scale hardware neural networks.

Relation between crystal structure and optical properties in the correlated blue pigment YIn1xMnxO3

Valentin Ransmayr, Jan M. Tomczak, and Anna Galler

Phys. Rev. Materials 6, 105003 (2022) - Published 28 October, 2022

Metamaterials, optical, photonic, and plasmonic materials

Emergent anisotropy and textures in two dimensional magnetic arrays

Nanny Strandqvist, Björn Erik Skovdal, Merlin Pohlit, Henry Stopfel, Lisanne van Dijk, Vassilios Kapaklis, and Björgvin Hjörvarsson

Phys. Rev. Materials 6, 105201 (2022) - Published 31 October, 2022

Materials for energy harvesting, storage, and generation

Electrochemical performance of KTiOAsO4 (KTA) in potassium-ion batteries from density-functional theory

A. Bocchini, U. Gerstmann, T. Bartley, H.-G. Steinrück, G. Henkel, and W. G. Schmidt

Phys. Rev. Materials 6, 105401 (2022) - Published 31 October, 2022

Soft, molecular, and amorphous materials

Helical microstructures in molluscan biomineralization are a biological example of close packed helices that may form from a colloidal liquid crystal precursor in a twist–bend nematic phase

Katarzyna Berent, Julyan H. E. Cartwright, Antonio G. Checa, Carlos Pimentel, Paula Ramos-Silva, and C. Ignacio Sainz-Díaz

Phys. Rev. Materials 6, 105601 (2022) - Published 17 October, 2022

The shells of some mollusk species have compact helical structures that researchers propose develop from the self-assembly of a liquid-crystalline material.

Materials for catalysis and electrochemistry

Transition metal atom adsorption on the titanium carbide MXene: Trends across the periodic table for the bare and O-terminated surfaces

Henrique Rocha, José D. Gouveia, and José R. B. Gomes

Phys. Rev. Materials 6, 105801 (2022) - Published 14 October, 2022

Nanomaterials

Dielectric effects, crystal field, and shape anisotropy tuning of the exciton fine structure of halide perovskite nanocrystals

A. Ghribi, S. Ben Radhia, K. Boujdaria, L. Legrand, T. Barisien, M. Chamarro, and C. Testelin

Phys. Rev. Materials 6, 106001 (2022) - Published 3 October, 2022

Fragmentation of faceted crystalline wires

Nan Wang and Alain Karma

Phys. Rev. Materials 6, 106002 (2022) - Published 7 October, 2022

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