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Coalescence of droplets due to a constant force interaction in a quiescent viscous fluid

John M. Frostad1,*, Alexandra Paul1,2, and L. Gary Leal1

  • 1Department of Chemical Engineering, University of California, Santa Barbara, Santa Barbara, California 93106, USA
  • 2Department of Biophysical Chemistry, Saarland University, Saarbrucken 66123, Germany

  • *Corresponding author: frostad@engineering.ucsb.edu

Phys. Rev. Fluids 1, 033904 – Published 25 July, 2016

DOI: https://doi.org/10.1103/PhysRevFluids.1.033904

Abstract

A cantilevered-capillary force apparatus is used to study the time scale for the coalescence of two droplets compressed together with a constant force. Power-law trends for the coalescence time as a function of droplet radius and compression force are experimentally measured. The measurements are compared against several different scaling theories from the literature. One of the existing theories is found to correctly predict the dependence on the droplet radius, but all of the theories overpredict the dependence on the force. A transition is also observed in the measured drainage time from a small variation around a single deterministic value for droplets with a radius of 125 µm or less to a broad distribution of drainage times for droplets with a radius of 150 µm. A qualitative explanation for this transition is provided via scaling arguments.

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References (36)

  1. A. K. Chesters, The modeling of coalescence processes in fluid-liquid dispersions: a review of current understanding, Chem. Eng. Res. Design 69, 259 (1991).
  2. L. G. Leal, Flow induced coalescence of drops in a viscous fluid, Phys. Fluids 16, 1833 (2004).
  3. P. J. A. Janssen and P. D. Anderson, Modeling film drainage and coalescence of drops in a viscous fluid, Macromol. Mater. Eng. 296, 238 (2011).
  4. Y. Yoon, F. Baldessari, H. D. Ceniceros, and L. G. Leal, Coalescence of two equal-sized deformable drops in an axisymmetric flow, Phys. Fluids 19, 102102 (2007).
  5. B. Dai and L. G. Leal, The mechanism of surfactant effects on drop coalescence, Phys. Fluids 20, 040802 (2008).
  6. S. G. Yiantsios and R. H. Davis, Close appraoch and deformation of two viscous drops due to gravity and van der Waals forces, J. Colloid Interface Sci. 144, 412 (1991).
  7. R. H. Davis, J. A. Schonberg, and J. M. Rallison, The lubrication force between two viscous drops, Phys. Fluids A 1, 77 (1989).
  8. M. A. Rother, A. Z. Zinchenko, and R. H. Davis, Buoyancy-driven coalescence of slightly deformable drops, J. Fluid Mech. 346, 117 (1997).
  9. S. G. Yiantsios and R. H. Davis, On the buoyancy driven motion of a drop towards a rigid surface or a deformable interface, J. Fluid Mech. 217, 547 (1990).
  10. F. Baldessari and L. G. Leal, Effect of overall drop deformation on flow-induced coalescence at low capillary numbers, Phys. Fluids 18, 013602 (2006).
  11. M. B. Nemer, P. Santioro, X. Chen, J. Blawzdziewicz, and M. Loewenberg, Coalescence of drops with mobile interfaces in a quiescent fluid, J. Fluid Mech. 728, 471 (2013).
  12. I. U. Vakarelski, R. Manica, X. Tang, S. J. O’Shea, G. W. Stevens, F. Grieser, R. R. Dagastine, and D. Y. C. Chan, Dynamic interactions between microbubbles in water, Proc. Natl. Acad. Sci. USA 107, 11177 (2010).
  13. R. Manica, J. N. Connor, R. R. Dagastine, S. L. Carnie, R. G. Horn, and D. Y. C. Chan, Hydrodynamic forces involving deformable interfaces at nanometer separations, Phys. Fluids 20, 032101 (2008).
  14. Y. Liao and D. Lucas, A literature review on mechanisms and models for the coalescence process of fluid particles, Chem. Eng. Sci. 65, 2851 (2010).
  15. E. Klaseboer, J. Chevaillier, C. Gourdon, and O. Masbernat, Film drainage between colliding drops at constant approach velocity: Experiments and modeling, J. Colloid Interface Sci. 229, 274 (2000).
  16. L. G. Cascao Pereira, C. Johansson, H. W. Blanch, and C. J. Radke, A bike-wheel microcell for measurement of thin-film forces, Colloids Surf. A 186, 103 (2001).
  17. G. E. Charles and S. G. Mason, The coalescence of liquid drops with flat liquid/liquid interfaces, J. Colloid Sci. 15, 236 (1960).
  18. M. Manga and H. A. Stone, Buoyancy-driven interactions between two deformable viscous drops, J. Fluid Mech. 256, 647 (1993).
  19. H. Yang, C. Park, Y. Hu, and L. Leal, The coalescence of two equal-sized drops in a two-dimensional linear flow, Phys. Fluids 13, 1087 (2001).
  20. H. J. Lockie, R. Manica, G. W. Stevens, F. Grieser, D. Y. C. Chan, and R. R. Dagastine, Precision AFM measurements of dynamic interactions between deformable drops in aqueous surfactant and surfactant-free solutions, Langmuir 27, 2676 (2011).
  21. J. M. Frostad, M. C. Collins, and L. G. Leal, Cantilevered-capillary force apparatus for measuring multiphase fluid interactions, Langmuir 29, 4715 (2013).
  22. L. Wang, D. Sharp, J. Masliyah, and Z. Xu, Measurement of interactions between solid particles, liquid droplets, and/or gas bubbles in a liquid using an integrated thin film drainage apparatus, Langmuir 29, 3594 (2013).
  23. I. B. Bazhlekov, A. K. Chesters, and F. N. van de Vosse, The effect of the dispersed to continuous-phase viscosity ratio on film drainage between interacting drops, Int. J. Multiphase Flow 26, 445 (2000).
  24. A. Zdravkov, G. W. Peters, and H. E. Meijer, Film drainage between two captive drops: PEO-water in silicon oil, J. Colloid Interface Sci. 266, 195 (2003).
  25. G. J. Elfring and E. Lauga, Buckling instability of squeezed droplets, Phys. Fluids 24, 072102 (2012).
  26. A. D. Myshkis, V. G. Babskii, N. D. Kopachevskii, L. A. Slobozhanin, and A. D. Tyuptsov, Low-Gravity Fluid Mechanics: Mathematical Theory of Capillary Phenomena (Springer, Berlin, 2011).
  27. W. Howe, Die rotations-flächen, Ph.D. thesis, Universität zu Berlin, 1887.
  28. R. D. Gillette and D. C. Dyson, Stability of fluid interfaces of revolution between equal solid circular plates, Chem. Eng. J. 2, 44 (1971).
  29. H. Kusumaatmaja and R. Lipowsky, Equilibrium morphologies and effective spring constants of capillary bridges, Langmuir 26, 18734 (2010).
  30. A. Vrij and J. T. G. Overbeek. Rupture of thin liquid films due to spontaneous fluctuations in thickness, J. Am. Chem. Soc. 90, 3074 (1968).
  31. R. J. Gumerman and G. M. Homsy, The stability of radially bounded thin films, Chem. Eng. Commun. 2, 27 (1975).
  32. S. Kaur and L. G. Leal, Three-dimensional stability of a thin film between two approaching drops, Phys. Fluids 21, 072101 (2009).
  33. D. Chappelear, Models of a liquid drop approaching an interface, J. Colloid Sci. 16, 186 (1961).
  34. J. M. Frostad, J. Walter, and L. G. Leal, A scaling relation for the capillary-pressure driven drainage of thin films, Phys. Fluids 25, 052108 (2013).
  35. M. B. Nemer, X. Chen, D. H. Papadopoulos, J. Bławzdziewicz, and M. Loewenberg, Comment on “Two touching spherical drops in uniaxial extensional flow: Analytic solution to the creeping flow problem,” J. Colloid Interface Sci. 308, 1 (2007).
  36. J.-D. Chen, P. S. Hahn, and J. C. Slattery, Coalescence time for a small drop or bubble at a fluid-fluid interface, AIChE J. 30, 622 (1984).

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