• Accepted Paper

Pressure-tuned successive structural distortions and magnetic phase transitions in EuAg4As2

Jin Jiang, Xuliang Chen, Shuyang Wang, Chao An, Yongji Shi, Yong Nie, Xiangde Zhu, Wei Ning, Lili Zhang, Yonghui Zhou, and Zhaorong Yang

Phys. Rev. B - Accepted 1 September, 2026

DOI: https://doi.org/10.1103/b61c-rd2y

Abstract

We examine the structural, vibrational, and transport properties of EuAg4As2 single crystals under pressures up to 28.8-41.8 GPa, aiming to trace the evolution of the structural distortion near Ts~130 K and the two magnetic transitions at TN1~15 K and TN2~9 K. Under ambient conditions, a Raman-active phonon mode centered at 157 cm-1 is observed and identified as having A1g symmetry, and its temperature evolution shows no discernible anomaly across these three transitions. Under pressure, combined synchrotron x-ray diffraction and Raman measurements reveal two structural distortions at Pc1~7 GPa and Pc2~17 GPa. Structural refinements and bond-valence-sum analysis suggest that these transitions mainly involve successive discontinuous modifications of the Ag-As tetrahedra, without changing the average crystal symmetry. Distinct transport and magnetic responses accompany these structural distortions: for P<Pc1, Ts increases while its resistivity anomaly is suppressed, and TN1 and TN2 gradually increases; for Pc1<P<Pc2, high-temperature ferromagnetic-like and low-temperature antiferromagnetic-like states emerge; and for P>Pc2, the resistivity becomes metallic-like, with only a faint broad kink and very weak magnetoresistance comparable to that of traditional metals.

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