Export citation

Export citation

Choose format for download:

Download Citation
  • Invited
  • Access by Xinjiang University

Regime diagram for droplet breakup and phase transition in shock-driven and detonative flows

Lorenzo Angelilli* and Venkat Raman

  • *Contact author: langelil@umich.edu

Phys. Rev. Fluids 11, 100501 – Published 7 October, 2026

DOI: https://doi.org/10.1103/cljr-373d

Abstract

Liquid-fueled detonative flows involve heavily coupled droplet breakup, phase transition, and chemical heat release over extremely short timescales. In rotating detonation engines and related high-speed propulsion systems, whether liquid fuel remains coupled to the leading wave depends not only on droplet size or Weber number, but also on the total work extractable imposed by the compressible flow and the timescale over which vapor becomes available. This work develops a regime diagram for droplet dynamics in shock-driven and detonative environments using two dimensionless groups: a thermodynamic-load coordinate, which measures the ability of the surrounding gas to drive droplet disintegration, and a timescale ratio, which compares phase-change and aerodynamic-response rates. The diagram is constructed using physically based criteria for aerodynamic breakup, compressibility effects, and transcritical or supercritical interfacial behavior. Recent shock-droplet interaction experiments, liquid-fueled detonation studies, and rotating detonation engine data are mapped onto this framework. The resulting classification shows that water droplets generally remain in breakup-dominated regimes, whereas hydrocarbon fuels more readily enter compressible and supercritical-transition regimes where rapid vapor release can couple with detonation heat release. For liquid-fueled rotating detonations, sustained operation is favored when strong thermodynamic loading is combined with phase-change rates fast enough to synchronize vapor production with the wave cycle. The diagram provides a unified interpretation of breakup, vaporization, and sustained two-phase detonation, while highlighting the need for phase-change models valid across all the possible thermodynamic conditions.

Physics Subject Headings (PhySH)

Article Text

References (82)

  1. P. Wolański, W. Balicki, W. Perkowski, and A. Bilar, Experimental research of liquid-fueled continuously rotating detonation chamber, Shock Waves 31, 807 (2021).
  2. K. Ishihara, T. Sato, T. Kimura, K. Nakajima, K. Nakata, N. Itouyama, A. Kawasaki, K. Matsuoka, K. Matsuyama, J. Kasahara, et al., Nitrous oxide/ethanol cylindrical rotating detonation engine for sounding rocket space flight, J. Spacecr. Rockets 62, 44 (2025).
  3. T. Sato, K. Nakata, K. Ishihara, N. Itouyama, K. Matsuoka, J. Kasahara, A. Kawasaki, D. Nakata, H. Eguchi, M. Uchiumi, et al., Combustion structure of a cylindrical rotating detonation engine with liquid ethanol and nitrous oxide, Combust. Flame 264, 113443 (2024).
  4. J. Kasahara, A. Kawasaki, K. Matsuoka, A. Matsuo, I. Funaki, D. Nakata, and M. Uchiumi, Research and development of rotating detonation engine system for the sounding rocket flight experiment S520-31, in AIP Conference Proceedings (AIP Publishing LLC, 2019), Vol. 2121, p. 020001.
  5. K. Ishihara, K. Yoneyama, H. Watanabe, N. Itouyama, A. Kawasaki, K. Matsuoka, J. Kasahara, A. Matsuo, I. Funaki, and K. Higashino, Thrust performance of converging rotating detonation engine compared with steady rocket engine, J. Propul. Power 39, 297 (2023).
  6. S. J. Schuetz, S. Salauddin, V. Malik, T. Rezzag, and K. A. Ahmed, Characterization of the atomization of bipropellant liquid rotating detonation rocket engine injectors with heated and non-heated fuels, in AIAA SCITECH 2025 Forum (AIAA, 2025), p. 0762
  7. S. Prakash, R. Bielawski, V. Raman, K. Ahmed, and J. Bennewitz, Three-dimensional numerical simulations of a liquid RP-2/O2 based rotating detonation engine, Combust. Flame 259, 113097 (2024).
  8. I. Dunn, W. Flores, A. Morales, V. Malik, and K. Ahmed, Carbon-based multi-phase rotating detonation engine, J. Energy Res. Technol. 144, 042101 (2022).
  9. T. Pritschau, A. Karnam, and E. Gutmark, Characterizing acoustic modes in a hollow rotating detonation combustor, Combust. Flame 275, 114057 (2025).
  10. W. Stoddard, A. C. St. George, R. B. Driscoll, V. Anand, and E. J. Gutmark, Experimental validation of expanded centerbodiless RDE design, in 54th AIAA Aerospace Sciences Meeting (AIAA, 2016), p. 0128.
  11. S. Yao, C. Guo, and W. Zhang, Effects of droplet evaporation on the flow field of hydrogen-enhanced rotating detonation engines with liquid kerosene, Int. J. Hydrogen Energy 48, 33335 (2023).
  12. C. Yan, J. Zhao, Y. Tong, B. Wang, C. Shu, W. Nie, and W. Lin, Formation and evolution of the numerical air-breathing rotating detonation fueled by C12H23, Combust. Sci. Technol. 197, 276 (2025).
  13. X. Han, Y. Wang, Q. Zheng, Y. Huang, Q. Xiao, H. Xu, Y. Wu, W. Feng, and C. Weng, Experimental study on propagation, quenching, and re-initiation characteristics of rotating detonation wave with liquid kerosene–oxygen-enriched air, Exp. Therm Fluid Sci. 148, 110984 (2023).
  14. W. Fan, Y. Shi, H. Wen, H. Hu, H. Chen, and B. Wang, Analysis of waves dynamics in a rotating detonation combustor fueled by kerosene, Phys. Fluids 36, 106135 (2024).
  15. S. Luo, Y. Sun, J. Song, and J. Liu, Performance analysis of a hybrid pulse detonation engine using liquid hydrogen as fuel, Int. J. Hydrogen Energy 47, 21537 (2022).
  16. V. Raman, S. Prakash, and M. Gamba, Nonidealities in rotating detonation engines, Annu. Rev. Fluid Mech. 55, 639 (2023).
  17. A. M. Burden, R. F. Burke, T. Rezzag, J. O. Jacobson, S. Schuetz, and K. A. Ahmed, Characterization of injection mixing in the rotating detonation rocket engine, in AIAA SCITECH 2023 Forum (AIAA, 2023), p. 0572.
  18. J. Sosa, R. Burke, K. A. Ahmed, D. J. Micka, J. W. Bennewitz, S. A. Danczyk, E. J. Paulson, and W. A. Hargus Jr., Experimental evidence of H2/O2 propellants powered rotating detonation waves, Combust. Flame 214, 136 (2020).
  19. Y. Zhang, Y. Tian, and J. Le, Review of atomization characteristics of liquid jets in crossflow, Phys. Fluids 36, 021302 (2024).
  20. Z. Kang, Z.-g. Wang, Q. Li, and P. Cheng, Review on pressure swirl injector in liquid rocket engine, Acta Astronaut. 145, 174 (2018).
  21. I. Oshima and A. Sou, Air-blast atomization of a liquid film, J. Fluid Mech. 985, A36 (2024).
  22. M. Patel, J. S. Rubio, D. Shekhtman, N. Parziale, J. Rabinovitch, R. Ni, and J. Capecelatro, Experimental and numerical investigation of inertial particles in underexpanded jets, J. Fluid Mech. 1000, A60 (2024).
  23. J. R. Burr, M. Maybee, B. Bigler, S. Beard, P. Rugel, R. Dave, A. Kastengren, and J. Bennewitz, Detonation enhanced secondary atomization of liquid droplets, ILASS-AMERICAS 2024 (ILASS, 2024).
  24. J. A. Nicholls and A. Ranger, Aerodynamic shattering of liquid drops, AIAA J. 7, 285 (1969).
  25. E. Dabora, K. Ragland, and J. Nicholls, Drop-size effects in spray detonations, in Symposium (International) on Combustion (Elsevier, 1969), Vol. 12, pp. 19–26.
  26. C. W. Kauffman, J. A. Nicholls, and K. Olzmann, The interaction of an incident shock wave with liquid fuel drops, Combust. Sci. Technol. 3, 165 (1971).
  27. M. Ullman, R. Bielawski, and V. Raman, Timescales and statistics of shock-induced droplet breakup, Phys. Rev. Fluids 10, 124301 (2025).
  28. N. Kateris, E. S. Genter, and H. Wang, Shock-initiated fragmentation of n-dodecane nano-droplets: A molecular dynamics study, in 29th International Colloquium on the Dynamics of Explosions and Reactive Systems, SNU Siheung, Korea (Institute for Dynamics of Explosions and Reactive Systems, 2023).
  29. N. Kateris, E. S. Genter, A. S. Jayaraman, and H. Wang, Coupled momentum and energy transfer in strong shock-induced droplet vaporization, in 14th US National Combustion Meeting (Convergent Science, 2025).
  30. S. S. Dammati, A. Poludnenko, N. Kateris, W. Dong, H. Wang, and T. Lu, Numerical simulations of non-ideal spray detonations in jet fuels with a shock-droplet interaction model, in AIAA SCITECH 2025 Forum (AIAA, 2025), p. 0388.
  31. L. Angelilli and V. Raman, A model for detonation-driven droplet combustion, Combust. Flame 290, 115057 (2026).
  32. S. Schroeder, S. Salauddin, A. Morales, M. Moran, R. Hytovick, E. Rigney, and K. Ahmed, Deformation and aerobreakup of RP-2 droplets from hypersonic shock waves, Proc. Combust. Inst. 40, 105338 (2024).
  33. T. Sato and V. Raman, Hydrocarbon fuel effects on non-premixed rotating detonation engine performance, in AIAA Scitech 2019 Forum (AIAA, 2019), p. 2023.
  34. T. Sato and V. Raman, Detonation structure in ethylene/air-based non-premixed rotating detonation engine, J. Propul. Power 36, 752 (2020).
  35. T. Sato, F. Chacon, L. White, V. Raman, and M. Gamba, Mixing and detonation structure in a rotating detonation engine with an axial air inlet, Proc. Combust. Inst. 38, 3769 (2021).
  36. S. Prakash, V. Raman, C. F. Lietz, W. A. Hargus, Jr., and S. A. Schumaker, Numerical simulation of a methane-oxygen rotating detonation rocket engine, Proc. Combust. Inst. 38, 3777 (2021).
  37. S. Prakash and V. Raman, The effects of mixture preburning on detonation wave propagation, Proc. Combust. Inst. 38, 3749 (2021).
  38. F. Chacon and M. Gamba, Study of parasitic combustion in an optically accessible continuous wave rotating detonation engine, in AIAA Scitech 2019 Forum (AIAA, 2019), p. 0473.
  39. F. Chacon, A. Feleo, and M. Gamba, Secondary waves dynamics and their impact on detonation structure in rotating detonation combustors, Shock Waves 31, 675 (2021).
  40. M. Ullman, S. Prakash, S. Barwey, and V. Raman, Detonation structure in the presence of mixture stratification using reaction-resolved simulations, Combust. Flame 264, 113427 (2024).
  41. R. Burke, T. Rezzag, I. Dunn, W. Flores, and K. Ahmed, The effect of premixed stratification on the wave dynamics of a rotating detonation combustor, Int. J. Hydrogen Energy 46, 27816 (2021).
  42. I. B. Dunn, V. Malik, W. Flores, A. Morales, and K. A. Ahmed, Experimental and theoretical analysis of carbon driven detonation waves in a heterogeneously premixed rotating detonation engine, Fuel 302, 121128 (2021).
  43. R. Borghi, Turbulent combustion modelling, Prog. Energy Combust. Sci. 14, 245 (1988).
  44. F. A. Williams, Combustion Theory (CRC Press, 2018).
  45. A. W. Skiba, T. M. Wabel, C. D. Carter, S. D. Hammack, J. E. Temme, and J. F. Driscoll, Premixed flames subjected to extreme levels of turbulence, Part I: Flame structure and a new measured regime diagram, Combust. Flame 189, 407 (2018).
  46. B. Abramzon and W. A. Sirignano, Droplet vaporization model for spray combustion calculations, Int. J. Heat Mass Transf. 32, 1605 (1989).
  47. S. K. Aggarwal, C. Yan, and G. Zhu, Transcritical vaporization of a liquid fuel droplet in a supercritical ambient, Combust. Sci. Technol. 174, 103 (2002).
  48. R. Miller, K. Harstad, and J. Bellan, Evaluation of equilibrium and non-equilibrium evaporation models for many-droplet gas-liquid flow simulations, Int. J. Multiphase Flow 24, 1025 (1998).
  49. A. Chauvin, E. Daniel, A. Chinnayya, J. Massoni, and G. Jourdan, Shock waves in sprays: Numerical study of secondary atomization and experimental comparison, Shock Waves 26, 403 (2016).
  50. S. Sharma, A. P. Singh, S. S. Rao, A. Kumar, and S. Basu, Shock induced aerobreakup of a droplet, J. Fluid Mech. 929, A27 (2021).
  51. A. Sayad, J. Rabinovitch, A. Dworzanczyk, and N. J. Parziale, Numerical modeling of shock induced aerobreakup of a droplet at high Reynolds and Weber number, in AIAA AVIATION 2023 Forum (AIAA, 2023), p. 4249.
  52. S. V. Poplavski, A. V. Minakov, A. A. Shebeleva, and V. M. Boyko, On the interaction of water droplet with a shock wave: Experiment and numerical simulation, Int. J. Multiphase Flow 127, 103273 (2020).
  53. F. Virot, G. Tymen, D. Hébert, J.-L. Rullier, and E. Lescoute, Experimental investigation of the interaction between a water droplet and a shock wave above Mach 4, Shock Waves 33, 369 (2023).
  54. X. Huang and Z. Lin, Study of the mechanism of shock-induced and detonation-induced droplet breakup based on hybrid solvers, Phys. Fluids 36, 086102 (2024).
  55. Z. Huang and H. Zhang, On the interactions between a propagating shock wave and evaporating water droplets, Phys. Fluids 32, 123315 (2020).
  56. Z. Huang, R. Zhu, and M. Davy, The aerodynamic breakup and interactions of evaporating water droplets with a propagating shock wave, Flow Turbul. Combust. 114, 243 (2025).
  57. G. Vadlamudi, A. Aravind, S. J. Rao, and S. Basu, Insights into spatio-temporal dynamics during shock–droplet flame interaction, J. Fluid Mech. 999, A22 (2024).
  58. M. Paudel, J. Keltz, J. A. McFarland, et al., Deformation and acceleration of small droplets at high-speed conditions, Int. J. Multiphase Flow 193, 105372 (2025).
  59. S. Salauddin, A. Morales, R. Hytovick, R. Burke, V. Malik, J. Patten, S. Schroeder, and K. Ahmed, Detonation and shock-induced breakup characteristics of RP-2 liquid droplets: S. Salauddin, et al., Shock Waves 33, 191 (2023).
  60. T. Brown, R. Hytovick, L. Berson, R. Burke, S. Salauddin, and K. Ahmed, Dynamics of mono-size aerosolized liquid fuel detonations, Proc. Combust. Inst. 40, 105416 (2024).
  61. Q. Meng, S. Li, Y. Xu, and H. Zhang, Droplet fragmentation effects on detonations in n-dodecane mists, Combust. Flame 273, 113944 (2025).
  62. C. J. Young, V. O. Duke-Walker, and J. A. McFarland, Droplet breakup and evaporation in liquid-fueled detonations, Exp. Therm Fluid Sci. 160, 111324 (2025).
  63. N. Srinivasan and S. Yang, Simulation of shock-droplet interactions at detonation-relevant conditions using vapor-liquid equilibrium theory, in AIAA SCITECH 2025 Forum (AIAA, 2025), p. 1173.
  64. J.-M. Li, P.-H. Chang, L. Li, Y. Yang, C. J. Teo, and B. C. Khoo, Investigation of injection strategy for liquid-fuel rotating detonation engine, in 2018 AIAA Aerospace Sciences Meeting (AIAA, 2018), p. 0403.
  65. F. A. e. Bykovskii, S. A. Zhdan, and E. F. Vedernikov, Continuous detonation of the liquid kerosene—Air mixture with addition of hydrogen or Syngas, Combust. Explos. Shock Waves 55, 589 (2019).
  66. J. Kindracki, Experimental research on rotating detonation in liquid fuel–gaseous air mixtures, Aerosp. Sci. Technol. 43, 445 (2015).
  67. J. Kindracki, K. Wacko, P. Woźniak, S. Siatkowski, and Ł. Meżyk, Influence of gaseous hydrogen addition on initiation of rotating detonation in liquid fuel–air mixtures, Energies 13, 5101 (2020).
  68. X. Li, J. Li, Q. Qin, W. Jin, and L. Yuan, Experimental study on detonation characteristics of liquid kerosene/air rotating detonation engine, Acta Astronaut. 215, 124 (2024).
  69. H. Liu, F. Song, D. Jin, Z. Yang, S. Xu, and X. Yang, Experimental investigation of kerosene droplet distribution in a linearized rotating detonation engine, Combust. Sci. Technol. 196, 1227 (2024).
  70. H. Meng, Q. Zheng, C. Weng, Y. Wu, W. Feng, G. Xu, and F. Wang, Propagation mode analysis of rotating detonation waves fueled by liquid kerosene, Acta Astronaut. 187, 248 (2021).
  71. S. Zhou, R. Wang, F. Liu, H. Ning, Y. Ma, T. Zhang, and N. Hu, Effects of liquid-fuel temperature on rotating-detonation-wave propagation, Acta Astronaut. 223, 134 (2024).
  72. W. Cao, Q. Liu, F. Wang, and C. Weng, Effects of the droplet size and engine size on two-phase kerosene/air rotating detonation engines in flight operation conditions, Acta Astronaut. 223, 108 (2024).
  73. F. Wang and C. Weng, Numerical research on two-phase kerosene/air rotating detonation engines, Acta Astronaut. 192, 199 (2022).
  74. H. Wen, W. Wei, W. Fan, Q. Xie, and B. Wang, On the propagation stability of droplet-laden two-phase rotating detonation waves, Combust. Flame 244, 112271 (2022).
  75. M. Zhao and H. Zhang, Rotating detonative combustion in partially pre-vaporized dilute n-heptane sprays: Droplet size and equivalence ratio effects, Fuel 304, 121481 (2021).
  76. J. Li, S. Yao, J. Yu, J. Li, Y. Lei, and W. Zhang, Shock interactions and re-initiation mechanism of liquid ethanol-fueled rotating detonation wave, Phys. Fluids 36, 096106 (2024).
  77. J. Li, S. Yao, Y. Lei, J. Yu, and W. Zhang, Characterization of droplet kinematics and spatial distribution in a two-phase ethanol-fueled rotating detonation flow field, Int. J. Hydrogen Energy 102, 260 (2025).
  78. J. Li, S. Yao, Y. Lei, J. Yu, Y. Zhou, and W. Zhang, Experimental investigation of rotating detonation engine fueled by liquid ethanol and oxygen-enriched air, Exp. Therm Fluid Sci. 167, 111494 (2025).
  79. T. Sato, K. Ishihara, K. Yoneyama, S. Ito, N. Itouyama, H. Watanabe, A. Kawasaki, K. Matsuoka, J. Kasahara, A. Matsuo, et al., Experimental research on thrust performance of rotating detonation engine with liquid ethanol and gaseous oxygen, in AIAA AVIATION 2022 Forum (AIAA, 2022), p. 4143.
  80. M. Salvadori, A. Panchal, and S. Menon, Simulation of liquid droplets combustion in a rotating detonation engine, Proc. Combust. Inst. 39, 3063 (2023).
  81. X. Li, W. Jin, J. Li, Q. Yao, Q. Qin, and L. Yuan, Effects of inlet air temperature and mass flow rate on the performance of a liquid kerosene/air rotating detonation ramjet combustor, Acta Astronaut. 238, 495 (2025).
  82. X. Han, Y. Huang, Q. Zheng, Q. Xiao, H. Xu, F. Wang, Y. Wu, W. Feng, and C. Weng, Study of the characteristics and combustion efficiency of liquid kerosene/oxygen-enriched air rotating detonation wave with different modes, Fuel 355, 129424 (2024).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation