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Resonance Transition Probabilities for Third-Row Atoms and Ions (Mgi, Siii-iii, Pii, Piv, Sii-iii, Cliii) Including the Important Correlation Effects

Donald R. Beck and Oktay Sinanoğlu

  • Sterling Chemistry Laboratory, Yale University, New Haven, Connecticut 06520

Phys. Rev. Lett. 28, 945 – Published 10 April, 1972

DOI: https://doi.org/10.1103/PhysRevLett.28.945

Abstract

A new atomic structure theory, which includes all the important correlation effects, is used to calculate f values for the transitions KL 3sa3pb3dcKL 3sa3pb3dc in the species Mgi, Siii-iii, Pii, Piv, Sii-iii, and Cliii. Even for the difficult transitions with f<0.1, the results we report are in good agreement with experiment, in contrast to the order-of-magnitude errors in previously availabel values. A new type of virtual excitation, from the L shell, is found to contribute 30-60% to such total f values.

References (20)

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