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Phonon natures in Raman spectra of Y-Ba-Cu-O compounds

Ming-sheng Zhang

Zhen Yin

Gongjian Hu and Qiang Chen

  • Center for Materials Analysis and Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210008, China

  • Physics Department, Nanjing University, Nanjing 210008, China

  • Center for Materials Analysis, Nanjing University, Nanjing 210008, China

Phys. Rev. B 41, 2003 – Published 1 February, 1990

DOI: https://doi.org/10.1103/PhysRevB.41.2003

Abstract

Raman spectra of the superconducting phase and nonsuperconducting phases, which mainly include semiconducting-phase and impurity-phase BaCuO2, are examined in Y-Ba-Cu-O compounds. The doping effects from substitution of copper atoms by impurity atoms are discussed. The substitution of a lighter atom, e.g., vanadium, gives rise to local modes at 810 and 840 cm1, which are qualitatively elucidated by the theory of lattice dynamics in nonideal solids with a local perturbational operator related to the mass-defective coefficient. In tin substitution there is a critical doping xc=1. Above xc the system becomes nonsuperconducting, which could be explained on the basis of band-structure analysis. The emergence of a Raman line at 646 cm1 below T0=234 K shows a phase transition. The discrimination of this line from 640 cm1 in impurity-phase BaCuO2 is clearly made.

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