Export citation

Export citation

Choose format for download:

Download Citation
  • Access by Xinjiang University

Simulations of clean drops rising into a layer of dissolved surfactant

David W. Martin1,*, Tamunotubo George2, and François Blanchette2

  • 1San Bernardino Valley College, 701 S Mt Vernon Ave, San Bernardino, California 92410, USA
  • 2University of California, Merced, 5200 Lake Rd, Merced, California 95343, USA

  • *Corresponding author: dwmath@gmail.com

Phys. Rev. Fluids 4, 014302 – Published 8 January, 2019

DOI: https://doi.org/10.1103/PhysRevFluids.4.014302

Abstract

We present simulations of clean drops rising into a layer of dissolved surfactant. Immediately after entering the surfactant layer, the drop is seen to accelerate suddenly as surfactant adsorbs onto its surface. The drop subsequently slows down to reach a terminal velocity that is between that of a clean drop and that of a solid object. For drops of viscosity equal to that of the ambient fluid, the terminal drop velocity, transition length, and maximal speed are all quantified and plotted against the Biot number, the ratio of convective to desorption timescales, and the adsorption number, the ratio of desorption to adsorption timescales. We find that faster sorption generally results in greater acceleration on entering the surfactant layer, a faster transition to equilibrium, and a faster terminal velocity. Drops of two different Reynolds numbers are considered to investigate the influence of inertial effects.

Physics Subject Headings (PhySH)

Article Text

References (41)

  1. J. S. Hadamard, Mouvement permanent lent d'une sphère liquide et visqueuse dans un liquide visqueux, C. R. Acad. Sci. 152, 1735 (1911).
  2. W. Rybczynski, Über die fortschreitende Bewegung einer flüssigen Kugel in einem zahen Medium, Bull. Acad. Sci. Cracovie A40 (1911).
  3. F. H. Garner and A. H. P. Skelland, Some factors affecting droplet behaviour in liquid-liquid systems, Chem. Eng. Sci. 4, 149 (1955).
  4. E. R. Elzinga and J. T. Banchero, Some observations on the mechanics of drops in liquid-liquid systems, Am. Inst. Chem. Eng. J. 7, 394 (1961).
  5. T. J. Horton, T. R. Fritsch, and R. C. Kintner, Experimental determination of circulation velocities inside drops, Can. J. Chem. Eng. 43, 143 (1965).
  6. A. Frumkin and V. Levich, On surfactants and interfacial motion, Zhur. Fiz. Khim. 21, 1183 (1947).
  7. R. M. Edge and C. D. Grant, The motion of drops in water contaminated with a surface-active agent, Chem. Eng. Sci. 27, 1709 (1972).
  8. T. Yamamoto and T. Ishii, Effect of surface active materials on the drag coefficients and shapes of single large gas bubbles, Chem. Eng. Sci. 42, 1297 (1987).
  9. K. J. Stebe, S. Lin, and C. Maldarelli, Remobilizing surfactant retarded fluid particle interfaces. I. Stress-free conditions at the interfaces of micellar solutions of surfactants with fast sorption kinetics, Phys. Fluids A 3, 3 (1991).
  10. D. A. Saville, The effects of interfacial tension gradients on the motion of drops and bubbles, Chem. Eng. J. 5, 251 (1973).
  11. J. F. Harper, On spherical bubbles rising steadily in dilute surfactant solutions, Q. J. Mech. Appl. Math. 27, 87 (1974).
  12. J. A. Holbrook and M. D. Levan, Retardation of droplet motion by surfactant. Part 1. Theoretical development and asymptotic solutions, Chem. Eng. Commun. 20, 191 (1983).
  13. J. A. Holbrook and M. D. Levan, Retardation of droplet motion by surfactant. Part 2. Numerical solutions for exterior diffusion, surface diffusion, and adsorption kinetics, Chem. Eng. Commun. 20, 273 (1983).
  14. P. Savic, Circulation and Distortion of Liquid Drops Falling through a Viscous Medium (National Research Council Canada, Ottawa, 1953).
  15. R. E. Davis and A. Acrivos, The influence of surfactants on the creeping motion of bubbles, Chem. Eng. Sci. 21, 681 (1966).
  16. J. F. Harper, On bubbles with small immobile adsorbed films rising in liquids at low Reynolds numbers, J. Fluid Mech. 58, 539 (1973).
  17. S. S. Sadhal and R. E. Johnson, Stokes flow past bubbles and drops partially coated with thin films. Part 1. Stagnant cap of surfactant film—Exact solution, J. Fluid Mech. 126, 237 (1983).
  18. Z. He, C. Maldarelli, and Z. Dagan, The size of stagnant caps of bulk soluble surfactant on the interfaces of translating fluid droplets, J. Colloid Interface Sci. 146, 442 (1991).
  19. J. Chen and K. J. Stebe, Marangoni retardation of the terminal velocity of a settling droplet: The role of surfactant physico-chemistry, J. Colloid Interface Sci. 178, 144 (1996).
  20. Y. Wang, D. T. Papageorgiou, and C. Maldarelli, Increased mobility of a surfactant-retarded bubble at high bulk concentrations, J. Fluid Mech. 390, 251 (1999).
  21. R. B. Fdhila and P. C. Duineveld, The effect of surfactant on the rise of a spherical bubble at high Reynolds and Péclet numbers, Phys. Fluids 8, 310 (1996).
  22. R. Palaparthi, D. T. Papageorgiou, and C. Maldarelli, Theory and experiments on the stagnant cap regime in the motion of spherical surfactant-laden bubbles, J. Fluid Mech. 559, 1 (2006).
  23. S. S. Dukhin, V. I. Kovalchuk, G. G. Gochev, M. Lotfi, M. Krzan, K. Malysa, and R. Miller, Dynamics of rear stagnant cap formation at the surface of spherical bubbles rising in surfactant solutions at large Reynolds numbers under conditions of small Marangoni number and slow sorption kinetics, Adv. Colloid Interface Sci. 222, 260 (2015), Reinhard Miller, Honorary Issue.
  24. G. F. Andrews, R. Fike, and S. Wong, Bubble hydrodynamics and mass transfer at high Reynolds number and surfactant concentration, Chem. Eng. Sci. 43, 1467 (1988).
  25. J. B. Mclaughlin, Numerical simulation of bubble motion in water, J. Colloid Interface Sci. 184, 614 (1996).
  26. D. M. Leppinen, M. Renksizbulut, and R. J. Haywood, The effects of surfactants on droplet behavior at intermediate Reynolds-numbers. 1. The numerical-model and steady-state results, Chem. Eng. Sci. 51, 479 (1996).
  27. S. S. Dukhin, M. Lotfi, V. I. Kovalchuk, D. Bastani, and R. Miller, Dynamics of rear stagnant cap formation at the surface of rising bubbles in surfactant solutions at large Reynolds and Marangoni numbers and for slow sorption kinetics, Colloids Surf. A 492, 127 (2016).
  28. S. Tasoglu, U. Demirci, and M. Muradoglu, The effect of soluble surfactant on the transient motion of a buoyancy driven bubble, Phys. Fluids 20, 040805 (2008).
  29. C. H. Chang and E. I. Franses, Modified Langmuir-Hinselwood kinetics for dynamic adsorption of surfactants at the air/water interface, Colloids Surf. 69, 189 (1992).
  30. C. D. Eggleton and K. J. Stebe, An adsorption-desorption-controlled surfactant on a deforming droplet, J. Colloid Interface Sci. 208, 68 (1998).
  31. C. H. Chang and E. I. Franses, Review. adsorption dynamics of surfactants at the air/water interface: A critical review of mathematical models, data, and mechanisms, Colloids Surf. A 100, 1 (1995).
  32. H. A. Stone and L. G. Leal, The effects of surfactants on drop deformation and breakup, J. Fluid Mech. 220, 161 (1990).
  33. D. W. Martin and F. Blanchette, Simulations of surfactant-laden drops rising in a density-stratified medium, Phys. Rev. Fluids 2, 023602 (2017).
  34. B. Lafaurie, C. Nardone, R. Scardovelli, S. Zaleski, and G. Zanetti, Modelling merging and fragmentation in multiphase flows with surfer, J. Computat. Phys. 113, 134 (1994).
  35. S. Popinet and S. Zaleski, A front tracking algorithm for the accurate representation of surface tension, Int. J. Numer. Meth. Fluids 30, 775 (1999).
  36. D. W. Martin and F. Blanchette, Simulations of surfactant effects on the dynamics of coalescing drops and bubbles, Phys. Fluids 27, 012103 (2015).
  37. D. L. Brown, R. Cortez, and M. L. Minion, Accurate projection methods for the incompressible Navier-Stokes equations, J. Computat. Phys. 168, 464 (2001).
  38. F. Blanchette and Y. Lei, Energy considerations for multiphase fluids with variable density and surface tension, SIAM Rev. 51, 423 (2009).
  39. J. C. Padrino, T. Funada, and D. D. Joseph, Purely irrotational theories for the viscous effects on the oscillations of drops and bubbles, Int. J. Multiphas. Flow 34, 61 (2008).
  40. M. R. Booty and M. Siegel, A hybrid numerical method for interfacial fluid flow with soluble surfactant, J. Computat. Phys. 229, 3864 (2010).
  41. F. Blanchette and A. M. Shapiro, Drops settling in sharp stratification with and without Marangoni effects, Phys. Fluids. 23, 042104 (2012).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation