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Hopping transport on a fractal: ac conductivity of porous silicon
Phys. Rev. B 51, 2199 – Published 15 January, 1995
DOI: https://doi.org/10.1103/PhysRevB.51.2199
Abstract
We have measured the frequency dependence of the conductivity and the dielectric constant of various samples of porous Si in the regime 1 Hz to 100 kHz at different temperatures. The conductivity data exhibit a strong frequency dependence. When normalized to the dc conductivity, our data obey a universal scaling law, with a well-defined crossover in which the real part of the conductivity σ’ changes from an dependence to being proportional to ω. We explain this in terms of activated hopping in a fractal network. The low-frequency regime is governed by the fractal properties of porous Si, whereas the high-frequency dispersion comes from a broad distribution of activation energies. Calculations using the effective-medium approximation for activated hopping on a percolating lattice give fair agreement with the data.
References (61)
- L. T. Canham, Appl. Phys. Lett. 57, 1046 (1990).
- C. Pickering, M. I. J. Beale, D. J. Robbins, P. J. Pearson and R. Greef, J. Phys. C 17, 6535 (1984).
- A. G. Cullis and L. T. Canham, Nature 353, 335 (1991).
- V. Lehman and U. Gösele, Appl. Phys. Lett. 58, 856 (1991).
- M. I. J. Beale, J. D. Benjamin, M. J. Uren, N. G. Chew and A. G. Cullis, J. Cryst. Growth 73, 622 (1985).
- R. C. Anderson, R. S. Muller and C. W. Tobias, J. Electrochem. Soc. 138, 3450 (1991).
- N. Koshida, Y. Kiuchi, and S. Yosimura, in Proceedings of the 10th Symposium on Photoelectronic Image Devices, London, 1991, edited by B. Morgan (Institute of Physics, Bristol, 1992), p. 377.
- M. Ben Chorin, F. Möller and F. Koch, Phys. Rev. B 49, 2981 (1994).
- R. L. Smith and S. D. Collins, J. Appl. Phys. 7, R1 (1992).
- P. Goudeau, A. Naudon, G. Bomchil and R. Herino, J. Appl. Phys. 66, 625 (1989).
- V. Vezin, P. Goudeau, A. Naudon, A. Halimaoui and G. Bomchil, Appl. Phys. Lett. 60, 2625 (1992).
- B. J. Heuser, S. Spooner, C. J. Glinka, D. L. Gilliam, N. A. Winslow, and M. S. Boley, in Microcrystalline Semiconductors: Materials Science & Devices, edited by P. M. Fauchet, C. C. Tsai, L. T. Canham, I. Shimizu, and Y. Aovagi, MRS Symposia Proceedings No. 283 (Materials Research Society, Pittsburgh, 1993), p. 209.
- N. F. Mott and E. A. Davis, Electronic Processes in NonCrystalline Materials, 2nd ed. (Clarendon Press, Oxford, 1979).
- H. Böttger and V. V. Bryksin, Hopping Conduction in Solids (Akademie Verlag, Berlin, 1985).
- A. K. Jonscher, Nature 267, 673 (1979); Dielectric Relaxation in Solids (Chelsea, London, 1983).
- A. R. Long, Adv. Phys. 31, 553 (1982).
- We use the notation σ(ω)=σ'(ω)+iσ''(ω) for the complex dynamic conductivity.
- J. R. Macdonald, Impedance Spectroscopy (Wiley, New York, 1987).
- D. A. G. Bruggeman, Ann. Phys. (Leipzig) 24, 636 (1935).
- D. J. Bergman, Ann. Phys. (N.Y.) 138, 78 (1981).
- W. Theiss and P. Grosse, in Microcrystalline Semiconductors: Materials Science & Devices (Ref. 12), p. 215.
- K. L. Ngai, Comm. Solid State Phys. 9, 127 (1979).
- J. P. Bouchaud and A. Georges, Phys. Rep. 195, 127 (1990).
- W. Schirmacher, Ber. Bunsenges. Phys. Chem. 95, 368 (1991).
- M. Pollak and T. H. Geballe, Phys. Rev. 122, 1742 (1961); ibid. 6, 1742 (1961).
- J. P. Clerc, G. Giraud, M. M. Laugier and J. M. Luck, Adv. Phys. 39, 191 (1990).
- A. R. Long, in Hopping Transport in Solids, edited by M. Pollak and B. I. Shklovski (North Holland, Amsterdam, 1991), p. 207.
- R. A. Street, G. Davies and A. D. Yoffe, J. Non Cryst. Solids 5, 276 (1971).
- M. Ben Chorin, F. Möller, and F. Koch, in Light Emission from Silicon, edited by J. C. Vial, L. T. Canham, and W. Lang, European Materials Research Society Symp. Proc. Vol. 43 (North Holland, Amsterdam, 1994) [reprinted from J. Lumin. 57, 159 (1993)].
- Physics of Group IV Elements and III V Compounds, edited by O. Madelung, Landolt Börnstein, New Series Group III, Vol. 17, Pt. a (Springer Verlag, Heidelberg, 1982).
- J. Kočka and J. Krištofic, Phys. Status Solidi A 45, 559 (1978).
- W. Schirmacher, Solid State Commun. 39, 893 (1981).
- S. Summerfield, Philos. Mag. B 52, 9 (1985).
- J. Dyre, Phys. Rev. B 47, 9128 (1993).
- For noninteracting carriers in the case of Boltzmann statistics, we have partial n/ partial μ= n/T, and for Fermi statistics partial n/ partial μ=N(), where N() is the density of states at the Fermi level.
- J. P. Hansen and I. R. McDonald, Theory of Simple Liquids, 2nd ed. (Academic Press, London, 1986).
- S. Alexander and R. Orbach, J. Phys. 43, L625 (1982).
- T. Nakayama, K. Yakubo and R. L. Orbach, Rev. Mod. Phys. 66, 381 (1994).
- B. B. Mandelbrot, The Fractal Geometry of Nature (Freeman, New York, 1977).
- D. Stauffer, Introduction to Percolation Theory (Taylor & Francis, London, 1985).
- Y. Gefen, A. Aharony and S. Alexander, Phys. Rev. Lett. 50, 77 (1983)
- The analysis of Gefen et al. (Ref. protect A. Coniglio, M. Daoud and H. J. Herrmann), which is based on the random walk concept adopted in the present paper, has been criticized by , J. Phys. A. 22, 4189 (1989), on the basis of an equivalent network analysis. However, Coniglio et al. did not utilize the equivalent network for the electrochemical potential [which is the correct procedure (Ref. protect et al.)], but that for the electrical potential only. If the correct network is utilized, the results of Gefen are reproduced [W. Schirmacher, J. Phys. A 27, L727 (1994)].
- In the notation of percolation theory (Refs. protect and protect ) tilde μ = μ - β, where μ is the conductivity exponent and β the exponent which belongs to the probability for a site to be on the infinite cluster.
- Since in PS we do not have evidence for variable range hopping (Ref. protect ), we ignore the fluctuations of due to the hopping distances .
- S. Kirkpatrick, Rev. Mod. Phys. 45, 574 (1973).
- R. J. Elliott, J. A. Krumhansl and P. L. Leath, Rev. Mod. Phys. 46, 465 (1974).
- C. R. Gochanour, H. Ch. Andersen and D. M. Fayer, J. Chem. Phys. 70, 4254 (1979).
- B. Movaghar, B. Pohlmann and W. Schirmacher, Solid State Commun. 34, 451 (1980).
- B. Movaghar, B. Pohlmann and G. Sauer, Phys. Status Solidi B 97, 553 (1980).
- B. Movaghar and W. Schirmacher, J. Phys. C 14, 859 (1980).
- S. Summerfield and P. N. Butcher, J. Phys. C 15, 7003 (1982).
- W. Schirmacher, Solid State Ion. 28 30, 129 (1988).
- W. Schirmacher and M. Wagener, in Festkörperprobleme /Advances in Solid State Physics, edited by U. Rössler (Vieweg, Braunschweig, 1991), Vol. 31, p. 39.
- S. Summerfield, Solid State Commun. 39, 401 (1981).
- I. Webman, Phys. Rev. Lett. 47, 1496 (1981).
- T. Odagaki and M. Lax, Phys. Rev. B 24, 5284 (1981).
- E. N. Economou, Green's Functions in Quantum Physics, 2nd ed. (Springer Verlag, Heidelberg, 1990).
- The final saturation of σ '(ω ) → langle rangle is only observed in computer simulations but not in experiments because in the relevant frequency regime ( approx Hz) molecular and atomic polarization phenomena become important.
- J. H. Kaufman, C. K. Baker, A. I. Nazzal, M. Flickner and O. R. Melroy, Phys. Rev. Lett. 56, 1932 (1986).
- D. W. Schaefer, B. J. Olivier, C. S. Ashley, D. Richter, B. Farago, B. Frick, L. Hrubesh, M. J. van Bommel and S. Krueger, J. Noncryst. Sol. 145, 105 (1992).
- A. L. Efros and B. I. Shklovskii, in Electron Electron Interactions in Disordered Systems, edited by A. L. Efros and M. Pollak (North Holland, Amsterdam, 1985).