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How to make a giant bubble
Phys. Rev. Fluids 5, 013304 – Published 29 January, 2020
DOI: https://doi.org/10.1103/PhysRevFluids.5.013304
Abstract
Using mixtures of soap, water, and long-chain polymers, free-floating soap bubbles can be formed with volumes approaching . Here we investigate how such thin films are created and maintained over time. We show how the extensional rheology is the most important factor in creating the bubble and how polydispersity in molecular weight of the solvated polymers leads to better performance at lower concentrations. Additionally, using IR absorption, we measure soap film thickness profiles and film lifetimes. Although the initial thickness mostly depends on the choice of detergent, polymers can dramatically increase film lifetime at high molecular weights and high concentrations, although such high concentrations can inhibit the initial film formation. Thus, the ideal concentration of polymer additives for making giant bubbles requires a robust viscoelastic rheology during extension and is aided by long film lifetimes during gravitational drainage and evaporation.
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References (63)
- Guinness World Records, https://www.guinnessworldrecords.com/world-records/largest-free-floating-soap-bubble (accessed 29 June 2019).
- R. E. Goldstein, H. K. Moffatt, A. I. Pesci, and R. L. Ricca, Soap-film Möbius strip changes topology with a twist singularity, Proc. Natl. Acad. Sci. USA 107, 21979 (2010).
- M. Rivera, P. Vorobieff, and R. E. Ecke, Turbulence in Flowing Soap Films: Velocity, Vorticity, and Thickness Fields, Phys. Rev. Lett. 81, 1417 (1998).
- L. Ristroph and J. Zhang, Anomalous Hydrodynamic Drafting of Interacting Flapping Flags, Phys. Rev. Lett. 101, 194502 (2008).
- L. Salkin, A. Schmit, P. Panizza, and L. Courbin, Generating Soap Bubbles by Blowing on Soap Films, Phys. Rev. Lett. 116, 077801 (2016).
- S. Poulain, E. Villermaux, and L. Bourouiba, Ageing and burst of surface bubbles, J. Fluid. Mech. 851, 636 (2018).
- C. Isenberg, Soap films and bubbles, Phys. Educ. 16, 218 (1981).
- G. Rämme, Reflected laser light from a soap bubble—A demonstration experiment, Phys. Educ. 27, 282 (1992).
- G. Rämme, Surface tension from deflating a soap bubble, Phys. Educ. 32, 191 (1997).
- K. Schilling and M. Zessner, Foam in the aquatic environment, Water Res. 45, 4355 (2011).
- Toxic foam floods the streets of Bangalore, https://www.cnn.com/2017/05/31/asia/india-toxic-foam-lake/index.html (accessed 11 July 2019).
- Soap Bubble Wiki, https://soapbubble.fandom.com (accessed 29 June 2019).
- B. Lautrup, Physics of Continuous Matter, 2nd ed. (CRC, Boca Raton, 2011).
- P. G. de Gennes, “Young” soap films, Langmuir 17, 2416 (2001).
- P.-G. de Gennes, F. Brochard-Wyart, and D. Quéré, Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves, 1st ed. (Springer, New York, 2004).
- C. Cohen, B. D. Texier, E. Reyssat, J. H. Snoeijer, D. Quéré, and C. Clanet, On the shape of giant soap bubbles, Proc. Natl. Acad. Sci. USA 114, 2515 (2017).
- D. Mudgil, S. Barak, and B. S. Khatkar, Guar gum: Processing, properties and food applications—A review, J. Food Sci. Technol. 51, 409 (2014).
- J. C. Burton, F. M. Huisman, P. Alison, D. Rogerson, and P. Taborek, Experimental and numerical investigation of the equilibrium geometry of liquid lenses, Langmuir 26, 15316 (2010).
- E. A. van Nierop, B. Scheid, and H. A. Stone, On the thickness of soap films: An alternative to Frankel's law, J. Fluid Mech. 602, 119 (2008).
- B. H. Zimm, Dynamics of polymer molecules in dilute solution: Viscoelasticity, flow birefringence and dielectric loss, J. Chem. Phys. 24, 269 (1956).
- C. Wagner, Y. Amarouchene, D. Bonn, and J. Eggers, Droplet Detachment and Satellite Bead Formation in Viscoelastic Fluids, Phys. Rev. Lett. 95, 164504 (2005).
- C. Clasen, J. P. Plog, W.-M. Kulicke, M. Owens, C. Macosko, L. E. Scriven, M. Verani, and G. H. McKinley, How dilute are dilute solutions in extensional flows? J. Rheol. 50, 849 (2006).
- L. Palangetic, N. K. Reddy, S. Srinivasan, R. E. Cohen, G. H. McKinley, and C. Clasen, Dispersity and spinnability: Why highly polydisperse polymer solutions are desirable for electrospinning, Polymer 55, 4920 (2014).
- F. Del Giudice, S. J. Haward, and A. Q. Shen, Relaxation time of dilute polymer solutions: A microfluidic approach, J. Rheol. 61, 327 (2017).
- G. H. McKinley and T. Sridhar, Filament-stretching rheometry of complex fluids, Annu. Rev. Fluid Mech. 34, 375 (2002).
- J. Dinic, L. N. Jimenez, and V. Sharma, Pinch-off dynamics and dripping-onto-substrate (DoS) rheometry of complex fluids, Lab Chip 17, 460 (2017).
- J. Dinic and V. Sharma, Macromolecular relaxation, strain, and extensibility determine elastocapillary thinning and extensional viscosity of polymer solutions, Proc. Natl. Acad. Sci. USA 116, 8766 (2019).
- J. C. Burton, J. E. Rutledge, and P. Taborek, Fluid pinch-off in superfluid and normal , Phys. Rev. E 75, 036311 (2007).
- P. P. Bhat, S. Appathurai, M. T. Harris, M. Pasquali, G. H. McKinley, and O. A. Basaran, Formation of beads-on-a-string structures during break-up of viscoelastic filaments, Nat. Phys. 6, 625 (2010).
- P. de Sainte Claire, Degradation of PEO in the solid state: A theoretical kinetic model, Macromolecules 42, 3469 (2009).
- S. Morlat and J.-L. Gardette, Phototransformation of water-soluble polymers. I: Photo- and thermooxidation of poly(ethylene oxide) in solid state, Polymer 42, 6071 (2001).
- A. Dupas, I. Hénaut, J.-F. Argillier, and T. Aubry, Mechanical degradation onset of polyethylene oxide used as a hydrosoluble model polymer for enhanced oil recovery, Oil Gas Sci. Technol. 67, 931 (2012).
- B. A. Buchholz, J. M. Zahn, M. Kenward, G. W. Slater, and A. E. Barron, Flow-induced chain scission as a physical route to narrowly distributed, high molar mass polymers, Polymer 45, 1223 (2004).
- A. J. Müller, J. A. Odell, and S. Carrington, Degradation of semidilute polymer solutions in elongational flows, Polymer 33, 2598 (1992).
- R. Holyst, A. Bielejewska, J. Szymański, A. Wilk, A. Patkowski, J. Gapiński, A. Żywociński, T. Kalwarczyk, E. Kalwarczyk, M. Tabaka, N. Ziębacz, and S. A. Wieczorek, Scaling form of viscosity at all length-scales in poly(ethylene glycol) solutions studied by fluorescence correlation spectroscopy and capillary electrophoresis, Phys. Chem. Chem. Phys. 11, 9025 (2009).
- K. Devan and J. C. Selser, Asymptotic behavior and long-range interactions in aqueous solutions of polyethylene oxide), Macromolecules 24, 5943 (1991).
- Q. Ying and B. Chu, Overlap concentration of macromolecules in solution, Macromolecules 20, 362 (1987).
- M. M. Cross, Polymer rheology: Influence of molecular weight and polydispersity, J. Appl. Polym. Sci. 13, 765 (1969).
- W.-M. Kulicke, M. Elasabee, C. D. Eisenbach, and M. Peuscher, Effect of molecular weight and molecular weight distribution on the rheological properties of aqueous poly(ethylene oxide) solution, Polymer Bull. 9, 190 (1983).
- P. K. Bhattacharjee, J. P. Oberhauser, G. H. McKinley, L. G. Leal, and T. Sridhar, Extensional rheometry of entangled solutions, Macromolecules 35, 10131 (2002).
- X. Ye, R. G. Larson, C. Pattamaprom, and T. Sridhar, Extensional properties of monodisperse and bidisperse polystyrene solutions, J. Rheol. 47, 443 (2003).
- X. Ye and T. Sridhar, Effects of the polydispersity on rheological properties of entangled polystyrene solutions, Macromolecules 38, 3442 (2005).
- K. J. Mysels, Soap Films: Studies of Their Thinning, 1st ed. (Pergamon, Oxford, 1959).
- L. Champougny, J. Miguet, R. Henaff, F. Restagno, F. Foulogne, and E. Rio, Influence of evaporation on soap film rupture, Langmuir 34, 3221 (2018).
- L. Saulnier, L. Champougny, G. Bastien, F. Restagno, D. Langevin, and E. Rio, A study of generation and rupture of soap films, Soft Matter 10, 2899 (2014).
- S. Naire, R. J. Braun, and S. A. Snow, An insoluble surfactant model for a vertical draining free film, J. Colloid. Interface Sci. 230, 91 (2000).
- S. Berg, E. A. Adelizzi, and S. M. Troian, Experimental study of entrainment and drainage flows in microscale soap films, Langmuir 21, 3867 (2005).
- L. W. Schwartz and R. V. Roy, Modeling draining flow in mobile and immobile soap films, J. Colloid Interface Sci. 218, 309 (1999).
- D. Langevin, Influence of interfacial rheology on foam and emulsion properties, Adv. Colloid Interface Sci. 88, 209 (2000).
- J. Seiwert, B. Dollet, and I. Cantat, Theoretical study of the generation of soap films: Role of interfacial visco-elasticity, J. Fluid Mech. 739, 124 (2014).
- A. A. Sonin, A. Bonfillon, and D. Langevin, Thinning of soap films: The role of surface viscoelasticity, J. Colloid. Interface Sci. 162, 323 (1994).
- S. Lionti-Addad and J. M. Di Meglio, Stabilization of aqueous foam by hydrosoluble polymers. 1. Sodium dodecyl sulfate-poly(ethylene oxide) system, Langmuir 8, 324 (1992).
- E. A. Adelizzi and S. M. Troian, Interfacial slip in entrained soap films containing associating hydrosoluble polymer, Langmuir 20, 7482 (2004).
- R. Bruinsma, J. M. Di Meglio, D. Quere, and S. Cohen-Addad, Formation of soap films from polymer solutions, Langmuir 8, 3161 (1992).
- S. Cohen-Addad and J.-M. di Meglio, Stabilization of aqueous foam by hydrosoluble polymers. 2. Role of polymer/surfactant interactions, Langmuir 10, 773 (1994).
- X. L. Wu, R. Levine, M. Rutgers, H. Kellay, and W. I. Goldburg, Infrared technique for measuring thickness of a flowing soap film, Rev. Sci. Instrum. 72, 2467 (2001).
- G. Debrégeas, P.-G. de Gennes, and F. Brochard-Wyart, The life and death of “bare” viscous bubbles, Science 279, 1704 (1998).
- M. S. Bhamla, C. Chai, M. A. Àlvarez Valenzuela, J. Tajuelo, and G. G. Fuller, Interfacial mechanisms for stability of surfactant-laden films, PLoS One 12, e0175753 (2017).
- B. H. Cao and M. W. Kim, Molecular weight dependence of the surface tension of aqueous poly(ethylene oxide) solutions, Faraday Discuss. 98, 245 (1994).
- W. Zhang and R. G. Larson, Tension-induced nematic phase separation in bidisperse homopolymer melts, ACS Cent. Sci. 4, 1545 (2018).
- S. M. Clegg, P. A. Williams, P. Warren, and I. D. Robb, Phase behavior of polymers with concentrated dispersions of surfactants, Langmuir 10, 3390 (1994).
- E. Helfand and G. H. Fredrickson, Large Fluctuations in Polymer Solutions Under Shear, Phys. Rev. Lett. 62, 2468 (1989).
- S. T. Milner, Hydrodynamics of Semidilute Polymer Solutions, Phys. Rev. Lett. 66, 1477 (1991).