Export citation

Export citation

Choose format for download:

Download Citation
  • Access by Xinjiang University

From mixing to displacement of miscible phases in porous media: The role of heterogeneity and inlet pressures

Yahel Eliyahu-Yakir*, Ludmila Abezgauz, and Yaniv Edery

  • *Contact author: yahel.eliyahu-yakir@epfl.ch
  • Contact author: yanivedery@technion.ac.il

Phys. Rev. Fluids 9, 084501 – Published 2 August, 2024

DOI: https://doi.org/10.1103/PhysRevFluids.9.084501

Abstract

Miscible multiphase flow in porous media is a key phenomenon in various industrial and natural processes, such as hydrogen storage and geological carbon sequestration. However, the parameters controlling the patterns of displacement and mixing in these flows are not completely resolved. This study delves into the effects of heterogeneity and inlet pressure on mixing and displacement patterns of low-viscosity miscible phase invasion into a high-viscosity resident phase, that is saturating a porous medium. The findings highlight the substantial influence of inlet pressures and heterogeneity levels in transitioning from uniform to fingering patterns at the pore scale. These phenomena are detectable at the Darcy scale, and their transition from a uniform front to finger formation is effectively marked through a modified Sherwood number. This modified Sherwood number links microscale patterns to physical properties such as velocity distribution, diffusion, and viscosity contrasts. Additionally, the study employs breakthrough curve (BTC) analysis to illustrate the role of higher heterogeneity and inlet pressure in broadening the fluid velocity distribution, leading to the fingering pattern. These research insights provide a nondimensional approach that scales the BTCs, and can serve future models of miscible phase flow in porous media, linking pore-scale dynamics with macroscale Darcy-scale observations.

Physics Subject Headings (PhySH)

Article Text

References (54)

  1. P. Barlow and E. Reichard, Saltwater intrusion in coastal regions of North America, Hydrogeol. J. 18, 247 (2010).
  2. N. Heinemann, J. Alcalde, J. M. Miocic, S. J. Hangx, J. Kallmeyer, C. Ostertag-Henning, A. Hassanpouryouzband, E. M. Thaysen, G. J. Strobel, C. Schmidt-Hattenberger, Enabling large-scale hydrogen storage in porous media–the scientific challenges, Energy Environ. Sci. 14, 853 (2021).
  3. S. Krevor, H. De Coninck, S. E. Gasda, N. S. Ghaleigh, V. de Gooyert, H. Hajibeygi, R. Juanes, J. Neufeld, J. J. Roberts, and F. Swennenhuis, Subsurface carbon dioxide and hydrogen storage for a sustainable energy future, Nat. Rev. Earth Environ. 4, 102 (2023).
  4. R. J. Glass, J.-Y. Parlange, and T. S. Steenhuis, Wetting front instability: 1. Theoretical discussion and dimensional analysis, Water Resour. Res. 25, 1187 (1989).
  5. B. Pan, X. Yin, Y. Ju, and S. Iglauer, Underground hydrogen storage: Influencing parameters and future outlook, Adv. Colloid Interface Sci. 294, 102473 (2021).
  6. C. Tan and G. Homsy, Stability of miscible displacements in porous media: Rectilinear flow, Phys. Fluids 29, 3549 (1986).
  7. R. Moosavi, A. Kumar, A. De Wit, and M. Schröter, Influence of mineralization and injection flow rate on flow patterns in three-dimensional porous media, Phys. Chem. Chem. Phys. 21, 14605 (2019).
  8. M. A. Celia, J. M. Nordbotten, S. Bachu, M. Dobossy, and B. Court, Risk of leakage versus depth of injection in geological storage, Energy Procedia 1, 2573 (2009) .
  9. H. Deng, B. R. Ellis, C. A. Peters, J. P. Fitts, D. Crandall, and G. S. Bromhal, Modifications of carbonate fracture hydrodynamic properties by CO2-acidified brine flow, Energy Fuels 27, 4221 (2013).
  10. Y. Edery, M. Stolar, G. Porta, and A. Guadagnini, Feedback mechanisms between precipitation and dissolution reactions across randomly heterogeneous conductivity fields, Hydrol. Earth Syst. Sci. 25, 5905 (2021).
  11. E. Shavelzon and Y. Edery, Shannon entropy of transport self-organization due to dissolution/precipitation reaction at varying Peclet number in an initially homogeneous porous media, Hydrol. Earth Syst. Sci. Discuss. 28, 1803 (2024).
  12. B. Ellis, C. Peters, J. Fitts, G. Bromhal, D. McIntyre, R. Warzinski, and E. Rosenbaum, Deterioration of a fractured carbonate caprock exposed to CO2-acidified brine flow, Greenhouse Gases Sci. Technol. 1, 248 (2011).
  13. R. G. Fagin and C. H. Stewart, Jr., A new approach to the two-dimensional multiphase reservoir simulator, Soc. Pet. Eng. J. 6, 175 (1966).
  14. A. Birtles and M. Reeves, Computer modelling of regional groundwater systems in the confined-unconfined flow regime, J. Hydrol. 34, 97 (1977).
  15. G. M. Homsy, Viscous fingering in porous media, Annu. Rev. Fluid Mech. 19, 271 (1987).
  16. L. Paterson, Fingering with miscible fluids in a Hele Shaw cell, Phys. Fluids 28, 26 (1985).
  17. P. King, The fractal nature of viscous fingering in porous media, J. Phys. A: Math. Gen. 20, L529 (1987).
  18. J.-D. Chen, Radial viscous fingering patterns in Hele-Shaw cells, Exp. Fluids 5, 363 (1987).
  19. M. Hopp-Hirschler, M. S. Shadloo, and U. Nieken, Viscous fingering phenomena in the early stage of polymer membrane formation, J. Fluid Mech. 864, 97 (2019).
  20. R. Luo, Y. Chen, and S. Lee, Particle-induced viscous fingering: Review and outlook, Phys. Rev. Fluids 3, 110502 (2018).
  21. D. Pritchard, The linear stability of double-diffusive miscible rectilinear displacements in a Hele-Shaw cell, Eur. J. Mech., B: Fluids 28, 564 (2009).
  22. S. Pramanik, A. De Wit, and M. Mishra, Viscous fingering and deformation of a miscible circular blob in a rectilinear displacement in porous media, J. Fluid Mech. 782, R2 (2015).
  23. S. Nand, V. Sharma, S. K. Das, S. S. Padhee, and M. Mishra, Effect of Hele–Shaw cell gap on radial viscous fingering, Sci. Rep. 12, 18967 (2022).
  24. J.-C. Bacri, D. Salin, and R. Woumeni, Three-dimensional miscible viscous fingering in porous media, Phys. Rev. Lett. 67, 2005 (1991).
  25. L. Paterson, Radial fingering in a Hele Shaw cell, J. Fluid Mech. 113, 513 (1981).
  26. R. L. Slobod and R. A. Thomas, Effect of transverse diffusion on fingering in miscible-phase displacement, Soc. Pet. Eng. J. 3, 9 (1963).
  27. C. Nicolaides, B. Jha, L. Cueto-Felgueroso, and R. Juanes, Impact of viscous fingering and permeability heterogeneity on fluid mixing in porous media, Water Resour. Res. 51, 2634 (2015).
  28. H. S. Rabbani, D. Or, Y. Liu, C.-Y. Lai, N. B. Lu, S. S. Datta, H. A. Stone, and N. Shokri, Suppressing viscous fingering in structured porous media, Proc. Natl. Acad. Sci. USA 115, 4833 (2018).
  29. B. Zhao, C. W. MacMinn, and R. Juanes, Wettability control on multiphase flow in patterned microfluidics, Proc. Natl. Acad. Sci. USA 113, 10251 (2016).
  30. B. Levaché and D. Bartolo, Revisiting the Saffman-Taylor experiment: Imbibition patterns and liquid-entrainment transitions, Phys. Rev. Lett. 113, 044501 (2014).
  31. B. Berkowitz, H. Scher, and S. Stephen, Correction to “Anomalous transport in laboratory-scale, heterogeneous porous media”, Water Resour. Res. 36, 1371 (2000).
  32. A. Dagan and Y. Edery, Bifurcating paths: The relation between preferential pathways, channel splitting, under sampled regions, and tortuosity on the darcy scale, Adv. Water Resour. 184, 104622 (2024).
  33. S. S. Gopalakrishnan, J. Carballido-Landeira, A. De Wit, and B. Knaepen, Relative role of convective and diffusive mixing in the miscible Rayleigh-Taylor instability in porous media, Phys. Rev. Fluids 2, 012501(R) (2017).
  34. B. Jha, L. Cueto-Felgueroso, and R. Juanes, Fluid mixing from viscous fingering, Phys. Rev. Lett. 106, 194502 (2011).
  35. M. C. Kim and S. Pramanik, Miscible viscous fingering in a packed cylindrical column: Theory and numerics, Phys. Rev. Fluids 8, 013901 (2023).
  36. Q. Yuan, B. Ling, and S. A. Aryana, New phase diagram of miscible viscous fingering instabilities in porous media with dead-end pores, Phys. Fluids 34, 092109 (2022).
  37. T. Lei and K. H. Luo, Pore-scale simulation of miscible viscous fingering with dissolution reaction in porous media, Phys. Fluids 33, 034134 (2021).
  38. S. Afshari, S. H. Hejazi, and A. Kantzas, Role of medium heterogeneity and viscosity contrast in miscible flow regimes and mixing zone growth: A computational pore-scale approach, Phys. Rev. Fluids 3, 054501 (2018).
  39. M. Barzan and F. Hajiesmaeilbaigi, Investigation the concentration effect on the absorption and fluorescence properties of Rhodamine 6G dye, Optik 159, 157 (2018).
  40. M. Sahimi, Flow phenomena in rocks: From continuum models to fractals, percolation, cellular automata, and simulated annealing, Rev. Mod. Phys. 65, 1393 (1993).
  41. K. Alim, S. Parsa, D. A. Weitz, and M. P. Brenner, Local pore size correlations determine flow distributions in porous media, Phys. Rev. Lett. 119, 144501 (2017).
  42. Z. Alhashmi, M. Blunt, and B. Bijeljic, The impact of pore structure heterogeneity, transport, and reaction conditions on fluid–fluid reaction rate studied on images of pore space, Transp. Porous Media 115, 215 (2016).
  43. B. Bijeljic and M. J. Blunt, Pore-scale modeling and continuous time random walk analysis of dispersion in porous media, Water Resour. Res. 42, 2005WR004578 (2006).
  44. B. Bijeljic, A. Raeini, P. Mostaghimi, and M. J. Blunt, Predictions of non-Fickian solute transport in different classes of porous media using direct simulation on pore-scale images, Phys. Rev. E 87, 013011 (2013).
  45. Y. Edery, I. Dror, H. Scher, and B. Berkowitz, Anomalous reactive transport in porous media: Experiments and modeling, Phys. Rev. E 91, 052130 (2015).
  46. S. Aramideh, P. P. Vlachos, and A. M. Ardekani, Pore-scale statistics of flow and transport through porous media, Phys. Rev. E 98, 013104 (2018).
  47. P. K. Kang, P. De Anna, J. P. Nunes, B. Bijeljic, M. J. Blunt, and R. Juanes, Pore-scale intermittent velocity structure underpinning anomalous transport through 3-D porous media, Geophys. Res. Lett. 41, 6184 (2014).
  48. B. Bijeljic, P. Mostaghimi, and M. J. Blunt, Signature of non-Fickian solute transport in complex heterogeneous porous media, Phys. Rev. Lett. 107, 204502 (2011).
  49. Y. Edery, S. Geiger, and B. Berkowitz, Structural controls on anomalous transport in fractured porous rock, Water Resour. Res. 52, 5634 (2016).
  50. Y. Nishijima and G. Oster, Diffusion in glycerol-water mixture, Bull. Chem. Soc. Jpn. 33, 1649 (1960).
  51. J.-H. Kim, J. A. Ochoa, and S. Whitaker, Diffusion in anisotropic porous media, Transp. Porous Media 2, 327 (1987).
  52. M. Quintard, Diffusion in isotropic and anisotropic porous systems: Three-dimensional calculations, Transp. Porous Media 11, 187 (1993).
  53. M. Quintard and S. Whitaker, Transport in ordered and disordered porous media: Volume-averaged equations, closure problems, and comparison with experiment, Chem. Eng. Sci. 48, 2537 (1993).
  54. S. Beyhaghi and K. Pillai, Estimation of tortuosity and effective diffusivity tensors using closure formulation in a sintered polymer wick during transport of a nondilute, multicomponent liquid mixture, Spec. Top. Rev. Porous Media: Int. J. 2, 267 (2011).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation