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Wannier-Slater theorem for solids with nonuniform band structure

C. M. van Vliet*

A. H. Marshak

  • Department of Electrical Engineering, University of Florida, Gainesville, Florida 32611

  • Department of Electrical and Computer Engineering, Louisiana State University, Baton Rouge, Louisiana 70803

  • *On leave from Centre de Recherches des Mathématiques Appliquées, Université de Montréal, Montréal, Québec H3C 3J7, Canada.

Phys. Rev. B 26, 6734 – Published 15 December, 1982

DOI: https://doi.org/10.1103/PhysRevB.26.6734

Abstract

The Wannier-Slater theorem for the Hamiltonian of a solid in an external field of force is generalized for solids with a nonuniform band structure, such as graded-gap mixed semiconductors. Our formulation is related to that of Gora and Williams, and their effectivemass equation is obtained if a k-space Taylor expansion is permissible. This paper extends a too-restricted, earlier discussion by us in connection with transport in position-dependent band structures. The concept of a graded effective mass M and position-dependent band bottom Ec is derived from this treatment. It is pointed out, however, that the concept of a position-dependent effective mass has no strict quantum-mechanical validity. In the correspondence limit, Hamilton's equations lead to an acceleration which contains the effect of an external field M1·F, plus a dissipative term which stems from the deviation in periodicity of the crystal potential.

Comments & Replies

Comment on "Position-dependent effective masses in semiconductor theory"

Carolyn M. Van Vliet and Alan H. Marshak
Phys. Rev. B 29, 5960 (1984)

References (11)

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  11. W. Jones and N. H. March, Theoretical Solid State Physics (Wiley, New York, 1973), Vol. 2, App. A8.1

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