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Wannier-Slater theorem for solids with nonuniform band structure
Phys. Rev. B 26, 6734 – Published 15 December, 1982
DOI: https://doi.org/10.1103/PhysRevB.26.6734
Abstract
The Wannier-Slater theorem for the Hamiltonian of a solid in an external field of force is generalized for solids with a nonuniform band structure, such as graded-gap mixed semiconductors. Our formulation is related to that of Gora and Williams, and their effectivemass equation is obtained if a -space Taylor expansion is permissible. This paper extends a too-restricted, earlier discussion by us in connection with transport in position-dependent band structures. The concept of a graded effective mass and position-dependent band bottom is derived from this treatment. It is pointed out, however, that the concept of a position-dependent effective mass has no strict quantum-mechanical validity. In the correspondence limit, Hamilton's equations lead to an acceleration which contains the effect of an external field , plus a dissipative term which stems from the deviation in periodicity of the crystal potential.
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Comment on "Position-dependent effective masses in semiconductor theory"
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