Comments on "Magnetic phase transition, aggregate formation, and electrical conductivity in Fe<span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mi mathvariant="normal">Cl</mi></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span>-doped polyacetylene"

A. Pron; Z. Kucharski; P. Bernier; I. Kulszewicz; M. Zagorska; J. Suwalski; D. Billaud

doi:10.1103/PhysRevB.31.4690

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Comments on "Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene"

A. Pron

Z. Kucharski

P. Bernier

I. Kulszewicz and M. Zagorska

J. Suwalski

D. Billaud

Department of Chemistry, Technical University of Warsaw, 00664 Warsaw, Poland

Institute of Atomic Energy, Otwock, Swierk, Poland

Groupe de Dynamique des Phases Condensées, Université des Sciences et Techniques du Languedoc, 34060 Montpellier Cedex, France

Department of Chemistry, Technical University of Warsaw, 00664 Warsaw, Poland

Institute of Atomic Energy, Otwock, Swierk, Poland

Laboratoire de Chimie Minérale Appliquée, Université de Nancy I, 54506 Vandoeuvre les Nancy Cedex, France

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Phys. Rev. B 31, 4690 – Published 1 April, 1985

DOI: https://doi.org/10.1103/PhysRevB.31.4690

Abstract

Mössbauer and chemical analysis studies, of ${(CH)}_{x}$ oxidized chemically with Fe ${Cl}_{3}$ or oxidized electro-chemically in LiCl-Fe ${Cl}_{3}$ -C $H_{3}$ N $O_{2}$ , show that only Fe ${Cl}_{4}^{-}$ species exists in the system. The ${Fe}^{2 +}$ appears either as a degradation product, or as a result of washing with nitromethane that is not properly dried, and forms a separate phase of $Fe {Cl}_{2} \cdot n H_{2} O (n = 1, 2, or 4)$ .

Comments & Replies

Reply to "Comments on `Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene' "

E. K. Sichel

Phys. Rev. B 31, 4692 (1985)

Original Article

Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene

E. K. Sichel, M. F. Rubner, J. Georger, Jr., G. C. Papaefthymiou, S. Ofer, and R. B. Frankel

Phys. Rev. B 28, 6589(R) (1983)

References (9)

E. K. Sichel et al., Phys. Rev. B 28, 6589 (1983)
A. Pron, M. Zagorska, Z. Kucharski, M. Lukasiak, and J. Suwalski, Mater. Res. Bull. 17, 1505 (1982)
J. Przyluski, M. Zagorska, K. Conder, and A. Pron, Polymer 23, 1879 (1982)
Z. Kucharski, M. Lukasiak, J. Suwalski, and A. Pron, J. Phys. (Paris) Colloq. 44, C3-321 (1983)
Z. Kucharski, A. Pron, J. Suwalski, I. Kulszewicz, D. Billaud, and P. Bernier, Solid State Commun. 50, 397 (1984)
H. Sakai, Y. Maeda, T. Kobayashi, and M. Shirakawa, Bull. Chem. Soc. Jpn. 56, 1616 (1983)
Reubenbauer et al., Hyper. Interact. 8, 125 (1979)
S. Chandra and G. R. Hoy, Phys. Lett. 22, 254 (1966)
M. Zagorska, A. Pron, Y. Przyluski, B. Krische, and G. Ahlgren, J. Chem. Soc. Chem. Commun. 1126 (1983)

[c1] E. K. Sichel et al., Phys. Rev. B 28, 6589 (1983)

[c2] A. Pron, M. Zagorska, Z. Kucharski, M. Lukasiak, and J. Suwalski, Mater. Res. Bull. 17, 1505 (1982)

[c3] J. Przyluski, M. Zagorska, K. Conder, and A. Pron, Polymer 23, 1879 (1982)

[c4] Z. Kucharski, M. Lukasiak, J. Suwalski, and A. Pron, J. Phys. (Paris) Colloq. 44, C3-321 (1983)

[c5] Z. Kucharski, A. Pron, J. Suwalski, I. Kulszewicz, D. Billaud, and P. Bernier, Solid State Commun. 50, 397 (1984)

[c6] H. Sakai, Y. Maeda, T. Kobayashi, and M. Shirakawa, Bull. Chem. Soc. Jpn. 56, 1616 (1983)

[c7] Reubenbauer et al., Hyper. Interact. 8, 125 (1979)

[c8] S. Chandra and G. R. Hoy, Phys. Lett. 22, 254 (1966)

[c9] M. Zagorska, A. Pron, Y. Przyluski, B. Krische, and G. Ahlgren, J. Chem. Soc. Chem. Commun. 1126 (1983)

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Comments on "Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene"

Abstract

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Reply to "Comments on `Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene' "

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Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene

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Comments on "Magnetic phase transition, aggregate formation, and electrical conductivity in FeCl3-doped polyacetylene"

Abstract

Comments & Replies

Reply to "Comments on `Magnetic phase transition, aggregate formation, and electrical conductivity in FeCl3-doped polyacetylene' "

Original Article

Magnetic phase transition, aggregate formation, and electrical conductivity in FeCl3-doped polyacetylene

References (9)

Comments on "Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene"

Reply to "Comments on `Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene' "

Magnetic phase transition, aggregate formation, and electrical conductivity in Fe ${Cl}_{3}$ -doped polyacetylene