Phase diagram of <math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mi mathvariant="normal">Li</mi></mrow><mrow><mi mathvariant="normal">x</mi></mrow></msub></mrow></math><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mi mathvariant="normal">Mo</mi></mrow><mrow><mn>6</mn></mrow></msub></mrow></math><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mi mathvariant="normal">Se</mi></mrow><mrow><mn>8</mn></mrow></msub></mrow></math> for 0<x<1 from in situ x-ray studies

J. R. Dahn; W. R. McKinnon

doi:10.1103/PhysRevB.32.3003

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Phase diagram of ${Li}_{x}$ ${Mo}_{6}$ ${Se}_{8}$ for 0<x<1 from in situ x-ray studies

J. R. Dahn and W. R. McKinnon

Solid State Chemistry, Division of Chemistry, National Research Council of Canada, Ottawa, Canada K1A OR9

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Phys. Rev. B 32, 3003 – Published 1 September, 1985

DOI: https://doi.org/10.1103/PhysRevB.32.3003

Abstract

The intercalated Li in ${Li}_{x}$ ${Mo}_{6}$ ${Se}_{8}$ separates into regions of high and low concentration below a critical temperature $T_{c}$ =267 K. The phase diagram agrees with a mean-field solution to a lattice-gas model of intercalation in ${Li}_{x}$ ${Mo}_{6}$ ${Se}_{8}$ . The implications of this agreement are considered.

References (11)

S. T. Coleman, W. R. McKinnon and J. R. Dahn, Phys. Rev. B 29, 4147 (1984).
J. R. Dahn, W. R. McKinnon and S. T. Coleman, Phys. Rev. B 31, 484 (1985).
J. R. Dahn, W. R. McKinnon, J. Murray, R. R. Haering, R. S. McMillan and A. H. Rivers-Bowerman, Phys. Rev. B 32, 3316 (1985).
H. Horner and H. Wagner, J. Phys. C 7, 3305 (1974).
H. Wagner, in Hydrogen in Metals I, edited by G. Alefeld and J. Volkl (Springer, Berlin, 1978), p. 5.
J. R. Dahn, M. A. Py and R. R. Haering, Can. J. Phys. 60, 307 (1982).
We used a Cambion 801-1003-01-00-00 thermoelectric module from Cambridge Thermionic Corporation, Cambridge, Mass. 02238.
H. P. Klug and L. E. Alexander, X-ray Diffraction Procedures (Wiley, New York, 1974).
K. Huang, Statistical Mechanics (Wiley, New York, 1963).
W. R. McKinnon and J. R. Dahn, Phys. Rev. B 31, 3084 (1985).
K. Yvon, in Current Topics in Materials Science, edited by E. Kaldis (North-Holland, Amsterdam, 1979), Vol. 3, p. 53.

[c1] S. T. Coleman, W. R. McKinnon and J. R. Dahn, Phys. Rev. B 29, 4147 (1984).

[c2] J. R. Dahn, W. R. McKinnon and S. T. Coleman, Phys. Rev. B 31, 484 (1985).

[c3] J. R. Dahn, W. R. McKinnon, J. Murray, R. R. Haering, R. S. McMillan and A. H. Rivers-Bowerman, Phys. Rev. B 32, 3316 (1985).

[c4] H. Horner and H. Wagner, J. Phys. C 7, 3305 (1974).

[c5] H. Wagner, in Hydrogen in Metals I, edited by G. Alefeld and J. Volkl (Springer, Berlin, 1978), p. 5.

[c6] J. R. Dahn, M. A. Py and R. R. Haering, Can. J. Phys. 60, 307 (1982).

[c7] We used a Cambion 801-1003-01-00-00 thermoelectric module from Cambridge Thermionic Corporation, Cambridge, Mass. 02238.

[c8] H. P. Klug and L. E. Alexander, X-ray Diffraction Procedures (Wiley, New York, 1974).

[c9] K. Huang, Statistical Mechanics (Wiley, New York, 1963).

[c10] W. R. McKinnon and J. R. Dahn, Phys. Rev. B 31, 3084 (1985).

[c11] K. Yvon, in Current Topics in Materials Science, edited by E. Kaldis (North-Holland, Amsterdam, 1979), Vol. 3, p. 53.

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Phase diagram of ${Li}_{x}$ ${Mo}_{6}$ ${Se}_{8}$ for 0<x<1 from in situ x-ray studies

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Phase diagram of LixMo6Se8 for 0<x<1 from in situ x-ray studies

Abstract

References (11)

Phase diagram of ${Li}_{x}$ ${Mo}_{6}$ ${Se}_{8}$ for 0<x<1 from in situ x-ray studies