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Unusual chemisorption behavior of Te on Cu{111} versus Cu {100}

F. Comin, P. H. Citrin, P. Eisenberger*, and J. E. Rowe

  • Bell Laboratories, Murray Hill, New Jersey 07974

  • *Present address: Exxon Research and Engineering, Linden, N.J. 07036.

Phys. Rev. B 26, 7060(R) – Published 15 December, 1982

DOI: https://doi.org/10.1103/PhysRevB.26.7060

Abstract

Surface extended x-ray absorption fine-structure measurements of Te chemisorbed on Cu {111} and Cu {100} surfaces show the adsorbate structures to be remarkably different. Unlike the overlayer occupation of Te in the highest-symmetry hollow sites found here for Cu {100}, the data for Cu {111} indicate substitutional displacement by Te of surface Cu atoms.

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